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Ni2P Aerogels with Pt Single-Atom Doping Tune Competitive Adsorption for Boosted Methanol Electrooxidation
Abstract
Methanol oxidation reaction (MOR) provides an effective method to attain high-value-added chemicals. Nevertheless, the competitive adsorption between CH 3 OH and OH – causes poor activity and selectivity. In this work, Ni 2 P aerogels decorated with single-atom Pt are designed to tune the adsorption behavior of CH 3 OH and OH –, achieving an unprecedented current density of 2848.3 A g cat –1 and a Faradaic efficiency of 93.3% for formic acid. A series of electrochemical tests, operando spectroscopic characterizations, and theoretical calculations verify that Pt single-atom doping not only accelerates the adsorption of CH 3 OH and realizes high coverage of CH 3 OH on Ni active sites to impede the OER, but it also decreases the barrier of the rate-determining step, achieving a high-efficiency MOR. Specifically, an underlying competitive adsorption mechanism between CH 3 OH and OH – to enhance MOR is proposed. This work is highly instructive for developing promising and efficient electrocatalysts at the atomic scale and contributing to a deeper understanding of the MOR mechanism.
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Loading Pt onto substrates with large specific surface areas is an effective solution to inhibit Pt aggregation.
“Loading Pt onto substrates with large specific surface areas (e.g., lamellar Ni(OH)2 [13], Ni2P aerogel [14], and Mxene [15]) is an effective solution to inhibit Pt aggregation.”
From Synergistic interaction of monodisperse Pt nanoparticles with defect‐rich graphene aerogel for efficient acidic hydrogen evolution (2025) · cites this paper as [14]
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Cites
Unveiling the Electrooxidation of Urea: Intramolecular Coupling of the N−N Bond
Chen, W., Xu, L., Zhu, X., Huang, Y., Wang, Z., Wang, D., Zhou, Y., Du, S., Li, Q., Xie, C. Y., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202015773 · Cited by 541
Qi, Y., Zhang, Y., Li, Y., Zhao, Y., Zhu, Y., Jiang, H., & Li, C. (2022) · Nature Communications · doi:10.1038/s41467-022-32443-5 · Cited by 507
Zhu, J., Xia, L., Yu, R., Lu, R., Li, J., He, R., Wu, Y., Zhang, W., Hong, X., Chen, W., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c03982 · Cited by 389
Toward Electrocatalytic Methanol Oxidation Reaction: Longstanding Debates and Emerging Catalysts
Wang, J., Zhang, B., Guo, W., Wang, L., Chen, J., Pan, H., & Sun, W. (2023) · Advanced Materials · doi:10.1002/adma.202211099 · Cited by 347
Li, S., Ma, R., Hu, J., Li, Z., Liu, L., Wang, X., Lu, Y., Sterbinsky, G. E., Liu, S., Zheng, L., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-30670-4 · Cited by 343
Self-citationYe, F., Zhang, S., Cheng, Q., Long, Y., Liu, D., Paul, R., Fang, Y., Su, Y., Qu, L., Dai, L., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-37679-3 · Cited by 325
Boosting urea electrooxidation on oxyanion-engineered nickel sites via inhibited water oxidation
Gao, X., Bai, X., Wang, P., Jiao, Y., Davey, K., Zheng, Y., & Qiao, S.-Z. (2023) · Nature Communications · doi:10.1038/s41467-023-41588-w · Cited by 306
High‐Performance Bismuth‐Doped Nickel Aerogel Electrocatalyst for the Methanol Oxidation Reaction
