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Phosphorus and Aluminum Codoped Porous NiO Nanosheets as Highly Efficient Electrocatalysts for Overall Water Splitting
Open accessAbstract
We present a facile way to fabricate phosphorus and aluminum codoped nickel oxide-based nanosheets by using layered double hydroxide (AlNi-LDH) as precursors, which showed an overall water-splitting performance in alkaline solution. The codoping of phosphorus and aluminum into nickel oxide nanosheets leads to an optimum balance among surface chemical state, electrochemically active surface area, and density of active sites. As a result, it can afford a current density of 100 mA cm –2 at the overpotential of 310 mV for oxygen evolution reaction (OER) and a current density of 10 mA cm –2 at the overpotential of 138 mV for hydrogen evolution reaction (HER) in 1 M KOH. When it was used as a bifunctional catalyst in a two-electrode water-splitting device, a potential of 1.56 V was achieved at the current density of 10 mA cm –2 .
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“Fig. 4d showed that the characteristic peaks of P 2p at”
From Phosphorus doped nickel-molybdenum aerogel for efficient overall water splitting (2021) · cites this paper as [53]
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From Phosphorus doped nickel-molybdenum aerogel for efficient overall water splitting (2021) · cites this paper as [41]
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Metadata
- Authors
- Li, Z., Niu, W., Zhou, L., & Yang, Y.
- Affiliations
- University of Central Florida (US)
- Corresponding author
- Yang, Yang
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-03-15
- Volume
- 3
- Issue
- 4
- Pages
- 892-898
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2790018515
- Cited by
- 162
- References
- 58
- Citations by year
- 2026: 10 · 2025: 12 · 2024: 11 · 2023: 18 · 2022: 18 · 2021: 28 · 2020: 27 · 2019: 28 · 2018: 10
- FWCI
- 5.36
- Type
- journal article
- Language
- en
- Open access
- Locations
- ACS Energy Letters (publishedVersion)
- Journal of International Crisis and Risk Communication Research (submittedVersion)
- Funders
- University of Central Florida (20080741)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Keywords
- nickel oxide nanosheets, layered double hydroxide precursor, overall water splitting, oxygen evolution reaction, hydrogen evolution reaction, bifunctional electrocatalysts, alkaline electrocatalysis, active site density, electrochemically active surface area
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