The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Photocatalytic Oxidative Dehydrogenation of Ethane Using CO2 as a Soft Oxidant over Pd/TiO2 Catalysts to C2H4 and Syngas
Abstract
Using CO 2 as the soft oxidant for the oxidative dehydrogenation of ethane (ODE) is a potential advancement for ethylene production from ethane. However, the current ODE reaction is primarily operated at high temperatures (e.g., 873 K), and the development of alternative approaches for the ODE reaction under the mild conditions is still a challenge. Herein, we report a photocatalytic ODE using CO 2 as the oxidant over Pd/TiO 2 catalysts at room temperature. The presence of CO 2 significantly promoted the production of C 2 H 4 and syngas, and the 1% Pd/TiO 2 catalyst exhibited a C 2 H 4 production rate of 230.5 μmol/g cat ·h and syngas of 282.6 μmol/g cat ·h. Density functional theory (DFT) calculation verified that the intermediate energy level provided by Pd and the covalent bond in Pd–O stimulated the electron transfer, excitation, and separation. The photoinduced electron, hole, and isolate OH on the surface of TiO 2 played essential roles during the whole process. In addition, the possible reaction pathways of photocatalytic ODE with CO 2 were proposed on the basis of the experimental data and DFT calculation results.
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Cites
Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides
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CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts
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XPS and FTIR Surface Characterization of TiO2Particles Used in Polymer Encapsulation
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Artificial Photosynthesis over Crystalline TiO2-Based Catalysts: Fact or Fiction?
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Cited by
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
Oxidative dehydrogenation of ethane: catalytic and mechanistic aspects and future trends
Najari, S., Saeidi, S., Concepcion, P., Dionysiou, D. D., Bhargava, S. K., Lee, A. F., & Wilson, K. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01518k · Cited by 293
Metadata
- Authors
- Zhang, R., Wang, H., Tang, S., Liu, C., Dong, F., Yue, H., & Liang, B.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-08-28
- Volume
- 8
- Issue
- 10
- Pages
- 9280-9286
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2889228279
- Cited by
- 299
- References
- 24
- FWCI
- 3.45
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, R., Wang, H., Tang, S., Liu, C., Dong, F., Yue, H., & Liang, B. (2018). Photocatalytic Oxidative Dehydrogenation of Ethane Using CO2 as a Soft Oxidant over Pd/TiO2 Catalysts to C2H4 and Syngas. ACS Catalysis. https://doi.org/10.1021/acscatal.8b02441
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