The DOI matches its Crossref record; 65 of the 65 references it cites were found in a registry or an index.
Sulfur Vacancy-Rich O-Doped 1T-MoS2 Nanosheets for Exceptional Photocatalytic Nitrogen Fixation over CdS
Abstract
Here, we reported that sulfur vacancy-rich O-doped 1T-MoS 2 nanosheets (denoted as SV-1T-MoS 2 ) can surpass the activity of Pt as cocatalysts to assist in the photocatalytic nitrogen fixation of CdS nanorods. SV-1T-MoS 2 cocatalysts exhibit sulfur vacancies, O-doping, more metallic 1T phase, and high electronic conductivity, thus leading to the exposure of more active edge sites, high Brunauer–Emmett–Teller surface area, enhanced visible light absorption, and improved electron separation and transfer, which are beneficial for photocatalytic nitrogen fixation. Consequently, the optimized 30 wt % SV-1T-MoS 2 -/CdS composites exhibit an outstanding nitrogen fixation rate of 8220.83 μmol L –1 h –1 g –1 and long-term stability under simulated solar light irradiation, significantly higher than pure CdS nanorods, CdS–Pt (0.1 wt %), and 30 wt % 1T-MoS 2 /CdS composites. The catalytic mechanism of photocatalytic nitrogen fixation on SV-1T-MoS 2 is discussed by density functional theory calculations.
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Cites
Photoluminescence from Chemically Exfoliated MoS 2
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Photolysis of Water and Photoreduction of Nitrogen on Titanium Dioxide
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Cited by
From Conventional to Emerging Ammonia Production Technologies
Collado, L., Herrero, A., & de la Peña O’Shea, V. A. (2025) · Green Energy and Technology · doi:10.1007/978-3-031-62411-7_25 · Cited by 4
Metadata
- Authors
- Sun, B., Liang, Z., Qian, Y., Xu, X., Han, Y., & Tian, J.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-01-17
- Volume
- 12
- Issue
- 6
- Pages
- 7257-7269
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2999823694
- Cited by
- 284
- References
- 65
- FWCI
- 8.82
- Type
- journal article
- Language
- en
- Open access
- closed
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