Cited by 112Advanced Battery Materials and TechnologiesAdvancements in Battery MaterialsElectrocatalysts for Energy Conversion

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Morphology and Active-Site Engineering for Stable Round-Trip Efficiency Li–O2 Batteries: A Search for the Most Active Catalytic Site in Co3O4

Song, Kyeongse, Cho, Eunbi, Kang, Yong-Mook·2015·ACS Catalysis

DOI 10.1021/acscatal.5b01196

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Abstract

For the purpose of finding the catalytic active site for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) in the crystal structure of Co 3 O 4, a {100} faceted Co 3 O 4 cube enclosed by only a Co 2+ site and a {112} faceted Co 3 O 4 plate also exposing a Co 3+ site was adopted as a catalyst for lithium–oxygen (Li–O 2 ) batteries. Thus, we found that the Co 3+ site plays the crucial role of determining the adsorption properties of reactants, enabling high round-trip efficiency and cyclic stability, as well as the morphology of discharge products such as Li 2 O 2 .

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Authors: Song, K., Cho, E., & Kang, Y.-M.
Affiliations: Dongguk University (KR)
Corresponding author: Kang, Yong-Mook
ORCID: Cho, Eunbi
Kang, Yong-Mook
Venue: ACS Catalysis
Publisher: American Chemical Society (ACS)
Published: 2015-08-05
Volume: 5
Issue: 9
Pages: 5116-5122
ISSN: 2155-5435 (ISSN-L)
DOI: 10.1021/acscatal.5b01196
OpenAlex: W2517550844
Cited by: 112
References: 63
Citations by year: 2026: 3 · 2025: 7 · 2024: 7 · 2023: 9 · 2022: 13 · 2021: 12 · 2020: 12 · 2019: 16 · 2018: 11 · 2017: 11 · 2016: 8 · 2015: 3
FWCI: 5.30
Type: journal article
Language: en
Open access: closed
Locations: ACS Catalysis (publishedVersion)
Funders: National Research Foundation of Korea (NRF-2012M1A2A2671807, NRF-2013H1A2A1033981)
Ministry of Knowledge Economy (20122010100140)
Topics: Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords: lithium-oxygen batteries, cobalt oxide, Co3O4, oxygen reduction reaction, oxygen evolution reaction, active site engineering, facet engineering, round-trip efficiency, Li2O2 discharge product, cycling stability, morphology control

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Morphology and Active-Site Engineering for Stable Round-Trip Efficiency Li–O2 Batteries: A Search for the Most Active Catalytic Site in Co3O4

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