The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Engineering of β-Hydroxyl Esters into Elastomer–Nanoparticle Interface toward Malleable, Robust, and Reprocessable Vitrimer Composites
Abstract
Rubbers are strategically important due to their indispensable applications in the daily life and high-tech fields. For their real-world applications, the covalent cross-linking, reinforcement, and malleability of rubbers are three important issues because they are closely related to the elasticity, mechanical properties, and recycling of the rubber materials. Herein, we demonstrate a simple way to prepare covalently cross-linked yet recyclable and robust elastomeric vitrimer composites by incorporating exchangeable β-hydroxyl ester bonds into the elastomer-nanoparticle interface using epoxy group-functionalized silica (Esilica) as both cross-linker and reinforcement in carboxyl group-grafted styrene-butadiene rubber (CSBR). The Esilica-cross-linked CSBR composites exhibit promising mechanical properties due to the covalent linkages in the interface and fine silica dispersion in the matrix. In addition, the interface can undergo dynamic reshuffling via transesterification reactions to alter network topology at high temperatures, conferring the resulting composites the ability to be reshaped and recycled.
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Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis
Röttger, M., Domenech, T., van der Weegen, R., Breuillac, A., Nicolaÿ, R., & Leibler, L. (2017) · Science · doi:10.1126/science.aah5281 · Cited by 1,394
Dynamic Covalent Polymer Networks: from Old Chemistry to Modern Day Innovations
Zou, W., Dong, J., Luo, Y., Zhao, Q., & Xie, T. (2017) · Advanced Materials · doi:10.1002/adma.201606100 · Cited by 1,014
Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811
Making Insoluble Polymer Networks Malleable via Olefin Metathesis
Lu, Y.-X., Tournilhac, F., Leibler, L., & Guan, Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303356z · Cited by 568
Cited by
Vitrimers: directing chemical reactivity to control material properties
Guerre, M., Taplan, C., Winne, J. M., & Du Prez, F. E. (2020) · Chemical Science · doi:10.1039/d0sc01069c · Cited by 621
Chen, M., Zhou, L., Wu, Y., Zhao, X., & Zhang, Y. (2019) · ACS Macro Letters · doi:10.1021/acsmacrolett.9b00015 · Cited by 389
Xu, X., Ma, S., Wu, J., Yang, J., Wang, B., Wang, S., Li, Q., Feng, J., You, S., & Zhu, J. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta05293c · Cited by 285
Cao, L., Fan, J., Huang, J., & Chen, Y. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta11587g · Cited by 266
Self-citationVitrimer composites: current status and future challenges
Schenk, V., Labastie, K., Destarac, M., Olivier, P., & Guerre, M. (2022) · Materials Advances · doi:10.1039/d2ma00654e · Cited by 253
Metadata
- Authors
- Liu, Y., Tang, Z., Chen, Y., Zhang, C., & Guo, B.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-01-12
- Volume
- 10
- Issue
- 3
- Pages
- 2992-3001
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2779922300
- Cited by
- 212
- References
- 5
- FWCI
- 10.23
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, Y., Tang, Z., Chen, Y., Zhang, C., & Guo, B. (2018). Engineering of β-Hydroxyl Esters into Elastomer–Nanoparticle Interface toward Malleable, Robust, and Reprocessable Vitrimer Composites. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.7b17465
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