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Mechanistic Insights into the Reduction of CO2 on Tin Electrodes using in Situ ATR-IR Spectroscopy
Abstract
The reduction of CO 2 on tin cathodes was studied using in situ attenuated total reflectance infrared spectroscopy (ATR-IR). Thin films of a mixed Sn/SnO x species were deposited onto a single-crystal ZnSe ATR crystal. Peaks centered at about 1500, 1385, and 1100 cm –1, attributed to a surface-bound monodentate tin carbonate species, were consistently present under conditions at which CO 2 reduction takes place. It was shown that these peaks are only present at potentials where CO 2 reduction is observed. Moreover, these peaks disappear if the pH of the reaction is too low or if the tin surface is chemically etched to remove surface oxide. Sn 6 O 4 (OH) 4 and SnO 2 nanoparticles were shown to be catalytically active for CO 2 reduction, and insights into the oxidation state of the catalytically active species are gained from a comparison of the catalytic behavior of the two nanoparticle species. From these experiments, a mechanism governing the reduction of CO 2 on tin electrodes is proposed.
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Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
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Metadata
- Authors
- Baruch, M. F., Pander, J. E., White, J. L., & Bocarsly, A. B.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-04-22
- Volume
- 5
- Issue
- 5
- Pages
- 3148-3156
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2326437178
- Cited by
- 509
- References
- 1
- FWCI
- 10.66
- Type
- journal article
- Language
- en
- Open access
- closed
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- Baruch, M. F., Pander, J. E., White, J. L., & Bocarsly, A. B. (2015). Mechanistic Insights into the Reduction of CO2 on Tin Electrodes using in Situ ATR-IR Spectroscopy. ACS Catalysis. https://doi.org/10.1021/acscatal.5b00402
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