The DOI matches its Crossref record; 96 of the 96 references it cites were found in a registry or an index.
Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions
Open accessAbstract
or using artificial oxidants at iron and manganese centers supported on heme or nonheme-type ligand environments. Detailed reactivity studies together with spectroscopy and theory have helped us understand how the reactivities of these metal-oxygen intermediates are controlled by the electronic and steric properties of the metal centers. These studies have provided important insights into biological reactions, which have contributed to the design of biologically inspired oxidation catalysts containing earth-abundant metals like iron and manganese. In this Outlook article, we survey a few examples of these advances with particular emphasis in each case on the interplay of catalyst design and our understanding of metalloenzyme structure and function.
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1 retracted
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RetractedCatalytic Asymmetric Dihydroxylation
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Equilibrium acidities in dimethyl sulfoxide solution
Bordwell, F. G. (1988) · Accounts of Chemical Research · doi:10.1021/ar00156a004 · Cited by 2,874
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
Meunier, B. (1992) · Chemical Reviews · doi:10.1021/cr00014a008 · Cited by 2,090
Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes
Solomon, E. I., Brunold, T. C., Davis, M. I., Kemsley, J. N., Lee, S.-K., Lehnert, N., Neese, F., Skulan, A. J., Yang, Y.-S., & Zhou, J. (2000) · Chemical Reviews · doi:10.1021/cr9900275 · Cited by 1,713
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Heme Enzyme Structure and Function
Poulos, T. L. (2014) · Chemical Reviews · doi:10.1021/cr400415k · Cited by 1,443
Biologically inspired oxidation catalysis
Que, L., & Tolman, W. B. (2008) · Nature · doi:10.1038/nature07371 · Cited by 1,419
Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics
Rittle, J., & Green, M. T. (2010) · Science · doi:10.1126/science.1193478 · Cited by 1,368
Zhang, W., Lai, W., & Cao, R. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00299 · Cited by 1,322
Metadata
- Authors
- Guo, M., Corona, T., Ray, K., & Nam, W.
- Venue
- ACS Central Science
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-12-18
- Volume
- 5
- Issue
- 1
- Pages
- 13-28
- ISSN
- 2374-7943 (ISSN-L)
- 2374-7951
- OpenAlex
- W2904788895
- Cited by
- 401
- References
- 96
- FWCI
- 13.79
- Type
- journal article
- Language
- en
- Open access
- diamond
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- CoChat. (2026). Citation check: Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions. https://app.cochat.ai/papers/10.1021/acscentsci.8b00698
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- Guo, M., Corona, T., Ray, K., & Nam, W. (2019). Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions. ACS Central Science. https://doi.org/10.1021/acscentsci.8b00698
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