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Nickel Complexes for Robust Light-Driven and Electrocatalytic Hydrogen Production from Water
Abstract
A series of nickel bis(chelate) complexes having square planar coordination are studied for light-driven and electrocatalytic hydrogen production from water. The complexes Ni(abt) 2 (abt = 2-aminobenzenethiolate), Ni(mp) 2 (mp = 2-mercaptophenolate) and Ni(mpo) 2 (mpo = 2-mercaptopyridyl- N -oxide) are found to be active catalysts under light-driven conditions, using fluorescein (Fl) as the photosensitizer (PS) and triethanolamine (TEOA) as the sacrificial electron donor in water under basic pH (pH = 9.8). These molecular systems achieve a turnover number (TON) of ∼6000 (relative to catalyst) and are stable for more than 100 h under H 2 -generating conditions. When water-soluble CdSe quantum dots with tripodal S-donor capping agents are employed as PS and ascorbic acid (AA) is used as the sacrificial electron donor at pH 4.5, an active and robust system is obtained for the light-driven generation of H 2 from aqueous protons. A TON of over 280 000 is achieved for the three active catalysts. These complexes are also examined electrochemically in organic solvents with weak organic acids as the proton source and in aqueous and aqueous/organic media for proton reduction. The most active photochemical catalysts also show excellent electrocatalytic activity in neutral pH water, achieving Faradaic yields close to 100% under anaerobic conditions and ∼80% under aerobic conditions.
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Citations
Cites
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,310
Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen
Bard, A. J., & Fox, M. A. (1995) · Accounts of Chemical Research · doi:10.1021/ar00051a007 · Cited by 2,577
Artero, V., Chavarot‐Kerlidou, M., & Fontecave, M. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007987 · Cited by 1,393
Du, P., & Eisenberg, R. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03250c · Cited by 1,350
Self-citationA Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s −1 for H 2 Production
Helm, M. L., Stewart, M. P., Bullock, R. M., DuBois, M. R., & DuBois, D. L. (2011) · Science · doi:10.1126/science.1205864 · Cited by 1,219
A Molecular MoS 2 Edge Site Mimic for Catalytic Hydrogen Generation
Karunadasa, H. I., Montalvo, E., Sun, Y., Majda, M., Long, J. R., & Chang, C. J. (2012) · Science · doi:10.1126/science.1215868 · Cited by 1,215
Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions
Lyaskovskyy, V., & de Bruin, B. (2012) · ACS Catalysis · doi:10.1021/cs200660v · Cited by 1,079
Chemical Approaches to Artificial Photosynthesis. 2
Alstrum-Acevedo, J. H., Brennaman, M. K., & Meyer, T. J. (2005) · Inorganic Chemistry · doi:10.1021/ic050904r · Cited by 941
Robust Photogeneration of H 2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst
Han, Z., Qiu, F., Eisenberg, R., Holland, P. L., & Krauss, T. D. (2012) · Science · doi:10.1126/science.1227775 · Cited by 771
Self-citationA molecular molybdenum-oxo catalyst for generating hydrogen from water
Karunadasa, H. I., Chang, C. J., & Long, J. R. (2010) · Nature · doi:10.1038/nature08969 · Cited by 704
Energy implications of future stabilization of atmospheric CO2 content
Hoffert, M. I., Caldeira, K., Jain, A. K., Haites, E. F., Harvey, L. D. D., Potter, S. D., Schlesinger, M. E., Schneider, S. H., Watts, R. G., Wigley, T. M. L., et al. (1998) · Nature · doi:10.1038/27638 · Cited by 692
Making Hydrogen from Water Using a Homogeneous System Without Noble Metals
Lazarides, T., McCormick, T., Du, P., Luo, G., Lindley, B., & Eisenberg, R. (2009) · Journal of the American Chemical Society · doi:10.1021/ja903044n · Cited by 656
Self-citationSIR2011: a new package for crystal structure determination and refinement
Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B., Cascarano, G. L., Giacovazzo, C., Mallamo, M., Mazzone, A., Polidori, G., & Spagna, R. (2012) · Journal of Applied Crystallography · doi:10.1107/s0021889812001124 · Cited by 574
Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water
Sun, Y., Bigi, J. P., Piro, N. A., Tang, M. L., Long, J. R., & Chang, C. J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202743r · Cited by 442
Cobaloxime‐Based Photocatalytic Devices for Hydrogen Production
Fihri, A., Artero, V., Razavet, M., Baffert, C., Leibl, W., & Fontecave, M. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702953 · Cited by 425
A Cobalt–Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons
McNamara, W. R., Han, Z., Alperin, P. J., Brennessel, W. W., Holland, P. L., & Eisenberg, R. (2011) · Journal of the American Chemical Society · doi:10.1021/ja207842r · Cited by 398
Self-citationElectrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles
McCrory, C. C. L., Uyeda, C., & Peters, J. C. (2012) · Journal of the American Chemical Society · doi:10.1021/ja210661k · Cited by 351
Fuel from Water: The Photochemical Generation of Hydrogen from Water
Han, Z., & Eisenberg, R. (2014) · Accounts of Chemical Research · doi:10.1021/ar5001605 · Cited by 346
Self-citationBachler, V., Olbrich, G., Neese, F., & Wieghardt, K. (2002) · Inorganic Chemistry · doi:10.1021/ic0113101 · Cited by 335
McCormick, T. M., Calitree, B. D., Orchard, A., Kraut, N. D., Bright, F. V., Detty, M. R., & Eisenberg, R. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1057357 · Cited by 324
