High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis
Abstract
A metathesis reaction yields a strategy to cross-link and enhance polymers without compromising easy processing and recycling.
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Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, thermomechanical degradation, or wholesale replacement of network components with degradable versions.
“Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, 3-8 thermomechanical degradation, 9 or wholesale replacement of network components with degradable versions. 10-13”
From Cleavable comonomers enable degradable, recyclable thermoset plastics (2020) · cites this paper as [7]
Cites
Principles of polymer chemistry
(1995) · Choice Reviews Online · doi:10.5860/choice.33-2140 · Cited by 15,292 · see citing works
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625 · see citing works
Martı́n, R., & Buchwald, S. L. (2008) · Accounts of Chemical Research · doi:10.1021/ar800036s · Cited by 2,651 · see citing works
Rowan, S. J., Cantrill, S., Cousins, G. R. L., Sanders, J. K. M., & Stoddart, J. F. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020315)41:6 · Cited by 2,599 · see citing works
Vitrimers: permanent organic networks with glass-like fluidity
Denissen, W., Winne, J. M., & Prez, F. D. (2015) · Chemical Science · doi:10.1039/c5sc02223a · Cited by 1,810 · see citing works
Ruhland, K. (2020) · Catalysis from A to Z · doi:10.1002/9783527809080.cataz06077 · Cited by 1,727 · see citing works
A detailed examination of boronic acid–diol complexation
Springsteen, G., & Wang, B. (2002) · Tetrahedron · doi:10.1016/s0040-4020(02)00489-1 · Cited by 1,467 · see citing works
Catalytic Control of the Vitrimer Glass Transition
Capelot, M., Unterlass, M. M., Tournilhac, F., & Ludwik Leibler, B. (2012) · ACS Macro Letters · doi:10.1021/mz300239f · Cited by 1,217 · see citing works
Metal-Catalyzed Transesterification for Healing and Assembling of Thermosets
Capelot, M., Montarnal, D., Tournilhac, F., & Ludwik Leibler, B. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302894k · Cited by 1,206 · see citing works
Denissen, W., Rivero, G., Nicolaÿ, R., Ludwik Leibler, B., Winne, J. M., & Prez, F. D. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201404553 · Cited by 1,130 · see citing works
Self-citationMalleable and Self-Healing Covalent Polymer Networks through Tunable Dynamic Boronic Ester Bonds
Cromwell, O. R., Chung, J., & Guan, Z. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03551 · Cited by 1,056 · see citing works
(2005) · Wiley eBooks · doi:10.1002/3527606548 · Cited by 983 · see citing works
Heat‐ or Water‐Driven Malleability in a Highly Recyclable Covalent Network Polymer
Taynton, P., Yu, K., Shoemaker, R. K., Jin, Y., Qi, H. J., & Zhang, W. (2014) · Advanced Materials · doi:10.1002/adma.201400317 · Cited by 890 · see citing works
Mouldable liquid-crystalline elastomer actuators with exchangeable covalent bonds
Pei, Z., Yang, Y., Chen, Q., Terentjev, E. M., Wei, Y., & Ji, Y. J. (2013) · Nature Materials · doi:10.1038/nmat3812 · Cited by 888 · see citing works
Drying of Organic Solvents: Quantitative Evaluation of the Efficiency of Several Desiccants
Williams, D. B. G., & Lawton, M. C. (2010) · The Journal of Organic Chemistry · doi:10.1021/jo101589h · Cited by 856 · see citing works
Contact, Adhesion and Rupture of Elastic Solids
Maugis, D. (2000) · Springer series in solid-state sciences · doi:10.1007/978-3-662-04125-3 · Cited by 846 · see citing works
Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811 · see citing works
Photoinduced Plasticity in Cross-Linked Polymers
Scott, T. F., Schneider, A. D., Cook, W. D., & Bowman, C. N. (2005) · Science · doi:10.1126/science.1110505 · Cited by 779 · see citing works
Yan, J., Springsteen, G., Deeter, S. D., et al. (2004) · Tetrahedron · doi:10.1016/j.tet.2004.08.051 · Cited by 753 · see citing works
Room-Temperature Self-Healing Polymers Based on Dynamic-Covalent Boronic Esters
Cash, J. J., Kubo, T., Bapat, A. P., et al. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00210 · Cited by 718 · see citing works
A review of crazing and fracture in thermoplastics
