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ZnO As an Active and Selective Catalyst for Electrochemical Water Oxidation to Hydrogen Peroxide
Open accessAbstract
Electrochemical synthesis of hydrogen peroxide (H 2 O 2 ) via two-electron water oxidation reaction (2e-WOR) is an ideal process for delocalized production for water cleaning and other applications. Previously reported water oxidation catalysts have limited activity and selectivity, imposing a bottleneck for broad adoption of this technology. We identify ZnO as a new stable, nontoxic, active, and selective catalyst for 2e-WOR to generate H 2 O 2 . Using density functional theory calculations, we propose that the (10 1 0) facet of ZnO is an effective catalyst for 2e-WOR and confirm the prediction experimentally. We synthesize ZnO nanoparticles with a high fraction of (10 1 0) facets and find that this catalyst gives an overpotential of 40 mV at 0.1 mA/cm 2 and peak Faradaic efficiency of 81% toward H 2 O 2 evolution.
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Metadata
- Authors
- Kelly, S. R., Shi, X., Back, S., Vallez, L., Park, S. Y., Siahrostami, S., Zheng, X., & Nørskov, J. K.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-04-11
- Volume
- 9
- Issue
- 5
- Pages
- 4593-4599
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2936950634
- Cited by
- 298
- References
- 34
- FWCI
- 5.98
- Type
- journal article
- Language
- en
- Open access
- green
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