Heteroatom-Doped Transition Metal Electrocatalysts for Hydrogen Evolution Reaction

Combining theory and experiment in electrocatalysis: Insights into materials design

Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114

Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions

Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388

Improved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site Availability

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A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions

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Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts

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Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts

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Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution

Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D. C. B., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., et al. (2013) · Nature Materials · doi:10.1038/nmat3700 · Cited by 2,641

Emerging Two-Dimensional Nanomaterials for Electrocatalysis

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Energy and fuels from electrochemical interfaces

Stamenković, V. R., Strmcnik, D. S., Lopes, P. P., & Marković, N. M. (2016) · Nature Materials · doi:10.1038/nmat4738 · Cited by 2,039

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000

Probing the effect of isomeric -OH group in heteroleptic Copper(I)-triphenylphosphine appended dithiocarbamates on their electrocatalytic properties for homogeneous hydrogen evolution reactions

Daniel, O., Kushwaha, A., Srivastava, S., Muddassir, M., Kociok-Köhn, G. I., & Kumar, A. (2025) · Inorganica Chimica Acta · doi:10.1016/j.ica.2025.122802 · Cited by 3

Improving the electrocatalytic activity of Fe/Co-8-16-4 graphyne through sulfur or phosphorus doping for water splitting

Jafari, G., & Reisi‐Vanani, A. (2025) · Journal of Power Sources · doi:10.1016/j.jpowsour.2025.238579 · Cited by 3

Enhanced electrocatalytic oxygen evolution performance via amorphous–crystalline CoFeB@CTF heterostructure

Shi, L., Li, R., He, S., Hao, Y., Li, X., Wang, H., Pei, H., Guo, R., Liu, N., & Mo, Z. (2026) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2026.186441 · Cited by 3

Modification strategies of metal organic framework-derived tungsten-based electrocatalysts for hydrogen evolution

Gao, H., Ma, Z., Wang, C., Zhang, L., & Zhang, Y. (2026) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2026.187219 · Cited by 4

Emerging strategies for designing MoSe 2 -based electrocatalysts for renewable hydrogen technologies

Gautham Kumar, G., Sahoo, S., Etacheri, V., & Kundu, A. (2026) · Journal of Materials Chemistry A · doi:10.1039/d6ta01182a · Cited by 3

Fluorine-modulated heteroatom interactions in boron imidazolate frameworks enabling efficient water electrolysis

Abid, K., Dilpazir, S., Imran, M., Arif, S., Usman, M., Suliman, M. H., & Khan, A. (2026) · Journal of Power Sources · doi:10.1016/j.jpowsour.2026.240146 · Cited by 3

Insights into the state-of-the-art advancements in morphology and electronic structure engineering on cobalt diselenide-based nanomaterials for hydrogen evolution reaction

Bui, T. H., Nguyen, T. A. N., Bui, V. K. H., Nguyen, H. D., Tran, V. V., & Huu, H. (2025) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2025.150049 · Cited by 3

Facile and Cost‐effective Synthesis of CoP@N‐doped Carbon with High Catalytic Performance for Electrochemical Hydrogen Evolution Reaction

Yang, X., Shu, Y., Takada, R., Taniguchi, Y., Miyake, K., Uchida, Y., & Nishiyama, N. (2023) · Chemistry - An Asian Journal · doi:10.1002/asia.202300534 · Cited by 3

Induction heating boosts water splitting on iron–coated nickel foam

Li, T., Kang, S., Li, S., Yang, W., Lei, W., Lu, W., Li, Z., Zhu, D., Zhang, X., & Lei, P. (2024) · Journal of Physics D Applied Physics · doi:10.1088/1361-6463/ad816d · Cited by 3

An archetype of the electron-unobstructed core–shell composite with inherent selectivity: conductive metal–organic frameworks encapsulated with metal nanoparticles

Si, X., Zhao, H., Yi, B., Zhou, L., Ling, Y., An, Y., Wang, Y., Lee, H. K., Tsung, C., Ma, Y., et al. (2022) · Nanoscale · doi:10.1039/d2nr02681c · Cited by 3

Recent advances in nanostructured nonoxide materials—Borides, borates, chalcogenides, phosphides, phosphates, nitrides, carbides, alloys, and metal-organic frameworks

Bezerra, L. S., Martini, B. K., Cardoso, E. S. F., Fortunato, G. V., & Maia, G. (2022) · Elsevier eBooks · doi:10.1016/b978-0-12-823936-0.00011-5 · Cited by 3

Hydrogen production via water electrolysis on an active electrocatalyst rGONi nanocomposite

