The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Simultaneous Reduction of CO2 and Splitting of H2O by a Single Immobilized Cobalt Phthalocyanine Electrocatalyst
Abstract
Perfluorinated cobalt phthalocyanine (CoFPc) immobilized on carbon electrodes was found to electrocatalyze the reduction of CO 2 selectively to CO in an aqueous solution. The conversion of CO 2 became apparent at −0.5 V vs RHE, and the Faradaic efficiency for the CO production reached as high as 93% at −0.8 V vs RHE. Highly stable electrolysis of CO 2 /H 2 O into CO/O 2 was achieved for 12 h by applying the same catalyst as the cathode for CO 2 reduction and the anode for water oxidation. This result indicates the highly robust nature of the CoFPc at wide range of potentials from −0.9 V to +2.2 V vs RHE, demonstrating the potential bipolar electrolytic system for CO 2 /H 2 O electrolysis, using the single-site molecular CoFPc-based electrocatalyst, which is simple, inexpensive, robust, and efficient.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Roles of Cocatalysts in Photocatalysis and Photoelectrocatalysis
Yang, J., Wang, D., Han, H., & Li, C. (2013) · Accounts of Chemical Research · doi:10.1021/ar300227e · Cited by 2,848
Competition between CO 2 Reduction and H 2 Evolution on Transition-Metal Electrocatalysts
Zhang, Y.-J., Sethuraman, V., Michalsky, R., & Peterson, A. A. (2014) · ACS Catalysis · doi:10.1021/cs5012298 · Cited by 509
Cited by
Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts
Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2020) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 452
Wu, J., Sharifi, T., Gao, Y., Zhang, T., & Ajayan, P. M. (2019) · Advanced Materials · doi:10.1002/adma.201804257 · Cited by 325
Sekar, P., Calvillo, L., Tubaro, C., Baron, M., Pokle, A., Carraro, F., Martucci, A., & Agnoli, S. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02166 · Cited by 92
Metadata
- Authors
- Morlanés, N., Takanabe, K., & Rodionov, V.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-04-14
- Volume
- 6
- Issue
- 5
- Pages
- 3092-3095
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2340908997
- Cited by
- 278
- References
- 3
- FWCI
- 7.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Morlanés, N., Takanabe, K., & Rodionov, V. (2016). Simultaneous Reduction of CO2 and Splitting of H2O by a Single Immobilized Cobalt Phthalocyanine Electrocatalyst. ACS Catalysis. https://doi.org/10.1021/acscatal.6b00543
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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