The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Water-Mediated Mars–Van Krevelen Mechanism for CO Oxidation on Ceria-Supported Single-Atom Pt1 Catalyst
Abstract
In water-promoted CO oxidation, water was thought not to directly participate in CO 2 production. Here we report that via a water-mediated Mars–van Krevelen (MvK) mechanism, water can directly contribute to about 50% of CO 2 production on a single-atom Pt 1 /CeO 2 catalyst. The origin is the facile reaction of CO with the hydroxyl from dissociated water to yield the carboxyl intermediate, which dehydrogenates subsequently with the help of a lattice hydroxyl to generate CO 2 and water. The water-mediated MvK type reaction found here provides new insights in the promotion role of water in heterogeneous catalysis.
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Citations
Cites
Roles of Water for Chemical Reactions in High-Temperature Water
Akiya, N., & Savage, P. E. (2002) · Chemical Reviews · doi:10.1021/cr000668w · Cited by 1,581
Mhadeshwar, A. B., & Vlachos, D. G. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp048698g · Cited by 159
Cited by
Pereira-Hernández, X. I., DeLaRiva, A., Muravev, V., Kunwar, D., Xiong, H., Sudduth, B., Engelhard, M., Kovarik, L., Hensen, E. J. M., Wang, Y., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09308-5 · Cited by 499
The Multifaceted Reactivity of Single‐Atom Heterogeneous Catalysts
Mitchell, S., Vorobyeva, E., & Pérez‐Ramírez, J. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201806936 · Cited by 348
Sarma, B. B., Maurer, F., Doronkin, D. E., & Grunwaldt, J.-D. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00495 · Cited by 291
Single‐Atom Catalysts of Precious Metals for Electrochemical Reactions
Kim, J., Kim, H., & Lee, H. (2018) · ChemSusChem · doi:10.1002/cssc.201701306 · Cited by 282
Su, H., Gao, W., Li, L., Yuan, H., & Wen, D. (2023) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.3c02126 · Cited by 50
Metadata
- Authors
- Wang, C., Gu, X.-K., Yan, H., Lin, Y., Li, J., Liu, D., Li, W.-X., & Lu, J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-28
- Volume
- 7
- Issue
- 1
- Pages
- 887-891
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2567452826
- Cited by
- 557
- References
- 2
- FWCI
- 14.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, C., Gu, X.-K., Yan, H., Lin, Y., Li, J., Liu, D., Li, W.-X., & Lu, J. (2017). Water-Mediated Mars–Van Krevelen Mechanism for CO Oxidation on Ceria-Supported Single-Atom Pt1 Catalyst. ACS Catalysis. https://doi.org/10.1021/acscatal.6b02685
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