Kayan, D. B. (2022) · International Journal of Chemistry and Technology · doi:10.32571/ijct.1199967 · Cited by 2

Metal and Metal Oxide-based Electrocatalysts for the Hydrogen Evolution Reaction

Pallilavalappil, S., Jabeen, S., V., S., Animasree, V. P., Manoj, N., John, H., & Pillai, S. C. (2024) · Royal Society of Chemistry eBooks · doi:10.1039/9781837674664-00336 · Cited by 2

Boosting Water Dissociation Kinetics on GaOOH Nanosheets by Transition Metal Doping

Yan, Z., Zhang, Y., Wang, M., Chen, K.-S., Zhang, S., Chen, Y., Liu, H., & Li, J. (2025) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5c18600 · Cited by 2

g-C3N4 based mixed metal/semiconductor heterojunction nanocomposites towards photocatalytic water splitting for hydrogen production: A review

Ayοdhya, D. (2025) · Review of Materials Research · doi:10.1016/j.revmat.2025.100116 · Cited by 2

Self-supported electrodes for efficient water splitting: Integrating wettability with multidimensional engineering

Mu, L., Liu, Q., Li, J., Liu, H., Feng, P., Zhang, Y., He, J., & Qu, M. (2025) · Materials Today Physics · doi:10.1016/j.mtphys.2025.101977 · Cited by 2

The breakthrough of carbon-supported ruthenium catalysts in hydrogen evolution reaction: the "dual engines" of design and synthesis

Liu, Z.-L., Liu, B.-C., Hai-qin, F., Zhao, S., Wang, P., & Yi, T. (2025) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2025.116622 · Cited by 2

Self-supported rod-like Mo-Ni3S2 loaded nanosheet arrays for efficient urea oxidation-assisted hydrogen production

Li, J., Meng, X., Qi, X., & Fang, Y. (2026) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2026.120103 · Cited by 2

Modified Co electronic states in double-anionic CoPS nanocrystals induce highly efficient electrocatalytic hydrogen evolution

Wang, K., Liu, S., Mao, K., Chu, Z., Wang, Y., Chen, J., Yan, S., Dai, J., Niu, X., & Wu, X. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.166114 · Cited by 2

Mild and Fast Construction of Ni-Based Electrodes for Industrial-Grade Water Splitting

Lu, Z., Liang, R., Shao, Y., & Hao, W. (2023) · Inorganics · doi:10.3390/inorganics11040170 · Cited by 2

Efficiently triggering ordered and stable oxidation active sites on Ni-based interfaces by coordination with nitrogen family anions for glycerol electrolysis

Yan, Y., Liu, Q., Zhao, Y., Feng, Y., Wang, D., Schaaf, P., Guo, G., & Wang, X. (2025) · Materials Today Energy · doi:10.1016/j.mtener.2025.101874 · Cited by 2

Metal-supported cathodically activated graphite via self-reduction as electrocatalysts for efficient hydrogen evolution reaction

Yu, H., & Ghilane, J. (2022) · Materials Today Chemistry · doi:10.1016/j.mtchem.2022.101099 · Cited by 3

Identification and Optimization of Spinel Oxide Geometric Configurations for Enhanced C−N Coupling Reaction

Jiang, Y., Duan, C., Shang, Y., Chen, D., Zhou, Y., & Chen, C. (2025) · ChemCatChem · doi:10.1002/cctc.202500545 · Cited by 1

Multi-phase heterostructure of NiCoP/WP/Co2P4O12 for promoted alkaline hydrogen evolution activity

Song, L., Li, R., Yang, Z., Zhu, Z., Yuan, B., Ni, T., Chen, C., Yu, H., & Jin, R. (2026) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2026.119911 · Cited by 1

Construction of cobalt–cobalt oxide/N-doped carbon hybrids with regulated interfaces to boost the electrocatalytic hydrogen evolution in alkali medium

Fu, L., Gan, Q., Hao, H., Shi, C., & Jia, J.-G. (2026) · Journal of Physics and Chemistry of Solids · doi:10.1016/j.jpcs.2026.113627 · Cited by 1

Fine modulating the D-band center of Co3N nanozyme for efficient oxidative degradation of emerging organic contaminants

Wang, M., Zheng, Y., Zhang, J., Ren, Y., Gao, W., 商宁昭, Zhang, J., Gao, S., An, Z., & Wang, C. (2026) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2026.126683 · Cited by 1

Cobalt-dopant modulated surface dynamic reconstruction of nickel molybdate for accelerated oxygen evolution

Jiang, R., Liu, J., Zhang, J., Liu, J., Yuan, S., Chen, X., & Xie, Y. (2026) · Applied Surface Science · doi:10.1016/j.apsusc.2026.166826 · Cited by 1

