Roles of Water for Chemical Reactions in High-Temperature Water
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRoles of Water for Chemical Reactions in High-Temperature WaterNaoko Akiya and Phillip E. SavageView Author Information Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 Cite this: Chem. Rev. 2002, 102, 8, 2725–2750Publication Date (Web):June 21, 2002Publication History Received11 June 2001Published online21 June 2002Published inissue 1 August 2002https://pubs.acs.org/doi/10.1021/cr000668whttps://doi.org/10.1021/cr000668wresearch-articleACS PublicationsCopyright © 2002 American Chemical SocietyRequest reuse permissionsArticle Views11728Altmetric-Citations1300LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Hydrolysis,Kinetic parameters,Solvation,Solvents,Water Get e-Alerts
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Many acid- or base-catalyzed reactions are accelerated under HTL conditions.
“As a result, many acid- or base-catalyzed reactions are accelerated.28,29”
From The Impact of Sulfur-Containing Inorganic Compounds during the Depolymerization of Lignin by Hydrothermal Liquefaction of Black Liquor (2024) · cites this paper as [28]
Because of the high ionic product of water, a high H+ and OH- concentration is established in the HTL reaction medium, up to a factor of 1000 larger than at ambient conditions.
“Because of the high ionic product of water, Kw, a high H+ and OH– concentration is established in the reaction medium, up to a factor of 1000 larger than that at ambient conditions.”
From The Impact of Sulfur-Containing Inorganic Compounds during the Depolymerization of Lignin by Hydrothermal Liquefaction of Black Liquor (2024) · cites this paper as [28]
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- Authors
- Akiya, N., & Savage, P. E.
- Affiliations
- University of Michigan (US)
- Corresponding author
- Savage, Phillip E.
- ORCID
- Savage, Phillip E.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-06-21
- Volume
- 102
- Issue
- 8
- Pages
- 2725-2750
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2014025395
- Cited by
- 1,581
- References
- 1
- Citations by year
- 2026: 54 · 2025: 81 · 2024: 71 · 2023: 79 · 2022: 79 · 2021: 85 · 2020: 80 · 2019: 95 · 2018: 88 · 2017: 96 · 2016: 68 · 2015: 94 · 2014: 89 · 2013: 71 · 2012: 66
- FWCI
- 2.95
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Reviews (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Subcritical and Supercritical Water Processes
- Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- high-temperature water, water as solvent, hydrolysis, reaction kinetics, solvation, solvents, aqueous chemistry
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