The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Metal-Catalyzed Transesterification for Healing and Assembling of Thermosets
Abstract
Catalytic control of bond exchange reactions enables healing of cross-linked polymer materials under a wide range of conditions. The healing capability at high temperatures is demonstrated for epoxy-acid and epoxy-anhydride thermoset networks in the presence of transesterification catalysts. At lower temperatures, the exchange reactions are very sluggish, and the materials have properties of classical epoxy thermosets. Studies of model molecules confirmed that the healing kinetics is controlled by the transesterification reaction rate. The possibility of varying the catalyst concentration brings control and flexibility of welding and assembling of epoxy thermosets that do not exist for thermoplastics.
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Citations
Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
Self-citationCovalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175
A self-healing thermosetting composite material
Hayes, S. A., Jones, F. R., Marshiya, K., & Zhang, W. (2007) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2006.06.008 · Cited by 293
Cited by
High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis
Röttger, M., Domenech, T., van der Weegen, R., Breuillac, A., Nicolaÿ, R., & Leibler, L. (2017) · Science · doi:10.1126/science.aah5281 · Cited by 1,394
Denissen, W., Rivero, G., Nicolaÿ, R., Leibler, L., Winne, J. M., & Du Prez, F. E. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201404553 · Cited by 1,121
Self-citationAdvances in 4D Printing: Materials and Applications
Kuang, X., Roach, D. J., Wu, J., Hamel, C. M., Ding, Z., Wang, T., Dunn, M. L., & Qi, H. J. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201805290 · Cited by 1,095
Dynamic Covalent Polymer Networks: from Old Chemistry to Modern Day Innovations
Zou, W., Dong, J., Luo, Y., Zhao, Q., & Xie, T. (2017) · Advanced Materials · doi:10.1002/adma.201606100 · Cited by 1,014
Scheutz, G. M., Lessard, J. J., Sims, M. B., & Sumerlin, B. S. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07922 · Cited by 934
Metadata
- Authors
- Capelot, M., Montarnal, D., Tournilhac, F., & Leibler, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-30
- Volume
- 134
- Issue
- 18
- Pages
- 7664-7667
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2328954302
- Cited by
- 1,198
- References
- 3
- FWCI
- 17.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Capelot, M., Montarnal, D., Tournilhac, F., & Leibler, L. (2012). Metal-Catalyzed Transesterification for Healing and Assembling of Thermosets. Journal of the American Chemical Society. https://doi.org/10.1021/ja302894k
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