Precision Atomic Doping of Nanoalloy Electrocatalysts: Unlocking New Paths for Efficient Hydrogen Evolution Reaction

Li, K., Chen, T., Zhang, S., Su, S., Liu, M., Xie, H., Cui, H., Qie, Y., Nie, X., & Yan, Y. (2026) · Advanced Energy Materials · doi:10.1002/aenm.71156 · Cited by 1

Atomic precision unleashed: Single-atom catalysts revolutionizing electrocatalytic hydrogen evolution reaction

Saini, A., Saini, K., Gotharwal, G., Kaliyaperumal, A., Pathak, S., & Bhalothia, D. (2026) · Results in Engineering · doi:10.1016/j.rineng.2026.112491 · Cited by 1

Magnetic enhancement effect and research progress in oxygen evolution reaction

Hu, H., Junming, L., Sun, L., Xu, F., Huang, P., Peng, H., Zou, Y., Chu, H., & Zhang, H. (2023) · Chinese Science Bulletin (Chinese Version) · doi:10.1360/tb-2022-1133 · Cited by 1

Trifunctional Electrocatalysts for the Hydrogen Evolution Reaction (HER), Oxygen Evolution Reaction (OER), and Urea Oxidation Reaction (UOR)

Pataniya, P. M., Shah, A., Sharma, P. J., & Sumesh, C. K. (2024) · Royal Society of Chemistry eBooks · doi:10.1039/9781837674497-00434 · Cited by 1

Highly porous single-phase rhombohedral Cr Rh2−O3 nanofibers expediting oxygen evolution reaction

Kwon, T., Kim, K., Prabhakaran, S., Choi, S., Kim, J., Yim, Y., Park, J., Moon, H. R., Kim, M. H., Kim, D. H., et al. (2025) · Applied Surface Science Advances · doi:10.1016/j.apsadv.2025.100789 · Cited by 1

Boosting alkaline hydrogen evolution kinetics in CoP via high-valence ion doping for anion exchange membrane electrolyzers

Zhang, S., Wang, Z., Ma, S., Cao, Z., Liu, F., Li, Y., Xu, X., Ma, Y., Xue, Y., Tang, C., et al. (2025) · Chinese Chemical Letters · doi:10.1016/j.cclet.2025.111785 · Cited by 1

Synthesis of Co 2 P Nanoparticles Embedded N, P Co‐Doped Mesoporous Carbon via Molten Salt Process as Hydrogen Evolution Electrocatalyst under Alkaline Conditions

Xu, J., Bi, X., Tang, D., Zhang, W., Xin, S., Guan, B., & Zhao, Z. (2022) · ChemistrySelect · doi:10.1002/slct.202202944 · Cited by 1

Spin-State Controlled Atomically Precise Catalysts for Efficient Oxygen Evolution Reaction Design and Mechanism

Li, J., Wang, K., Zheng, C., & Li, J. (2024) · Springer eBooks · doi:10.1007/978-3-031-54622-8_13 · Cited by 1

Electrocatalytic hydrogen evolution performance of mesoporous Ni/NiO/carbon composites fabricated from carbon dotsPreprint

Yang, Y., Liu, R., Liu, W., Ji, L., Gao, M., & Zhai, Y. (2024) · ChemRxiv · doi:10.26434/chemrxiv-2024-vgzp3 · Cited by 1

Controllable preparation of noble metal-based nanomaterials for electrocatalytic hydrogen evolution reaction

Li, Y. (2024) · DR-NTU (Nanyang Technological University) · doi:10.32657/10356/179769 · Cited by 1

Nanoporous Ni-Al alloy by De-alloying for Electrocatalytic hydrogen Evolution Reaction

Zhou, Q., Luo, Y., Liu, H., Feng, J., Huang, G., Wang, D., & Fu, H. (2021) · IOP Conference Series Earth and Environmental Science · doi:10.1088/1755-1315/639/1/012002

Exploration of Ni-P-Based Catalytic Electrodes for Hydrogen Evolution Reaction

Ameen Sha, M., & Meenu, P. (2021) · Advances in computer and electrical engineering book series · doi:10.4018/978-1-7998-4945-2.ch003

Trifunctional Electrocatalysts

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Potassium electrochemical optimization of the MoS 2 catalytic hydrogen evolution reaction performance

Feng, S., Tu, Y., Zhang, Q., Xie, L., Liu, S., Wang, L., & Zhao, Q. (2025) · Chemical Communications · doi:10.1039/d5cc01053e

