The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Toward the Decentralized Electrochemical Production of H2O2: A Focus on the Catalysis
Open accessAbstract
H 2 O 2 is a valuable, environmentally friendly oxidizing agent with a wide range of uses from the provision of clean water to the synthesis of valuable chemicals. The on-site electrolytic production of H 2 O 2 would bring the chemical to applications beyond its present reach. The successful commercialization of electrochemical H 2 O 2 production requires cathode catalysts with high activity, selectivity, and stability. In this Perspective, we highlight our current understanding of the factors that control the cathode performance. We review the influence of catalyst material, electrolyte, and the structure of the interface at the mesoscopic scale. We provide original theoretical data on the role of the geometry of the active site and its influence on activity and selectivity. We have also conducted a series of original experiments on (i) the effect of pH on H 2 O 2 production on glassy carbon, pure metals, and metal–mercury alloys, and (ii) the influence of cell geometry and mass transport in liquid half-cells in comparison to membrane electrode assemblies.
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Cites
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Cited by
Highly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination
Jiang, K., Back, S., Akey, A. J., Xia, C., Hu, Y., Liang, W., Schaak, D., Stavitski, E., Nørskov, J. K., Siahrostami, S., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-11992-2 · Cited by 820
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Gao, J., Yang, H. B., Huang, X., Hung, S.-F., Cai, W., Jia, C., Miao, S., Chen, H. M., Yang, X., Huang, Y., et al. (2020) · Chem · doi:10.1016/j.chempr.2019.12.008 · Cited by 734
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Cation‐Vacancy‐Enriched Nickel Phosphide for Efficient Electrosynthesis of Hydrogen Peroxides
Zhou, Z., Kong, Y., Tan, H., Huang, Q., Wang, C., Pei, Z., Wang, H., Liu, Y., Wang, Y., Li, S., et al. (2022) · Advanced Materials · doi:10.1002/adma.202106541 · Cited by 325
Metadata
- Authors
- Yang, S., Verdaguer-Casadevall, A., Arnarson, L., Silvioli, L., Čolić, V., Frydendal, R., Rossmeisl, J., Chorkendorff, I., & Stephens, I. E. L.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-03-28
- Volume
- 8
- Issue
- 5
- Pages
- 4064-4081
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2795293472
- Cited by
- 1,215
- References
- 11
- FWCI
- 15.95
- Type
- journal article
- Language
- en
- Open access
- green
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