Kambour, R. P. (1973) · Journal of Polymer Science Macromolecular Reviews · doi:10.1002/pol.1973.230070101 · Cited by 698 · see citing works
Exploiting the Reversible Covalent Bonding of Boronic Acids: Recognition, Sensing, and Assembly
Bull, S. D., Davidson, M. G., van den Elsen, J. M. H., Fossey, J., Jenkins, A. T. A., Jiang, Y., Kubo, Y., Marken, F., Sakurai, K., Zhao, J., et al. (2012) · Accounts of Chemical Research · doi:10.1021/ar300130w · Cited by 672 · see citing works
Thermoset Shape‐Memory Polyurethane with Intrinsic Plasticity Enabled by Transcarbamoylation
Zheng, N., Fang, Z., Zou, W., Zhao, Q., & Xie, T. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602847 · Cited by 607 · see citing works
Making Insoluble Polymer Networks Malleable via Olefin Metathesis
Lu, Y.-X., Tournilhac, F., Leibler, L., & Guan, Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303356z · Cited by 568 · see citing works
Obadia, M. M., Mudraboyina, B. P., Serghei, A., Montarnal, D., & Drockenmuller, É. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b02653 · Cited by 521 · see citing works
Brutman, J. P., Delgado, P. A., & Hillmyer, M. A. (2014) · ACS Macro Letters · doi:10.1021/mz500269w · Cited by 516 · see citing works
Self-healing systems based on disulfide–thiol exchange reactions
Pepels, M. P. F., Filot, I. A. W., Klumperman, B., & Goossens, H. (2013) · Polymer Chemistry · doi:10.1039/c3py00087g · Cited by 469 · see citing works
Yang, Y., Pei, Z., Li, Z., Wei, Y., & Ji, Y. J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12531 · Cited by 411 · see citing works
Carbon nanotube–vitrimer composite for facile and efficient photo-welding of epoxy
Yang, Y., Pei, Z., Zhang, X., Tao, L., Wei, Y., & Ji, Y. J. (2014) · Chemical Science · doi:10.1039/c4sc00543k · Cited by 321 · see citing works
Bio‐Inspired High‐Performance and Recyclable Cross‐Linked Polymers
Shen, Y., Zhang, R., Wu, Q., Chen, T., & Sun, P. (2013) · Advanced Materials · doi:10.1002/adma.201301513 · Cited by 270 · see citing works
Regional Shape Control of Strategically Assembled Multishape Memory Vitrimers
Pei, Z., Yang, Y., Chen, Q., Wei, Y., & Ji, Y. (2016) · Advanced Materials · doi:10.1002/adma.201503789 · Cited by 250 · see citing works
Responsive Gels Based on a Dynamic Covalent Trithiocarbonate Cross-Linker
Nicolaÿ, R., Kamada, J., Wassen, A. R. V., & Matyjaszewski, K. A. (2010) · Macromolecules · doi:10.1021/ma100378r · Cited by 242 · see citing works
Self-citationMulti-stimuli responsive and multi-functional oligoaniline-modified vitrimers
Chen, Q., Yu, X., Pei, Z., Yang, Y., Wei, Y., & Ji, Y. J. (2016) · Chemical Science · doi:10.1039/c6sc02855a · Cited by 209 · see citing works
Multiple welding of long fiber epoxy vitrimer composites
Chabert, E., Vial, J., Cauchois, J.-P., Mihaluta, M., & Tournilhac, F. (2016) · Soft Matter · doi:10.1039/c6sm00257a · Cited by 183 · see citing works
Roy, C. D., & Brown, H. C. (2006) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2006.10.013 · Cited by 127 · see citing works
Crack propagation in lap shear joints
Kendall, K. (1975) · Journal of Physics D Applied Physics · doi:10.1088/0022-3727/8/5/010 · Cited by 104 · see citing works
The Structure of Macromolecules
Wunderlich, B. (1973) · Elsevier eBooks · doi:10.1016/b978-0-12-765601-4.50006-8 · Cited by 84 · see citing works
Xu, Y., Thurber, C. M., Lodge, T. P., & Hillmyer, M. A. (2012) · Macromolecules · doi:10.1021/ma302187b · Cited by 73 · see citing works
Roy, C. D., & Brown, H. C. (2007) · Monatshefte für Chemie - Chemical Monthly · doi:10.1007/s00706-007-0699-x · Cited by 52 · see citing works
Fyfe, J. W. B., Valverde, E., Seath, C. P., et al. (2015) · Chemistry - A European Journal · doi:10.1002/chem.201500970 · Cited by 52 · see citing works
Goldberg, A. R., & Northrop, B. H. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.5b02548 · Cited by 19 · see citing works
Roy, C. D., & Brown, H. C. (2007) · Monatshefte für Chemie - Chemical Monthly · doi:10.1007/s00706-007-0681-7 · Cited by 13 · see citing works
Savoji, M. T., Xu, Y., Thurber, C. M., Lodge, T. P., & Hillmyer, M. A. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b02640 · Cited by 13 · see citing works