Dubale, A. A., Zheng, Y., Wang, H., Hübner, R., Li, Y., Yang, J., Zhang, J., Sethi, N. K., He, L., Zheng, Z., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202004314 · Cited by 296
Self-citationLi, Y., Peng, C.-K., Hu, H., Chen, S.-Y., Choi, J.-H., Lin, Y.-G., & Lee, J.-M. (2022) · Nature Communications · doi:10.1038/s41467-022-28805-8 · Cited by 291
Single Iridium Atom Doped Ni 2 P Catalyst for Optimal Oxygen Evolution
Wang, Q., Zhang, Z., Cai, C., Wang, M., Zhao, Z. L., Li, M., Huang, X., Han, S., Zhou, H., Feng, Z., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c04682 · Cited by 279
Single-atom catalyst for high-performance methanol oxidation
Zhang, Z., Liu, J., Wang, J., Wang, Q., Wang, Y., Wang, K., Wang, Z., Gu, M. D., Tang, Z., Lim, J., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-25562-y · Cited by 276
Liu, G., Zhou, W., Ji, Y., Chen, B., Fu, G., Yun, Q., Chen, S., Lin, Y., Yin, P., Cui, X., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05856 · Cited by 266
High‐Entropy Alloy Aerogels: A New Platform for Carbon Dioxide Reduction
Li, H., Huang, H., Chen, Y., Lai, F., Fu, H., Zhang, L., Zhang, N., Bai, S., & Liu, T. (2023) · Advanced Materials · doi:10.1002/adma.202209242 · Cited by 242
Zhu, C., Shi, Q., Fu, S., Song, J., Xia, H., Du, D., & Lin, Y. (2016) · Advanced Materials · doi:10.1002/adma.201602546 · Cited by 238
Self-citationHao, Y., Yu, D., Zhu, S., Kuo, C., Chang, Y., Wang, L., Chen, H., Shao, M., & Peng, S. (2023) · Energy & Environmental Science · doi:10.1039/d2ee03936b · Cited by 238
Chen, D., Ding, Y., Cao, X., Wang, L., Lee, H., Lin, G., Li, W., Ding, G., & Sun, L. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202309478 · Cited by 235
Lin, R., Kang, L., Zhao, T., Feng, J., Celorrio, V., Zhang, G., Cibin, G., Kucernak, A. R., Brett, D. J. L., Corà, F., et al. (2022) · Energy & Environmental Science · doi:10.1039/d1ee03522c · Cited by 220
Xu, Y. P., Liu, M., Wang, M., Ren, T., Ren, K., Wang, Z., Li, X., Wang, L., & Wang, H. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120753 · Cited by 199
Self-citationLiu, C., Shi, X., Yue, K., Wang, P., Zhan, K., Wang, D., Xia, B. Y., & Yan, Y. P. (2023) · Advanced Materials · doi:10.1002/adma.202211177 · Cited by 196
Zhao, B., Liu, J., Xu, C., Feng, R., Sui, P., Wang, L., Zhang, J., Luo, J., & Fu, X. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202008812 · Cited by 185
Xiao, D., Bao, X., Dai, D., Gao, Y., Si, S., Wang, Z., Liu, Y., Wang, P., Zheng, Z., Cheng, H., et al. (2023) · Advanced Materials · doi:10.1002/adma.202304133 · Cited by 185
Du, R., Wang, J., Wang, Y., Hübner, R., Fan, X., Senkovska, I., Hu, Y., Kaskel, S., & Eychmüller, A. (2020) · Nature Communications · doi:10.1038/s41467-020-15391-w · Cited by 184
Short‐Range Diffusion Enables General Synthesis of Medium‐Entropy Alloy Aerogels
Han, G., Li, M., Liu, H., Zhang, W., He, L., Tian, F., Liu, Y., Yu, Y., Yang, W., & Guo, S. (2022) · Advanced Materials · doi:10.1002/adma.202202943 · Cited by 177
Sub‐Monolayer YO x /MoO x on Ultrathin Pt Nanowires Boosts Alcohol Oxidation Electrocatalysis
Li, M., Zhao, Z., Zhang, W., Luo, M., Lü, T., Sun, Y., Xia, Z., Chao, Y., Yin, K., Zhang, Q., et al. (2021) · Advanced Materials · doi:10.1002/adma.202103762 · Cited by 168
Yang, J., Hübner, R., Zhang, J., Wan, H., Zheng, Y., Wang, H., Qi, H., He, L., Li, Y., Dubale, A. A., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202015679 · Cited by 166
