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Cited by 348

The DOI matches its Crossref record; 149 of the 149 references it cites were found in a registry or an index.

The Multifaceted Reactivity of Single‐Atom Heterogeneous Catalysts

Open access
Mitchell, Sharon, Vorobyeva, Evgeniya, Pérez‐Ramírez, Javier·2018·Angewandte Chemie International Edition

Abstract

Single‐atom heterogeneous catalysts (SACs) attached to carefully chosen hosts are attracting considerable interest; principally because they offer maximum utilization per metal atom and are usually readily recyclable. However, diminution of the atomic population of nanoparticles or nanoclusters to single atoms can significantly alter reactivity because of the consequent changes in the active‐site structure. By examining various diverse applications, we ascertain whether the performance of SACs is enhanced or suppressed. We also note that SACs generally display unique kinds of catalytic cycles. The choice of host is crucial since it influences both the electronic and steric environment of the metal center. Moreover, it may function as a cocatalyst. All these aspects impact upon the design of new SACs, which exhibit similarities to hetero‐ and homogeneous predecessors. Additionally, SACs offer a viable replacement of soluble metal complexes in processes that remain difficult to heterogenize.

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Crossref · 10.1002/anie.201806936

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Metadata

Authors
Mitchell, S., Vorobyeva, E., & Pérez‐Ramírez, J.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2018-10-22
Volume
57
Issue
47
Pages
15316-15329
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2898000458
Cited by
348
References
149
FWCI
14.46
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: The Multifaceted Reactivity of Single‐Atom Heterogeneous Catalysts. https://app.cochat.ai/papers/10.1002/anie.201806936
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Mitchell, S., Vorobyeva, E., & Pérez‐Ramírez, J. (2018). The Multifaceted Reactivity of Single‐Atom Heterogeneous Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201806936

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