The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.
Efficient Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Coupled with 4-Nitrophenol Hydrogenation in a Water System
Abstract
Electrocatalytic conversion of biomass-derived 5-hydroxymethylfurfural (HMF) to value-added 2,5-furandicarboxylic acid (FDCA) is of great significance for sustainable chemical production. The key challenge is to establish an electrocatalytic system with a wide potential window, which can selectively oxidize HMF to FDCA without causing water oxidation. In this study, Cu foam decorated with Cu(OH) 2 (CF-Cu(OH) 2 ) was successfully fabricated as an efficient catalyst, and CuOOH active species generated by electrochemistry were demonstrated as the main catalytic sites for HMF oxidation. As a result, the current density of CF-Cu(OH) 2 reached up to 198.2 mA/cm 2 (100 mM HMF, 1.0 M KOH, 0.8 V vs Ag/AgCl), and a high faradic efficiency close to 100% for FDCA production (yield: 98.7%) was realized. Moreover, we reveal the mechanism for the electro-oxidation of HMF to FDCA and further provide an insight into the oxidation pathway for HMF. A paired electrochemical system exhibits superior catalytic performance of synergetic reactions (HMF oxidation and 4-NP reduction). Therefore, this work proposes a strategy to simultaneously produce two types of value-added chemicals at both electrodes, which can be applied in other electrocatalytic systems for the green synthesis of organic compounds.
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Cites
Catalysis by metallic nanoparticles in aqueous solution: model reactions
Hervés, P., Pérez-Lorenzo, M., Liz-Marzán, L. M., Dzubiella, J., Lu, Y., & Ballauff, M. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35029g · Cited by 1,087
Deng, Y., Handoko, A. D., Du, Y., Xi, S., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00205 · Cited by 1,057
Combined biomass valorization and hydrogen production in a photoelectrochemical cell
Cha, H. G., & Choi, K.-S. (2015) · Nature Chemistry · doi:10.1038/nchem.2194 · Cited by 835
Photocatalytic transformations of lignocellulosic biomass into chemicals
Wu, X., Luo, N., Xie, S., Zhang, H., Zhang, Q., Wang, F., & Wang, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00314j · Cited by 707
Wu, X., Fan, X., Xie, S., Lin, J., Cheng, J., Zhang, Q., Chen, L., & Wang, Y. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0148-8 · Cited by 649
Yang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539
Wang, L., Xu, H., Jiang, N., Wang, Z., Jiang, J., & Zhang, T. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c00284 · Cited by 538
Tuning the Selective Adsorption Site of Biomass on Co3O4 by Ir Single Atoms for Electrosynthesis
Lu, Y., Liu, T., Dong, C., Huang, Y., Li, Y., Chen, J., Zou, Y., & Wang, S. (2021) · Advanced Materials · doi:10.1002/adma.202007056 · Cited by 509
Liu, W.-J., Dang, L., Xu, Z., Yu, H.-Q., Jin, S., & Huber, G. W. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01017 · Cited by 507
Electrocatalytic Oxidation of 5‐(Hydroxymethyl)furfural Using High‐Surface‐Area Nickel Boride
Barwe, S., Weidner, J., Cychy, S., Morales, D. M., Dieckhöfer, S., Hiltrop, D., Masa, J., Muhler, M., & Schuhmann, W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201806298 · Cited by 507
Cited by
Heterogeneous‐Interface‐Enhanced Adsorption of Organic and Hydroxyl for Biomass Electrooxidation
Zhou, P., Lv, X., Tao, S., Wu, J., Wang, H., Wei, X., Wang, T., Zhou, B., Lu, Y., Frauenheim, T., et al. (2022) · Advanced Materials · doi:10.1002/adma.202204089 · Cited by 570
Chen, D., Ding, Y., Cao, X., Wang, L., Lee, H., Lin, G., Li, W., Ding, G., & Sun, L. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202309478 · Cited by 235
Yang, Z., Wang, S., Wei, C., Chen, L., Xue, Z., & Mu, T. (2024) · Energy & Environmental Science · doi:10.1039/d3ee04543a · Cited by 169
Xu, P., Bao, Z., Zhao, Y., Zheng, L., Lv, Z., Shi, X., Wang, H., Fang, X., & Zheng, H. (2024) · Advanced Energy Materials · doi:10.1002/aenm.202303557 · Cited by 128
Ren, G., Liu, B., Xu, X., Jing, P., Wu, J., & Zhang, J. (2024) · Nano Today · doi:10.1016/j.nantod.2024.102315 · Cited by 50
Metadata
- Authors
- Pang, X., Bai, H., Zhao, H., Fan, W., & Shi, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2022-01-11
- Volume
- 12
- Issue
- 2
- Pages
- 1545-1557
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W4206151592
- Cited by
- 285
- References
- 50
- FWCI
- 15.99
- Type
- journal article
- Language
- en
- Open access
- closed
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- Pang, X., Bai, H., Zhao, H., Fan, W., & Shi, W. (2022). Efficient Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Coupled with 4-Nitrophenol Hydrogenation in a Water System. ACS Catalysis. https://doi.org/10.1021/acscatal.1c04880
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