The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.
Efficient Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Coupled with 4-Nitrophenol Hydrogenation in a Water System
Abstract
Electrocatalytic conversion of biomass-derived 5-hydroxymethylfurfural (HMF) to value-added 2,5-furandicarboxylic acid (FDCA) is of great significance for sustainable chemical production. The key challenge is to establish an electrocatalytic system with a wide potential window, which can selectively oxidize HMF to FDCA without causing water oxidation. In this study, Cu foam decorated with Cu(OH) 2 (CF-Cu(OH) 2 ) was successfully fabricated as an efficient catalyst, and CuOOH active species generated by electrochemistry were demonstrated as the main catalytic sites for HMF oxidation. As a result, the current density of CF-Cu(OH) 2 reached up to 198.2 mA/cm 2 (100 mM HMF, 1.0 M KOH, 0.8 V vs Ag/AgCl), and a high faradic efficiency close to 100% for FDCA production (yield: 98.7%) was realized. Moreover, we reveal the mechanism for the electro-oxidation of HMF to FDCA and further provide an insight into the oxidation pathway for HMF. A paired electrochemical system exhibits superior catalytic performance of synergetic reactions (HMF oxidation and 4-NP reduction). Therefore, this work proposes a strategy to simultaneously produce two types of value-added chemicals at both electrodes, which can be applied in other electrocatalytic systems for the green synthesis of organic compounds.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Catalysis by metallic nanoparticles in aqueous solution: model reactions
Hervés, P., Pérez-Lorenzo, M., Liz-Marzán, L. M., Dzubiella, J., Lu, Y., & Ballauff, M. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35029g · Cited by 1,087
Deng, Y., Handoko, A. D., Du, Y., Xi, S., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00205 · Cited by 1,057
Combined biomass valorization and hydrogen production in a photoelectrochemical cell
Cha, H. G., & Choi, K.-S. (2015) · Nature Chemistry · doi:10.1038/nchem.2194 · Cited by 835
Photocatalytic transformations of lignocellulosic biomass into chemicals
Wu, X., Luo, N., Xie, S., Zhang, H., Zhang, Q., Wang, F., & Wang, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00314j · Cited by 707
Wu, X., Fan, X., Xie, S., Lin, J., Cheng, J., Zhang, Q., Chen, L., & Wang, Y. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0148-8 · Cited by 649
Yang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539
Wang, L., Xu, H., Jiang, N., Wang, Z., Jiang, J., & Zhang, T. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c00284 · Cited by 538
Tuning the Selective Adsorption Site of Biomass on Co3O4 by Ir Single Atoms for Electrosynthesis
Lu, Y., Liu, T., Dong, C., Huang, Y., Li, Y., Chen, J., Zou, Y., & Wang, S. (2021) · Advanced Materials · doi:10.1002/adma.202007056 · Cited by 509
Liu, W.-J., Dang, L., Xu, Z., Yu, H.-Q., Jin, S., & Huber, G. W. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01017 · Cited by 507
Electrocatalytic Oxidation of 5‐(Hydroxymethyl)furfural Using High‐Surface‐Area Nickel Boride
Barwe, S., Weidner, J., Cychy, S., Morales, D. M., Dieckhöfer, S., Hiltrop, D., Masa, J., Muhler, M., & Schuhmann, W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201806298 · Cited by 507
Taitt, B. J., Nam, D.-H., & Choi, K.-S. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04003 · Cited by 461
Davis, S. E., Zope, B. N., & Davis, R. J. (2012) · Green Chem. · doi:10.1039/c1gc16074e · Cited by 430
