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Cited by 230

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Hierarchical Cellular Structured Ceramic Nanofibrous Aerogels with Temperature-Invariant Superelasticity for Thermal Insulation

Dou, Lvye, Zhang, Xinxin, Cheng, Xiaota, Ma, Zongmin, Wang, Xueqin, Si, Yang, Yu, Jianyong, Ding, Bin·2019·ACS Applied Materials & Interfaces

Abstract

Silica aerogels are attractive for thermal insulation due to their low thermal conductivity and good heat resistance performance. However, the fabrication of silica aerogels with temperature-invariant superelasticity and ultralow thermal conductivity has remained extremely challenging. Herein, we designed and synthesized a hierarchical cellular structured silica nanofibrous aerogel by using electrospun SiO 2 nanofibers (SNFs) and SiO 2 nanoparticle aerogels (SNAs) as the matrix and SiO 2 sol as the high-temperature nanoglue. This pathway leads to the intrinsically random deposited SNFs assembling into a fibrous cellular structure, and the SNAs are evenly distributed on the fibrous cell wall. The unique hierarchical cellular structure of the ceramic nanofibrous aerogels endows it with integrated performances of the ultralow density of ∼0.2 mg cm –3, negative Poisson’s ratio, ultralow thermal conductivity (23.27 mW m –1 K –1 ), temperature-invariant superelasticity from −196 to 1100 °C, and editable shapes on a large scale. These favorable multifeatures present the aerogels ideal for thermal insulation in industrial, aerospace, and even extreme environmental conditions.

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Metadata

Authors
Dou, L., Zhang, X., Cheng, X., Ma, Z., Wang, X., Si, Y., Yu, J., & Ding, B.
Venue
ACS Applied Materials & Interfaces
Published
2019-07-22
Volume
11
Issue
32
Pages
29056-29064
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2964150739
Cited by
230
References
2
FWCI
8.30
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Hierarchical Cellular Structured Ceramic Nanofibrous Aerogels with Temperature-Invariant Superelasticity for Thermal Insulation. https://app.cochat.ai/papers/10.1021/acsami.9b10018
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Dou, L., Zhang, X., Cheng, X., Ma, Z., Wang, X., Si, Y., Yu, J., & Ding, B. (2019). Hierarchical Cellular Structured Ceramic Nanofibrous Aerogels with Temperature-Invariant Superelasticity for Thermal Insulation. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.9b10018

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