The DOI matches its Crossref record; 57 of the 57 references it cites were found in a registry or an index.
Covalently Cross-Linked Elastomers with Self-Healing and Malleable Abilities Enabled by Boronic Ester Bonds
Abstract
Covalently cross-linked rubbers are renowned for their high elasticity that play an indispensable role in various applications including tires, seals, and medical implants. Development of self-healing and malleable rubbers is highly desirable as it allows for damage repair and reprocessability to extend the lifetime and alleviate environmental pollution. Herein, we propose a facile approach to prepare permanently cross-linked yet self-healing and recyclable diene-rubber by programming dynamic boronic ester linkages into the network. The network is synthesized through one-pot thermally initiated thiol-ene "click" reaction between a novel dithiol-containing boronic ester cross-linker and commonly used styrene-butadiene rubber without modifying the macromolecular structure. The resulted samples are covalently cross-linked and possess relatively high mechanical strength which can be readily tailored by varying boronic ester content. Owing to the transesterification of boronic ester bonds, the samples can alter network topologies, endowing the materials with self-healing ability and malleability.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Hoyle, C. E., & Bowman, C. N. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200903924 · Cited by 4,182
Self-healing and thermoreversible rubber from supramolecular assembly
Cordier, P., Tournilhac, F., Soulié-Ziakovic, C., & Leibler, L. (2008) · Nature · doi:10.1038/nature06669 · Cited by 2,984
Vitrimers: permanent organic networks with glass-like fluidity
Denissen, W., Winne, J. M., & Du Prez, F. E. (2016) · Chemical Science · doi:10.1039/c5sc02223a · Cited by 1,790
Optically healable supramolecular polymers
Burnworth, M., Tang, L., Kumpfer, J. R., Duncan, A. J., Beyer, F. L., Fiore, G. L., Rowan, S. J., & Weder, C. (2011) · Nature · doi:10.1038/nature09963 · Cited by 1,778
Using the dynamic bond to access macroscopically responsive structurally dynamic polymers
Wojtecki, R. J., Meador, M. A., & Rowan, S. J. (2011) · Nature Materials · doi:10.1038/nmat2891 · Cited by 1,636
A highly stretchable autonomous self-healing elastomer
Li, C.-H., Wang, C., Keplinger, C., Zuo, J.-L., Jin, L., Sun, Y., Zheng, P., Cao, Y., Lissel, F., Linder, C., et al. (2016) · Nature Chemistry · doi:10.1038/nchem.2492 · Cited by 1,496
Recent advances in dynamic covalent chemistry
Jin, Y., Yu, C., Denman, R. J., & Zhang, W. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60044k · Cited by 1,487
High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis
Röttger, M., Domenech, T., van der Weegen, R., Breuillac, A., Nicolaÿ, R., & Leibler, L. (2017) · Science · doi:10.1126/science.aah5281 · Cited by 1,394
Covalent adaptable networks: smart, reconfigurable and responsive network systems
Kloxin, C. J., & Bowman, C. N. (2013) · Chem. Soc. Rev. · doi:10.1039/c3cs60046g · Cited by 1,370
Metal-Catalyzed Transesterification for Healing and Assembling of Thermosets
Capelot, M., Montarnal, D., Tournilhac, F., & Leibler, L. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302894k · Cited by 1,198
Cited by
A Highly Efficient Self‐Healing Elastomer with Unprecedented Mechanical Properties
Zhang, L., Liu, Z., Wu, X., Guan, Q., Chen, S., Sun, L., Guo, Y., Wang, S., Song, J., Jeffries, E. M., et al. (2019) · Advanced Materials · doi:10.1002/adma.201901402 · Cited by 664
Cho, S., Hwang, S. Y., Oh, D. X., & Park, J. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta02308j · Cited by 482
Boronic Ester Based Vitrimers with Enhanced Stability via Internal Boron–Nitrogen Coordination
Zhang, X., Wang, S., Jiang, Z., Li, Y., & Jing, X. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c10244 · Cited by 363
Self-citationLiu, Y., Tang, Z., Wu, S., & Guo, B. (2019) · ACS Macro Letters · doi:10.1021/acsmacrolett.9b00012 · Cited by 286
Self-citationElastomeric vitrimers from designer polyhydroxyalkanoates with recyclability and biodegradability
Cywar, R. M., Ling, C., Clarke, R. W., Kim, D. H., Kneucker, C. M., Salvachúa, D., Addison, B., Hesse, S. A., Takacs, C. J., Xu, S., et al. (2023) · Science Advances · doi:10.1126/sciadv.adi1735 · Cited by 46
Metadata
- Authors
- Chen, Y., Tang, Z., Zhang, X., Liu, Y., Wu, S., & Guo, B.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-06-26
- Volume
- 10
- Issue
- 28
- Pages
- 24224-24231
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2809736130
- Cited by
- 431
- References
- 57
- FWCI
- 15.08
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Covalently Cross-Linked Elastomers with Self-Healing and Malleable Abilities Enabled by Boronic Ester Bonds. https://app.cochat.ai/papers/10.1021/acsami.8b09863
- The paper
- Chen, Y., Tang, Z., Zhang, X., Liu, Y., Wu, S., & Guo, B. (2018). Covalently Cross-Linked Elastomers with Self-Healing and Malleable Abilities Enabled by Boronic Ester Bonds. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.8b09863
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
