The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Surface Phases of TiO2 Nanoparticles Studied by UV Raman Spectroscopy and FT-IR Spectroscopy
Abstract
Surface phases of TiO 2 nanoparticles (30 ∼ 200 nm) were studied by UV Raman spectroscopy and FT-IR spectroscopy with CO and CO 2 as probe molecules. UV Raman spectroscopy can differentiate the surface phase structure of TiO 2 calcined at different temperatures. IR spectra of adsorbed CO and CO 2 on TiO 2 calcined at different temperatures are in good agreement with the results from UV Raman spectra. IR results evidently confirm that UV Raman spectroscopy is a surface-sensitive technique for TiO 2 . Both UV Raman and IR spectra indicate that the crystalline phase of TiO 2 in the surface region is usually different from that in the bulk which is characterized by XRD. CO is weakly adsorbed on Ti 4+ ions of anatase phase but is hardly adsorbed on those of rutile phase at room temperature. Adsorbed CO 2 on anatase phase produces mainly bidentate carbonate, while on rutile phase produces mainly bicarbonate species. These results suggest that the surface Lewis acidity of anatase phase is stronger than that of rutile phase, and the concentration of cus Ti 4+ -O 2- pairs on the surface of anatase phase is much higher than that on rutile phase; however, the basicity of surface OH groups of rutile phase is stronger than that of anatase phase.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Light-induced amphiphilic surfaces
Wang, R., Hashimoto, K., Fujishima, A., Chikuni, M., Kojima, E., Kitamura, A., Shimohigoshi, M., & Watanabe, T. (1997) · Nature · doi:10.1038/41233 · Cited by 3,384
HARUTA, M. (1989) · Journal of Catalysis · doi:10.1016/0021-9517(89)90034-1 · Cited by 3,185
Raman spectrum of anatase, TiO 2
Ohsaka, T., Izumi, F., & Fujiki, Y. (1978) · Journal of Raman Spectroscopy · doi:10.1002/jrs.1250070606 · Cited by 2,327
UV Raman Spectroscopic Study on TiO2. I. Phase Transformation at the Surface and in the Bulk
Zhang, J., Li, M., Feng, Z., Chen, J., & Li, C. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0552473 · Cited by 969
Self-citationBusca, G., & Lorenzelli, V. (1982) · Materials Chemistry · doi:10.1016/0390-6035(82)90059-1 · Cited by 942
Particle size effects on transformation kinetics and phase stability in nanocrystalline TiO2
Gribb, A. A., & Banfield, J. F. (1997) · American Mineralogist · doi:10.2138/am-1997-7-809 · Cited by 722
Surface chemistry of titania (anatase) and titania-supported catalysts
Hadjiivanov, K. I., & Klissurski, D. G. (1996) · Chemical Society Reviews · doi:10.1039/cs9962500061 · Cited by 591
Cited by
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Guo, Q., Zhou, C., Ma, Z., & Yang, X. (2019) · Advanced Materials · doi:10.1002/adma.201901997 · Cited by 1,909
Nanomaterials for renewable energy production and storage
Chen, X., Li, C., Grätzel, M., Kostecki, R., & Mao, S. S. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35230c · Cited by 1,015
Self-citationLiu, L., Zhao, H., Andino, J. M., & Li, Y. (2012) · ACS Catalysis · doi:10.1021/cs300273q · Cited by 870
Long, R., Li, Y., Liu, Y., Chen, S., Zheng, X., Gao, C., He, C., Chen, N., Qi, Z., Song, L., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00452 · Cited by 571
Artificial Photosynthesis over Crystalline TiO2-Based Catalysts: Fact or Fiction?
Yang, C.-C., Yu, Y.-H., van der Linden, B., Wu, J. C. S., & Mul, G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja101318k · Cited by 375
Metadata
- Authors
- Su, W., Zhang, J., Feng, Z., Chen, T., Ying, P., & Li, C.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-04-30
- Volume
- 112
- Issue
- 20
- Pages
- 7710-7716
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W1974904479
- Cited by
- 379
- References
- 32
- FWCI
- 5.66
- Type
- journal article
- Language
- en
- Open access
- closed
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