Das, R., Sypu, V. S., Paumo, H. K., Bhaumik, M., Maharaj, V., & Maity, A. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.11.073 · Cited by 404
Jiang, N., You, B., Boonstra, R., Terrero Rodriguez, I. M., & Sun, Y. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00214 · Cited by 387
Wang, L., Sun, Y., Hu, L., Piao, J.-Y., Guo, J., Manthiram, A., Ma, J., & Cao, A. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta00880e · Cited by 351
Nam, D.-H., Taitt, B. J., & Choi, K.-S. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03152 · Cited by 339
Zhang, P., Sheng, X., Chen, X., Fang, Z., Jiang, J., Wang, M., Li, F., Fan, L., Ren, Y., Zhang, B., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201903936 · Cited by 298
Zhang, A., Zheng, W., Yuan, Z., Tian, J., Yue, L., Zheng, R., Wei, D., & Liu, J. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.122486 · Cited by 265
Biomass Valorization via Paired Electrosynthesis Over Vanadium Nitride‐Based Electrocatalysts
Li, S., Sun, X., Yao, Z., Zhong, X., Cao, Y., Liang, Y., Wei, Z., Deng, S., Zhuang, G., Li, X., et al. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201904780 · Cited by 226
Rajkumar, C., Veerakumar, P., Chen, S.-M., Thirumalraj, B., & Lin, K.-C. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b02041 · Cited by 211
Wu, X., Li, J., Xie, S., Duan, P., Zhang, H., Feng, J., Zhang, Q., Cheng, J., & Wang, Y. (2020) · Chem · doi:10.1016/j.chempr.2020.08.014 · Cited by 205
Huang, X., Song, J., Hua, M., Xie, Z., Liu, S., Wu, T., Yang, G., & Han, B. (2020) · Green Chemistry · doi:10.1039/c9gc03698a · Cited by 201
Green Chemistry: Electrochemical Organic Transformations via Paired Electrolysis
Sbei, N., Hardwick, T., & Ahmed, N. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c00665 · Cited by 179
Cai, M., Zhang, Y., Zhao, Y., Liu, Q., Li, Y., & Li, G. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta07793c · Cited by 172
Zhao, X., Fan, Y., Zhang, W., Zhang, X., Han, D., Niu, L., & Ivaska, A. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01033 · Cited by 164
Latsuzbaia, R., Bisselink, R. J. M., Anastasopol, A., van der Meer, H., van Heck, R., Yagüe, M. S., Zijlstra, M., Roelands, M., Crockatt, M., Goetheer, E. L. V., et al. (2018) · Journal of Applied Electrochemistry · doi:10.1007/s10800-018-1157-7 · Cited by 159
Zhu, M., Zhang, L., Liu, S., Wang, D., Qin, Y., Chen, Y., Dai, W., Wang, Y., Xing, Q., & Zou, J. (2020) · Chinese Chemical Letters · doi:10.1016/j.cclet.2020.01.017 · Cited by 159
Wang, Y., Zhou, W., Jia, R., Yu, Y., & Zhang, B. (2020) · Angewandte Chemie · doi:10.1002/ange.201915992 · Cited by 159
Zhang, N., Zou, Y., Li, T., Chen, W., Zhou, L. P., Liu, Z., Zhou, B., Huang, G., Lin, H., & Wang, S. (2019) · Angewandte Chemie · doi:10.1002/ange.201908722 · Cited by 152
Anantharaj, S., Hisashi Sugime, A., & Noda, S. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.0c08979 · Cited by 149
Zhang, M., Su, X., Ma, L., Khan, A., Wang, L., Wang, J., Maloletnev, A. S., & Yang, C. (2020) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.123870 · Cited by 144
Zhu, S., Wang, Z., Huang, F., Zhang, H., & Li, S. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta01805c · Cited by 138
Feng, Y. P., Lee, P.-H. H., Wu, D., Zhou, Z.-Y., Li, H., & Shih, K. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2017.02.029 · Cited by 133
Wang, F., Song, S., Li, K., Li, J., Pan, J., Yao, S., Ge, X., Feng, J., Wang, X., & Zhang, H. (2016) · Advanced Materials · doi:10.1002/adma.201603608 · Cited by 117
Liu, X., Zhang, M., & Li, Z. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b07443 · Cited by 99