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Wang, H., Jiao, L., Zheng, L., Fang, Q., Qin, Y., Luo, X., Wei, X., Hu, L., Gu, W., Wen, J., et al. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202103465 · Cited by 162
Self-citationXia, T., Zhao, K., Zhu, Y., Bai, X., Gao, H., Wang, Z., Gong, Y., Feng, M., Li, S. F., Zheng, Q., et al. (2022) · Advanced Materials · doi:10.1002/adma.202206508 · Cited by 149
Selective Methanol‐to‐Formate Electrocatalytic Conversion on Branched Nickel Carbide
Li, J., Wei, R., Wang, X., Zuo, Y., Han, X., Arbiol, J., Llorca, J., Yang, Y., Cabot, A., & Cui, C. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202004301 · Cited by 147
Wang, K., Huang, D., Guan, Y., Liu, F., He, J., & Ding, Y. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c04424 · Cited by 145
Emerging Noble Metal Aerogels: State of the Art and a Look Forward
Du, R., Fan, X., Jin, X., Hübner, R., Hu, Y., & Eychmüller, A. (2019) · Matter · doi:10.1016/j.matt.2019.05.006 · Cited by 139
Zhu, Y., Zhu, X., Bu, L., Shao, Q., Li, Y., Hu, Z., Chen, C., Pao, C., Yang, S., & Huang, X. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202004310 · Cited by 137
Pd Metallene Aerogels with Single-Atom W Doping for Selective Ethanol Oxidation
Wang, H., Zheng, H., Ling, L., Fang, Q., Jiao, L., Zheng, L., Qin, Y., Luo, Z. H., Gu, W., Song, W., et al. (2022) · ACS Nano · doi:10.1021/acsnano.2c09270 · Cited by 127
Self-citationZhao, B., Liu, J., Wang, X., Xu, C., Sui, P., Feng, R., Wang, L., Zhang, J., Luo, J., & Fu, X. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.105530 · Cited by 113
Unraveling the electrophilic oxygen-mediated mechanism for alcohol electrooxidation on NiO
Chen, W., Shi, J., Xie, C. L., Wang, Z., Xu, L., Li, Y., Wu, Y., Wu, B., Huang, Y., Zhou, B., et al. (2023) · National Science Review · doi:10.1093/nsr/nwad099 · Cited by 110
Liu, H., Jia, R., Qin, C., Yang, Q., Tang, Z., Li, M., & Ma, Z. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202210626 · Cited by 95
Chen, Y., Li, G., Mu, W., Wan, X., Lu, D., Gao, J., & Wen, D. (2023) · Analytical Chemistry · doi:10.1021/acs.analchem.2c05613 · Cited by 94
Optimizing the Pd Sites in Pure Metallic Aerogels for Efficient Electrocatalytic H 2 O 2 Production
Zhang, X., Wang, C., Chen, K., Clark, A. H., Hübner, R., Zhan, J., Zhang, L., Eychmüller, A., & Cai, B. (2023) · Advanced Materials · doi:10.1002/adma.202211512 · Cited by 82
Sun, S., Dong, L., Li, J., Shi, J., Liu, J., Wang, Y., Huang, Q., & Lan, Y. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202207282 · Cited by 72
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Wang, H., Zhang, S., Cai, W., Xu, B. Z., Cai, Z., Wu, Y., Luo, X., Wei, X., Liu, Z., Gu, W., et al. (2020) · Materials Horizons · doi:10.1039/d0mh00646g · Cited by 58
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Hui, L., Xue, Y., Xing, C., Liu, Y., Du, Y., Fang, Y., Yu, H., Huang, B., & Li, Y. (2022) · Advanced Science · doi:10.1002/advs.202104991 · Cited by 57
Zhou, Y., Wang, Z., Fang, W., Qi, R., Wang, Z., Xia, C., Lei, K., You, B., Yang, X., Liu, Y., et al. (2023) · ACS Catalysis · doi:10.1021/acscatal.2c05144 · Cited by 52
Self-citationFan, X., Cai, B., Du, R., Hübner, R., Georgi, M., Jiang, G., Li, L., Khoshkhoo, M. S., Sun, H., & Eychmüller, A. (2019) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b03121 · Cited by 35