Self-citationSingh, W. M., Baine, T., Kudo, S., Tian, S., Ma, X. A. N., Zhou, H., DeYonker, N. J., Pham, T. C., Bollinger, J. C., Baker, D. L., et al. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200082 · Cited by 324
Han, Z., McNamara, W. R., Eum, M., Holland, P. L., & Eisenberg, R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107329 · Cited by 319
Self-citationMcNamara, W. R., Han, Z., Yin, C.-J. (., Brennessel, W. W., Holland, P. L., & Eisenberg, R. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1120757109 · Cited by 296
Self-citationMolecular mechanisms of cobalt-catalyzed hydrogen evolution
Marinescu, S. C., Winkler, J. R., & Gray, H. B. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1213442109 · Cited by 284
Han, Z., Shen, L., Brennessel, W. W., Holland, P. L., & Eisenberg, R. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405257s · Cited by 284
Self-citationPhotocatalytic Water Reduction with Copper‐Based Photosensitizers: A Noble‐Metal‐Free System
Luo, S., Mejía, E., Friedrich, A., Pazidis, A., Junge, H., Surkus, A., Jackstell, R., Denurra, S., Gladiali, S., Lochbrunner, S., et al. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201205915 · Cited by 284
Carroll, M. E., Barton, B. E., Rauchfuss, T. B., & Carroll, P. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309216v · Cited by 280
Probst, B., Rodenberg, A., Guttentag, M., Hamm, P., & Alberto, R. (2010) · Inorganic Chemistry · doi:10.1021/ic100036v · Cited by 218
Streich, D., Astuti, Y., Orlandi, M., Schwartz, L., Lomoth, R., Hammarström, L., & Ott, S. (2010) · Chemistry – A European Journal · doi:10.1002/chem.200902489 · Cited by 210
Kleingardner, J. G., Kandemir, B., & Bren, K. L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja406818h · Cited by 210
Mondal, B., Sengupta, K., Rana, A., Mahammed, A., Botoshansky, M., Dey, S. G., Gross, Z., & Dey, A. (2013) · Inorganic Chemistry · doi:10.1021/ic4000473 · Cited by 201
Cobalt complexes as artificial hydrogenases for the reductive side of water splitting
Eckenhoff, W. T., McNamara, W. R., Du, P., & Eisenberg, R. (2013) · Biochimica et Biophysica Acta (BBA) - Bioenergetics · doi:10.1016/j.bbabio.2013.05.003 · Cited by 196
Self-citationDithiolene radicals: Sulfur K-edge X-ray absorption spectroscopy and Harry's intuition
Sproules, S., & Wieghardt, K. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.12.006 · Cited by 192
Catalytic proton reduction with transition metal complexes of the redox-active ligand bpy2PYMe
Nippe, M., Khnayzer, R. S., Panetier, J. A., Zee, D. Z., Olaiya, B. S., Head-Gordon, M., Chang, C. J., Castellano, F. N., & Long, J. R. (2013) · Chemical Science · doi:10.1039/c3sc51660a · Cited by 188
Orchestrated Photocatalytic Water Reduction Using Surface-Adsorbing Iridium Photosensitizers
DiSalle, B. F., & Bernhard, S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201514e · Cited by 176
McLaughlin, M. P., McCormick, T. M., Eisenberg, R., & Holland, P. L. (2011) · Chemical Communications · doi:10.1039/c1cc12347e · Cited by 168
Self-citationStewart, M. P., Ho, M.-H., Wiese, S., Lindstrom, M. L., Thogerson, C. E., Raugei, S., Bullock, R. M., & Helm, M. L. (2013) · Journal of the American Chemical Society · doi:10.1021/ja400181a · Cited by 168
Baker-Hawkes, M. J., Billig, E., & Gray, H. B. (1966) · Journal of the American Chemical Society · doi:10.1021/ja00973a021 · Cited by 147
Das, A., Han, Z., Haghighi, M. G., & Eisenberg, R. (2013) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1316755110 · Cited by 137
Self-citationSolis, B. H., & Hammes‐Schiffer, S. (2012) · Journal of the American Chemical Society · doi:10.1021/ja306857q · Cited by 135
Photocatalytic Hydrogen Generation System Using a Nickel-Thiolate Hexameric Cluster
Kagalwala, H. N., Gottlieb, E. R., Li, G., Li, T., Jin, R. M., & Bernhard, S. (2013) · Inorganic Chemistry · doi:10.1021/ic4013069 · Cited by 113
Zhang, P., Wang, M., Gloaguen, F., Chen, L., Quentel, F., & Sun, L. (2013) · Chemical Communications · doi:10.1039/c3cc43491e · Cited by 105
Protein Delivery of a Ni Catalyst to Photosystem I for Light-Driven Hydrogen Production
Silver, S. C., Niklas, J., Du, P., Poluektov, O. G., Tiede, D. M., & Utschig, L. M. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405277g · Cited by 97
Production of H2 at fast rates using a nickel electrocatalyst in water–acetonitrile solutions
Hoffert, W. A., Roberts, J. A. S., Bullock, R. M., & Helm, M. L. (2013) · Chemical Communications · doi:10.1039/c3cc43203c · Cited by 93
White, T. A., Whitaker, B. N., & Brewer, K. J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206782k · Cited by 58
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Dong, R., Pfeffermann, M., Liang, H., Zheng, Z., Zhu, X., Zhang, J., & Feng, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201506048 · Cited by 621
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Metadata
- Authors
- Das, A., Han, Z., Brennessel, W. W., Holland, P. L., & Eisenberg, R.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-01-29
- Volume
- 5
- Issue
- 3
- Pages
- 1397-1406
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2318260462
- Cited by
- 258
- References
- 45
- FWCI
- 11.05
- Type
- journal article
- Language
- en
- Open access
- closed
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