Magnetic Ni-N-Ni Centers in N-substituted NiO

Godin, S., Elfimov, I., Li, F., Davidson, B. A., Sutarto, R., Denlinger, J. D., Tjeng, L. H., Sawatzky, G. A., & Zou, K. (2025) · Physical Review Letters · doi:10.1103/mp1d-jg6c

Phosphorus-Promoted VS 2 Nanosheets: Unlocking Defect Engineering and Interlayer Modulation for Enhanced Hydrogen Evolution Reaction

Shyma, A. P., & Sellappan, R. (2025) · ACS Omega · doi:10.1021/acsomega.5c04904

p-d orbital hybridization induced by carbon-doped of nickel sulfides for enhanced hydrogen evolution reaction

Xu, X., Wei, H., Luo, Q., Chu, H., Liu, X., Jiang, Y., Zhu, Y., Zhang, L., Zhang, M., Yan, S., et al. (2026) · Applied Surface Science · doi:10.1016/j.apsusc.2026.166206

Engineering a high-performance amorphous/crystalline electrocatalyst from Rosa roxburghii pomace for ultra-stable alkaline hydrogen evolution reaction

Zhou, S., Liu, F., Ren, Q., Wang, H., & Wang, X. (2026) · Industrial Crops and Products · doi:10.1016/j.indcrop.2026.122894

Neighborhood environment modulation and dynamic reconstruction of metallic Fe by S and Co for efficient alkaline water splitting

Song, X., Fan, C., Zang, Z., Tang, Y., Ren, Y., Li, L., Yu, X., Yang, X., Lu, Z., & Zhang, X. (2026) · Materials Today Chemistry · doi:10.1016/j.mtchem.2026.103449

Mechanochemical fabrication of S, O co-doped Cu for hydrogen evolution reaction

Lv, W., Cheng, C.-Q., Ma, Z.-A., Xiao, L.-Y., Shuai, L., Zhang, J., Han, C. L., Li, X., Zhang, R., Yang, J., et al. (2026) · Acta Materialia · doi:10.1016/j.actamat.2026.122089

A methodical comparative analysis of the improved dechlorination of trichloroethylene (TCE) using C-, N-, and S-modified zero-valent iron (ZVI)

Luo, X., Chen, H., Shen, H., Zhang, L., Chen, J., Liu, S., Gao, B., Zhang, H., & Gu, Y. (2026) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2026.109888

Bifunctional enhancement via geometry and electronic effects of Co-Nx sites enables durable ORR catalysts in Zn-air battery

Zeng, M., Shi, H., Cui, W., Wu, X., Liang, S., Wang, W., Akbarjon, N., & Xu, Z. (2026) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2026.187371

Synthèse et caractérisation de matériaux à base de MXène : application à l'électrolyse de l'eau en milieu alcalin

Loupias, L. (2022) · theses.fr (ABES) · doi:10.70675/c7af8ae1z4111z4c7bz886az76ec49b4ea26

Engineering active sites for electrocatalytic energy conversion reactions

Hu, M., Zhao, D., Wei, D., Gan, L., Li, M., Du, L., Zhou, M., Zhang, L., Wang, L., Yan, X., et al. (2026) · Chemical Physics Reviews · doi:10.1063/5.0266768

Hydrogen evolution reaction: Ultra-thin defect-rich Pd metallenes

Subhan, C. M., Amini, M., Hassan, D., & Javed, M. H. (2026) · Next Materials · doi:10.1016/j.nxmate.2026.102187

Advances in chalcogenide-doped g-C3N4 photocatalysts for H2 evolution, CO2 reduction, and environmental remediation

Sahil, Kumar, N., Sharma, A., Tahir, M. D., Nguyen, T.-B., Priyanka, Singh, P., Mittal, A. K., & Sharma, S. (2026) · Inorganic Chemistry Communications · doi:10.1016/j.inoche.2026.117101

Unraveling the Kinetic Role of Doping in the Oxygen Evolution Reaction on Ce–Mn 3 O 4 Electrocatalysts

Wei, R., Li, D., Zhang, Y., Zhang, P., Zhang, J., Ge, Y., Cheng, Z., Ni, C., Sun, F., Min, Z., et al. (2026) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6c01342

Two‐Dimensional Quaternary Alloys of (RuMoVNb)Se 2 for Superior Hydrogen Evolution Reaction Catalysis

Ihsan, J., Kim, J. Y., Mishal, I., Choi, J. H., An, J. E., Choi, Y. J., Kim, D., Kwak, I. H., Vilé, G., Kwon, I. S., et al. (2026) · Advanced Science · doi:10.1002/advs.76600