Zhou, S., Feng, X., Shi, H., Chen, J., Zhang, F., & Song, W. (2012) · Sensors and Actuators B Chemical · doi:10.1016/j.snb.2012.11.035 · Cited by 92
Guan, W., Zhang, Y., Chen, Y., Wu, J., Cao, Y. C., Wei, Y., & Huo, P. (2021) · Journal of Catalysis · doi:10.1016/j.jcat.2021.02.012 · Cited by 91
Spaeth, A. D., Gagnon, N. L., Dhar, D., Yee, G. M., & Tolman, W. B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00210 · Cited by 83
Duan, Y. W., Zheng, M., Li, D., Deng, D., Ma, L., & Yang, Y. (2017) · Green Chemistry · doi:10.1039/c7gc02310c · Cited by 80
Zhao, D., Rodríguez‐Padrón, D., Luque, R., & Len, C. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b07170 · Cited by 78
Cai, M. S., Ding, S., Gibbons, B. J., Yang, X., Kessinger, M. C., & Morris, A. J. (2020) · Chemical Communications · doi:10.1039/d0cc02206c · Cited by 73
Coupled Chemical and Thermal Drivers in Microwaves toward Ultrafast HMF Oxidation to FDCA
Ji, T., Liu, C., Lü, X., & Zhu, J. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b01630 · Cited by 72
Modular Electrochemical Synthesis Using a Redox Reservoir Paired with Independent Half-Reactions
Wang, F., Li, W., Wang, R., Guo, T., Sheng, H., Fu, H., Stahl, S. S., & Jin, S. (2020) · Joule · doi:10.1016/j.joule.2020.11.011 · Cited by 68
Lu, Y., Dong, C., Huang, Y., Zou, Y., Liu, Z., Liu, Y., Li, Y., He, N., Shi, J., & Wang, S. (2020) · Angewandte Chemie · doi:10.1002/ange.202007767 · Cited by 60
Elektrokatalytische Oxidation von 5‐(Hydroxymethyl)furfural an Nickelborid mit großer Oberfläche
Barwe, S., Weidner, J., Cychy, S., Morales, D. M., Dieckhöfer, S., Hiltrop, D., Masa, J., Muhler, M., & Schuhmann, W. W. (2018) · Angewandte Chemie · doi:10.1002/ange.201806298 · Cited by 56
Anantharaj, S., Sugime, H., Yamaoka, S., & Noda, S. (2021) · ACS Applied Energy Materials · doi:10.1021/acsaem.0c02822 · Cited by 54
Sun, X., Liu, Z., Xue, Z., Zhang, Y., & Mu, T. (2015) · Green Chemistry · doi:10.1039/c5gc00092k · Cited by 49
Hua, M., Song, J., Huang, X., Hou, M., Fan, H., Zhang, Z., Wu, T., & Han, B. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c00971 · Cited by 43
Fang, Z., Zhang, P., Wang, M., Li, F., Wu, X., Fan, K., & Sun, L. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c03691 · Cited by 41
Afroz, K., Ntambwe, M., & Nuraje, N. (2020) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.0c01702 · Cited by 33
Cited by
Heterogeneous‐Interface‐Enhanced Adsorption of Organic and Hydroxyl for Biomass Electrooxidation
Zhou, P., Lv, X., Tao, S., Wu, J., Wang, H., Wei, X., Wang, T., Zhou, B., Lu, Y., Frauenheim, T., et al. (2022) · Advanced Materials · doi:10.1002/adma.202204089 · Cited by 570
Chen, D., Ding, Y., Cao, X., Wang, L., Lee, H., Lin, G., Li, W., Ding, G., & Sun, L. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202309478 · Cited by 235
Yang, Z., Wang, S., Wei, C., Chen, L., Xue, Z., & Mu, T. (2024) · Energy & Environmental Science · doi:10.1039/d3ee04543a · Cited by 169
Xu, P., Bao, Z., Zhao, Y., Zheng, L., Lv, Z., Shi, X., Wang, H., Fang, X., & Zheng, H. (2024) · Advanced Energy Materials · doi:10.1002/aenm.202303557 · Cited by 128
Ren, G., Liu, B., Xu, X., Jing, P., Wu, J., & Zhang, J. (2024) · Nano Today · doi:10.1016/j.nantod.2024.102315 · Cited by 50
Metadata
- Authors
- Pang, X., Bai, H., Zhao, H., Fan, W., & Shi, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2022-01-11
- Volume
- 12
- Issue
- 2
- Pages
- 1545-1557
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W4206151592
- Cited by
- 285
- References
- 50
- FWCI
- 15.99
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
