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Sub-nm RuOx Clusters on Pd Metallene for Synergistically Enhanced Nitrate Electroreduction to Ammonia
Abstract
The electrochemical nitrate reduction to ammonia reaction (NO 3 RR) has emerged as an appealing route for achieving both wastewater treatment and ammonia production. Herein, sub-nm RuO x clusters anchored on a Pd metallene (RuO x /Pd) are reported as a highly effective NO 3 RR catalyst, delivering a maximum NH 3 -Faradaic efficiency of 98.6% with a corresponding NH 3 yield rate of 23.5 mg h –1 cm –2 and partial a current density of 296.3 mA cm –2 at −0.5 V vs RHE. Operando spectroscopic characterizations combined with theoretical computations unveil the synergy of RuO x and Pd to enhance the NO 3 RR energetics through a mechanism of hydrogen spillover and hydrogen-bond interactions. In detail, RuO x activates NO 3 – to form intermediates, while Pd dissociates H 2 O to generate *H, which spontaneously migrates to the RuO x /Pd interface via a hydrogen spillover process. Further hydrogen-bond interactions between spillovered *H and intermediates makes spillovered *H desorb from the RuO x /Pd interface and participate in the intermediate hydrogenation, contributing to the enhanced activity of RuO x /Pd for NO 3 – -to-NH 3 conversion.
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Cited by
Phu, T. K. C., Hong, W. T., Han, H., Song, Y. I., Kim, J. H., Roh, S. H., Kim, M.-C., Koh, J. H., Oh, B.-K., Kim, J. Y., et al. (2024) · Materials Today · doi:10.1016/j.mattod.2024.05.007 · Cited by 22
Metadata
- Authors
- Li, X., Shen, P., Li, X., Ma, D., & Chu, K.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2023-01-11
- Volume
- 17
- Issue
- 2
- Pages
- 1081-1090
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W4315631276
- Cited by
- 369
- References
- 49
- FWCI
- 17.14
- Type
- journal article
- Language
- en
- Open access
- closed
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