Boron and nitrogen dual-doping of nickel electrocatalyst for efficient oxygen evolution and urea oxidation

Niu, X., Zheng, Z., Xu, L., Liu, T., & Xiang, J. (2026) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2026.190065

Twist-Angle-Dependent Electrocatalytic Activation of Basal Plane MoS2 in Twisted Bilayer Structures

Chen, Y., Zhang, H., Lu, H., Li, X., Huang, Z., & Yan, M. (2026) · Materials · doi:10.3390/ma19153211

Mo doping of perovskite oxide: an innovative pathway for high-performance hydrogen evolution reaction

Haggam, R. A., Tawfik, S. G., Maati, L. A. E., El‐Rayyes, A., Kumar, A., Sawwan, H., Hassan, R. U., & Fatima, S. (2026) · Chemical Papers · doi:10.1007/s11696-026-05038-3

Asymmetric electronic regulation via N/Ce surface modification of NiMoOx for persistent overall water splitting

Zheng, M., Xuan, H., Yang, Z., & Cheng, L. (2026) · Applied Surface Science · doi:10.1016/j.apsusc.2026.168016

A Ni-Doped Molybdenum Carbide Heterojunction Catalyst for Enhanced Hydrogen Evolution Reaction

Shen, X., Li, W., Qiu, W., Tang, M., Tang, M., Li, W., & Wang, D. (2026) · ACS Applied Energy Materials · doi:10.1021/acsaem.6c01369

Efficient Hydrazine‐Assisted Hydrogen Production via Tailoring Electron Injection Into Metallic Co Sites

Feng, Z., Qi, S., Liu, H., Meng, H., Mu, J., Zhang, Z., Gao, B., Lu, X., & Zhu, H. (2026) · Advanced Functional Materials · doi:10.1002/adfm.77323

Synergistic Regulation of Geometric and Electronic Structures in Embedded Ni Catalysts via Halogen-Doped Carbon Dots for Efficient Selective Hydrogenation

Ma, C., Huang, H., Liu, Y., Yao, Y., He, W., Jin, X., Yu, J., Wan, D., Xiang, Z., Zhou, Y., et al. (2026) · ACS Catalysis · doi:10.1021/acscatal.6c04828

Sodium citrate-ammonia regulated stepwise electrodeposition of self-supported NiCu electrocatalyst for highly efficient HMF electrooxidation to FDCA

Gao, H., & Chen, J. (2026) · Electrochimica Acta · doi:10.1016/j.electacta.2026.149915

Surface-Reconstructed Phosphorus-Doped CuFe Oxide Nanostructures for Energy-Efficient Methanol-Assisted Water ElectrolysisPreprint

Manivannan, S., & Kumar, R. (2026) · SSRN Electronic Journal · doi:10.2139/ssrn.7512565

Different percentages of metal doping in lithium titanate for the enhancement of electrochemical water splitting

Hossain, M. S., Abedin, R., Akhtar, U. S., & Ahmed, S. (2026) · RSC Advances · doi:10.1039/d6ra06927d

Synergistic effects of metallic and non-metallic element-doped electrocatalysts for the hydrogen evolution reaction: a review

Yesupatham, M. S., Murugesan, R., Richard, D., Radhakrishnan, A., & Maruthapillai, A. (2026) · Nanoscale · doi:10.1039/d5nr04327a · Cited by 19

Nonmetal Doping as a Robust Route for Boosting the Hydrogen Evolution of Metal‐Based Electrocatalysts

Hu, Q. L., Li, G., Han, Z., Wang, Z., Huang, X., Yang, H., Zhang, Q., Liu, J., & He, C. (2019) · Chemistry - A European Journal · doi:10.1002/chem.201902998 · Cited by 26

Role and advances in nonmetal doping of electrocatalysts for the hydrogen evolution reaction: a review

Xu, S., Liu, C., Teng, Z., Sun, F., Chi, J., Liu, X., Lai, J., Liu, F., & Wang, L. (2025) · Inorganic Chemistry Frontiers · doi:10.1039/d5qi00376h · Cited by 21

Fe‐Doped NiCoP Prussian Blue Derivatives for Alkaline Electrocatalytic Hydrogen Evolution

Zhang, C., Han, J., Hou, P., Zheng, T., Li, A., Zhou, Y., Xu, D., Meng, X., Wang, X., & Li, N. (2026) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.70363 · Cited by 2

Understanding the doping effect on hydrogen evolution activity of transition-metal phosphides: Modeled with Ni2P

Xiong, L., Wang, B., Cai, H., Hao, H., Li, J., Yang, T., & Yang, S. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120283 · Cited by 170