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Concave Rhombic Dodecahedral Au Nanocatalyst with Multiple High-Index Facets for CO2 Reduction
Abstract
A concave rhombic dodecahedron (RD) gold nanoparticle was synthesized by adding 4-aminothiophenol (4-ATP) during growth from seeds. This shape is enclosed by stabilized facets of various high-indexes, such as (331), (221), and (553). Because it is driven thermodynamically and stabilized by 4-ATP ligands, the concave RD maintains its structure over a few months, even after rigorous electrochemical reactions. We discussed the mechanism of the shape evolution controlled by 4-ATP and found that both the binding energy of Au-S and the aromatic geometry of 4-ATP are major determinants of Au atom deposition during growth. As a possible application, we demonstrated that the concave RD exhibits superior electrocatalytic performance for the selective conversion of CO2 to CO in aqueous solution.
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Metadata
- Authors
- Lee, H.-E., Yang, K. D., Yoon, S. M., Ahn, H.-Y., Lee, Y. Y., Chang, H., Jeong, D. H., Lee, Y.-S., Kim, M. Y., & Nam, K. T.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-07-21
- Volume
- 9
- Issue
- 8
- Pages
- 8384-8393
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2411411243
- Cited by
- 264
- References
- 40
- FWCI
- 7.04
- Type
- journal article
- Language
- en
- Open access
- closed
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