Using Supramolecular Chemistry to Build Quantum Logic Gates
Walsh, J. P. S., & Freedman, D. E. (2016) · Chem · doi:10.1016/j.chempr.2016.10.010 · Cited by 11 · see citing works
Combining Mobile and Dynamic Bonds for Rapid and Efficient Self-Healing Materials
Bo, G. D. (2016) · Chem · doi:10.1016/j.chempr.2016.10.013 · Cited by 5 · see citing works
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Kuang, X., Roach, D. J., Wu, J., Hamel, C. M., Ding, Z., Wang, T., Dunn, M. L., & Qi, H. J. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201805290 · Cited by 1,095 · see citing works
Scheutz, G. M., Lessard, J. J., Sims, M. B., & Sumerlin, B. S. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07922 · Cited by 934 · see citing works
Dynamic covalent chemistry in polymer networks: a mechanistic perspective
Winne, J. M., Leibler, L., & Du Prez, F. E. (2019) · Polymer Chemistry · doi:10.1039/c9py01260e · Cited by 736 · see citing works
Self-citationClosed-loop recycling of plastics enabled by dynamic covalent diketoenamine bonds
Christensen, P. R., Scheuermann, A. M., Loeffler, K. E., & Helms, B. A. (2019) · Nature Chemistry · doi:10.1038/s41557-019-0249-2 · Cited by 676 · see citing works
Cleavable comonomers enable degradable, recyclable thermoset plastics
Shieh, P., Zhang, W., Husted, K. E. L., Kristufek, S. L., Xiong, B., Lundberg, D. J., Lem, J., Veysset, D., Sun, Y., Nelson, K. A., et al. (2020) · Nature · doi:10.1038/s41586-020-2495-2 · Cited by 498 · see citing works
50th Anniversary Perspective: Networks and Gels: Soft but Dynamic and Tough
Creton, C. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01698 · Cited by 463 · see citing works
Li, L., Chen, X., Jin, K., & Torkelson, J. M. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b00922 · Cited by 424 · see citing works
Photoswitching topology in polymer networks with metal–organic cages as crosslinks
Gu, Y., Alt, E. A., Wang, H., Li, X., Willard, A. P., & Johnson, J. A. (2018) · Nature · doi:10.1038/s41586-018-0339-0 · Cited by 371 · see citing works
Upcycling and catalytic degradation of plastic wastes
Hou, Q., Zhen, M., Qian, H., Nie, Y., Bai, X., Xia, T., Laiq Ur Rehman, M., Li, Q., & Ju, M. (2021) · Cell Reports Physical Science · doi:10.1016/j.xcrp.2021.100514 · Cited by 335 · see citing works
Poly(oxime–ester) Vitrimers with Catalyst-Free Bond Exchange
He, C., Shi, S., Wang, D., Helms, B. A., & Russell, T. P. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b06668 · Cited by 229 · see citing works
Chen, L., Malollari, K. G., Uliana, A., Sanchez, D., Messersmith, P. B., & Hartwig, J. F. (2021) · Chem · doi:10.1016/j.chempr.2020.11.020 · Cited by 225 · see citing works
Li, L., Chen, X., & Torkelson, J. M. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b01359 · Cited by 224 · see citing works
Zheng, J., Arifuzzaman, M., Tang, X., Chen, X. C., & Saito, T. (2023) · Materials Horizons · doi:10.1039/d2mh01549h · Cited by 73 · see citing works
- Authors
- Röttger, M., Domenech, T., van der Weegen, R., Breuillac, A., Nicolaÿ, R., & Leibler, L.
- Affiliations
- Matière Molle et Chimie, École Supérieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI)–CNRS, UMR-7167, Paris Sciences et Lettres (PSL) Research University, 10 Rue Vauquelin, 75005 Paris, France.
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Nicolaÿ, Renaud
- ORCID
- Venue
- Science
- Published
- 2017-04-07
- Volume
- 356
- Issue
- 6333
- Pages
- 62-65
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2605061198
- Cited by
- 1,394
- References
- 45
- Citations by year
- 2026: 128 · 2025: 201 · 2024: 188 · 2023: 192 · 2022: 194 · 2021: 151 · 2020: 145 · 2019: 106 · 2018: 71 · 2017: 18
- FWCI
- 53.15
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Funders
- SASSYPOL-ITN European Union FP7-People-2013-ITN (award301079, 607602)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Engineering › Mechanical Engineering › Epoxy Resin Curing Processes
- Keywords
- vitrimers, poly(methyl methacrylate), polystyrene, high-density polyethylene, polymer networks, chemical resistance, dimensional stability, polymer recycling, extrusion and injection molding
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