The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Rational Catalyst Design for N2 Reduction under Ambient Conditions: Strategies toward Enhanced Conversion Efficiency
Open accessAbstract
Abstract Ammonia (NH3), one of the basic chemicals in most fertilizers and a promising carbon-free energy storage carrier, is typically synthesized via the Haber–Bosch process with high energy consumption and massive emission of greenhouse gases. The photo/electrocatalytic nitrogen reduction reaction (NRR) under ambient conditions has attracted increasing interests recently, providing alternative routes to realize green NH3 synthesis. Despite rapid advances achieved in this most attractive research field, the unsatisfactory conversion efficiency including a low NH3 yield rate, and limited Faradaic efficiency or apparent quantum efficiency still remains as a great challenge. The NRR performance is intrinsically related to the electronic and surface structure of catalysts. Rational design and preparation of advanced catalysts are indispensable to improve the performance (e.g., activity and selectivity) of NRR. In this Review, various strategies for the development of desirable catalysts are comprehensively summarized, mainly containing the defect engineering, structural manipulation, crystallographic tailoring, and interface regulation. State-of-the-art heterogeneous NRR catalysts, prevailing theories and underlying catalytic mechanisms, together with current issues, critical challenges, and perspectives are discussed. It is highly expected that this Review will promote the understanding of recent advances in this area and stimulate greater interests for designing promising NRR catalysts in future.
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CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
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Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution
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Greatly Improving Electrochemical N 2 Reduction over TiO 2 Nanoparticles by Iron Doping
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Cited by
High-entropy alloys in electrocatalysis: from fundamentals to applications
Ren, J.-T., Chen, L., Wang, H.-Y., & Yuan, Z.-Y. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00557g · Cited by 551
Comprehensive Understanding of the Thriving Ambient Electrochemical Nitrogen Reduction Reaction
Zhao, X., Hu, G., Chen, G., Zhang, H., Zhang, S., & Wang, H. (2021) · Advanced Materials · doi:10.1002/adma.202007650 · Cited by 503
Multi‐Sites Electrocatalysis in High‐Entropy Alloys
Li, H., Lai, J., Li, Z., & Wang, L. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202106715 · Cited by 494
Recent advances in electrocatalytic ammonia synthesis
Ouyang, L., Liang, J., Luo, Y., Zheng, D., Sun, S., Liu, Q., Hamdy, M. S., Sun, X., & Ying, B. (2023) · Chinese Journal of Catalysis · doi:10.1016/s1872-2067(23)64464-x · Cited by 266
Bao, Y., Zou, P., Liu, H., & Zheng, A. (2026) · Chemical Communications · doi:10.1039/d5cc05594f · Cited by 1
Metadata
- Authors
- Shi, L., Yin, Y., Wang, S., & Sun, H.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-05-26
- Volume
- 10
- Issue
- 12
- Pages
- 6870-6899
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W3030614241
- Cited by
- 418
- References
- 9
- FWCI
- 12.75
- Type
- journal article
- Language
- en
- Open access
- hybrid
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