The DOI matches its Crossref record; 51 of the 51 references it cites were found in a registry or an index.
Multilayer CuO@NiO Hollow Spheres: Microwave-Assisted Metal–Organic-Framework Derivation and Highly Reversible Structure-Matched Stepwise Lithium Storage
Abstract
A unique CuO@NiO microsphere with three-layer ball-in-ball hollow morphology is successfully synthesized by Cu-Ni bimetallic organic frameworks. The beforehand facile microwave-assisted production of the Ni organic framework sphere is used as the template to induce the morphology control of bimetallic oxides. Designed by the controlled surface cationic exchange reactions between Cu and Ni ions, there is an elemental gradient (decreased amount of CuO but increased amount of NiO) from the shell to the core of the microsphere product. This ternary metal oxide hollow structure is found to be very suitable for solving the critical volume expansion problem, which is critical for all high-capacity metal oxide electrodes for lithium ion batteries. A reversible larger-than-theoretical capacity of 1061 mAh·g(-1) can be retained after a repetitive 200 cycles without capacity fading compared to the initial cycle. These excellent electrochemical properties are ascribed to the step-by-step lithium insertion reactions induced by the matched CuO@NiO composition from the shell to the core and facilitated lithium/electron diffusion and accommodated volume change in the porous bimetallic oxides microsphere with a multiple-layer yolk-shell nanostructure.
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Cites
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
Poizot, P., Laruelle, S., Grugeon, S., Dupont, L., & Tarascon, J.-M. (2000) · Nature · doi:10.1038/35035045 · Cited by 8,041
Metal–Organic Framework Materials as Chemical Sensors
Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136
Carbon Dioxide Capture in Metal–Organic Frameworks
Sumida, K., Rogow, D. L., Mason, J. A., McDonald, T. M., Bloch, E. D., Herm, Z. R., Bae, T.-H., & Long, J. R. (2012) · Chemical Reviews · doi:10.1021/cr2003272 · Cited by 6,408
Luminescent Functional Metal–Organic Frameworks
Cui, Y., Yue, Y., Qian, G., & Chen, B. (2012) · Chemical Reviews · doi:10.1021/cr200101d · Cited by 5,697
Formation of hollow nanocrystals through the nanoscale kirkendall \neffect
Yin, Y., Rioux, R. M., Erdonmez, C. K., Hughes, S. M., Somorjai, G. A., & Alivisatos, A. P. (2004) · eScholarship (California Digital Library) · Cited by 3,537
Jiang, J., Li, Y., Liu, J., Huang, X., Yuan, C., & Lou, X. W. (. (2012) · Advanced Materials · doi:10.1002/adma.201202146 · Cited by 2,473
Mixed Transition‐Metal Oxides: Design, Synthesis, and Energy‐Related Applications
Yuan, C., Wu, H. B., Xie, Y., & Lou, X. W. (. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201303971 · Cited by 2,304
Yu, J. C., Yu, Ho, Jiang, & Zhang (2002) · Chemistry of Materials · doi:10.1021/cm020027c · Cited by 2,166
Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors
Lang, X., Hirata, A., Fujita, T., & Chen, M. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2011.13 · Cited by 2,109
High-energy cathode material for long-life and safe lithium batteries
Sun, Y.-K., Myung, S.-T., Park, B.-C., Prakash, J., Belharouak, I., & Amine, K. (2009) · Nature Materials · doi:10.1038/nmat2418 · Cited by 1,519
Cited by
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Guan, B. Y., Yu, X. Y., Wu, H. B., & Lou, X. W. (. (2017) · Advanced Materials · doi:10.1002/adma.201703614 · Cited by 733
Cheng, H., Li, M., Su, C., Li, N., & Liu, Z. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201701833 · Cited by 384
MOF-derived nanohybrids for electrocatalysis and energy storage: current status and perspectives
Zhang, H., Liu, X., Wu, Y., Guan, C., Cheetham, A. K., & Wang, J. (2018) · Chemical Communications · doi:10.1039/c8cc00789f · Cited by 309
Metal–organic framework derived hollow materials for electrochemical energy storage
Xie, X.-C., Huang, K.-J., & Wu, X. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta00612a · Cited by 284
Metadata
- Authors
- Guo, W., Sun, W., & Wang, Y.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-09
- Volume
- 9
- Issue
- 11
- Pages
- 11462-11471
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2206713858
- Cited by
- 375
- References
- 51
- FWCI
- 23.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- Guo, W., Sun, W., & Wang, Y. (2015). Multilayer CuO@NiO Hollow Spheres: Microwave-Assisted Metal–Organic-Framework Derivation and Highly Reversible Structure-Matched Stepwise Lithium Storage. ACS Nano. https://doi.org/10.1021/acsnano.5b05610
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