The DOI matches its Crossref record; 56 of the 56 references it cites were found in a registry or an index.
Monometallic Catalytic Models Hosted in Stable Metal–Organic Frameworks for Tunable CO2 Photoreduction
Abstract
The photocatalytic reduction of CO 2 to energy carriers has emerged as one of the most promising strategies to alleviate the energy crisis and CO 2 pollution, for which the development of catalyst was considered as the determining factor for the accomplishment of this conversion process. In this study, three stable and isostructural metal–organic frameworks (denoted as MOF-Ni, MOF-Co, and MOF-Cu ) have been synthesized and used as heterogeneous catalysts in photocatalytic CO 2 reduction reaction (CO 2 RR). It is worth noting that the MOF-Ni exhibited very high selectivity of 97.7% for photoreducing CO 2 to CO, which has exceeded most of the reported MOF-based catalysts in the field. Significantly, the MOFs associated with a monometallic catalytic center offer a simple and precise structural model which allows us to understand more definitively the specific effects of different metal-ion species on photoreduction of CO 2 as well as the reactive mechanism.
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Cited by
Recent progress in metal-organic frameworks-based hydrogels and aerogels and their applications
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Metadata
- Authors
- Wang, X.-K., Liu, J., Zhang, L., Dong, L.-Z., Li, S.-L., Kan, Y.-H., Li, D.-S., & Lan, Y.-Q.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-01-15
- Volume
- 9
- Issue
- 3
- Pages
- 1726-1732
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2908934650
- Cited by
- 384
- References
- 56
- FWCI
- 12.47
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, X.-K., Liu, J., Zhang, L., Dong, L.-Z., Li, S.-L., Kan, Y.-H., Li, D.-S., & Lan, Y.-Q. (2019). Monometallic Catalytic Models Hosted in Stable Metal–Organic Frameworks for Tunable CO2 Photoreduction. ACS Catalysis. https://doi.org/10.1021/acscatal.8b04887
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