The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
[Ti8Zr2O12(COO)16] Cluster: An Ideal Inorganic Building Unit for Photoactive Metal–Organic Frameworks
Open accessAbstract
High Resolution Image Download MS PowerPoint Slide Metal–organic frameworks (MOFs) based on Ti-oxo clusters (Ti-MOFs) represent a naturally self-assembled superlattice of TiO 2 nanoparticles separated by designable organic linkers as antenna chromophores, epitomizing a promising platform for solar energy conversion. However, despite the vast, diverse, and well-developed Ti-cluster chemistry, only a scarce number of Ti-MOFs have been documented. The synthetic conditions of most Ti-based clusters are incompatible with those required for MOF crystallization, which has severely limited the development of Ti-MOFs. This challenge has been met herein by the discovery of the [Ti 8 Zr 2 O 12 (COO) 16 ] cluster as a nearly ideal building unit for photoactive MOFs. A family of isoreticular photoactive MOFs were assembled, and their orbital alignments were fine-tuned by rational functionalization of organic linkers under computational guidance. These MOFs demonstrate high porosity, excellent chemical stability, tunable photoresponse, and good activity toward photocatalytic hydrogen evolution reactions. The discovery of the [Ti 8 Zr 2 O 12 (COO) 16 ] cluster and the facile construction of photoactive MOFs from this cluster shall pave the way for the development of future Ti-MOF-based photocatalysts.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Li, H., Eddaoudi, M., O'Keeffe, M., & Yaghi, O. M. (1999) · Nature · doi:10.1038/46248 · Cited by 8,554
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,310
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8057953 · Cited by 7,336
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
Furukawa, H., Gándara, F., Zhang, Y.-B., Jiang, J., Queen, W. L., Hudson, M. R., & Yaghi, O. M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500330a · Cited by 2,888
Zr-based metal–organic frameworks: design, synthesis, structure, and applications
Bai, Y., Dou, Y., Xie, L.-H., Rutledge, W., Li, J.-R., & Zhou, H.-C. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00837a · Cited by 2,545
Self-citationMetal–organic frameworks for artificial photosynthesis and photocatalysis
Zhang, T., & Lin, W. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00103f · Cited by 2,163
O’Keeffe, M., & Yaghi, O. M. (2012) · Chemical Reviews · doi:10.1021/cr200205j · Cited by 2,143
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Wang, C.-C., Wang, X., & Liu, W. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.123601 · Cited by 258
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Metadata
- Authors
- Yuan, S., Qin, J.-S., Xu, H.-Q., Su, J., Rossi, D., Chen, Y., Zhang, L., Lollar, C., Wang, Q., Jiang, H.-L., Son, D. H., Xu, H., Huang, Z., Zou, X., & Zhou, H.-C.
- Venue
- ACS Central Science
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-11-29
- Volume
- 4
- Issue
- 1
- Pages
- 105-111
- ISSN
- 2374-7943 (ISSN-L)
- 2374-7951
- OpenAlex
- W2770232639
- Cited by
- 265
- References
- 37
- FWCI
- 9.54
- Type
- journal article
- Language
- en
- Open access
- diamond
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- Yuan, S., Qin, J.-S., Xu, H.-Q., Su, J., Rossi, D., Chen, Y., Zhang, L., Lollar, C., Wang, Q., Jiang, H.-L., Son, D. H., Xu, H., Huang, Z., Zou, X., & Zhou, H.-C. (2018). [Ti8Zr2O12(COO)16] Cluster: An Ideal Inorganic Building Unit for Photoactive Metal–Organic Frameworks. ACS Central Science. https://doi.org/10.1021/acscentsci.7b00497
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