Kuang, Y., Qiao, W., Wang, S., Yang, F., & Feng, L. (2024) · ACS Materials Letters · doi:10.1021/acsmaterialslett.4c00244 · Cited by 34
Synergistic Effect of Nickel Oxyhydroxide and Tungsten Carbide in Electrocatalytic Alcohol Oxidation
Zhang, M., Zhu, J., Wan, R., Liu, B., Zhang, D., Zhang, C., Wang, J., & Niu, J. (2022) · Chemistry of Materials · doi:10.1021/acs.chemmater.1c02535 · Cited by 31
Li, R., Tursun, M., Jiang, Y., Zhan, Q., Ji, S., Bi, W., Wang, C., Liu, Y., Dai, S., Wu, C. J., et al. (2023) · ACS Materials Letters · doi:10.1021/acsmaterialslett.3c00826 · Cited by 15
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Li, C., Qin, P., Peng, G., Waterhouse, G. I. N., Shang, L., & Zhang, T. (2025) · Matter · doi:10.1016/j.matt.2025.102096 · Cited by 29
Yao, H., Yu, X., Jia, Y., Zhang, J., Yao, J., Liu, J., Su, B., & Guo, X. (2025) · Rare Metals · doi:10.1007/s12598-024-03111-y · Cited by 13
Li, M., Liao, L., Li, H., Shi, Y., Qie, Z., Xiang, K., Zou, J., & Fu, X. (2025) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2025.126160 · Cited by 12
Zhang, C., Jiang, L., Sun, Z., Tang, Z., Lu, K., Zhu, Q., Zhang, X., Ge, H., Zhao, Z., Chen, W., et al. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202518043 · Cited by 10
Zhao, M., Yuan, J., Yang, F., Liu, H., Sun, X., Sun, Y., Sun, S., Liu, J., & Li, Y. (2025) · Green Chemistry · doi:10.1039/d5gc03579a · Cited by 9
Liu, D., Chen, C., Luo, Y., & Tong, Y. (2026) · Chemical Engineering Journal · doi:10.1016/j.cej.2026.180093 · Cited by 3
Yang, M., Sheng, S., Wan, Z., Xu, Y., Qi, R., Luo, X., Pan, W., Yang, K., Zhang, Z., & Deng, G. (2025) · Molecular Catalysis · doi:10.1016/j.mcat.2025.115313 · Cited by 2
Sheng, S., Xu, Y., Qi, R., Luo, X., Wan, Z., Li, P., Pan, W., Sun, Q. H., Xiong, Z., Yang, K., et al. (2024) · SSRN Electronic Journal · doi:10.2139/ssrn.4891428
Zheng, Y., He, X., Qu, L., Wang, P., 任, 美., 毛治博, Liu, H., Song, Y., Ma, L., Lei, H., et al. (2026) · Electrochimica Acta · doi:10.1016/j.electacta.2026.150155
Li, H., Xia, T., Bo, X., Zou, J., Li, S., & Xiang, K. (2026) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.70809
Metadata
- Authors
- Wang, H., Xie, K., Fang, Q., Zheng, L., Yang, X., Ling, L., Wen, Y., Lin, L., Yang, X., Gu, W., He, C., & Zhu, C.
- Affiliations
- Central China Normal University (CN)
- Henan Polytechnic University (CN)
- Chinese Academy of Sciences (CN)
- Huazhong University of Science and Technology (CN)
- Xi'an Technological University (CN)
- Corresponding author
- Zheng, Lirong
- He, Chaozheng
- Zhu, Chengzhou
- ORCID
- Venue
- ACS Materials Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2024-05-20
- Volume
- 6
- Issue
- 6
- Pages
- 2446-2454
- ISSN
- 2639-4979 (ISSN-L)
- OpenAlex
- W4398142893
- Cited by
- 12
- References
- 45
- Citations by year
- 2026: 4 · 2025: 7 · 2024: 1
- FWCI
- 0.80
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Materials Letters (publishedVersion)
- Funders
- Central China Normal University
- Fundamental Research Funds for the Central Universities (CCNU20TS013, CCNU22JC006)
- Higher Education Discipline Innovation Project (B17019)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Keywords
- methanol oxidation, competitive adsorption, methanol adsorption, hydroxide adsorption, formic acid selectivity, electrocatalysts, rate-determining step, operando spectroscopy
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