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Synthesis of Ultrathin Si Nanosheets from Natural Clays for Lithium-Ion Battery Anodes
Abstract
Two-dimensional Si nanosheets have been studied as a promising candidate for lithium-ion battery anode materials. However, Si nanosheets reported so far showed poor cycling performances and required further improvements. In this work, we utilize inexpensive natural clays for preparing high quality Si nanosheets via a one-step simultaneous molten salt-induced exfoliation and chemical reduction process. This approach produces high purity mesoporous Si nanosheets in high yield. As a control experiment, two-step process (pre-exfoliated silicate sheets and subsequent chemical reduction) cannot sustain their original two-dimensional structure. In contrast, one-step method results in a production of 5 nm-thick highly porous Si nanosheets. Carbon-coated Si nanosheet anodes exhibit a high reversible capacity of 865 mAh g(-1) at 1.0 A g(-1) with an outstanding capacity retention of 92.3% after 500 cycles. It also delivers high rate capability, corresponding to a capacity of 60% at 20 A g(-1) compared to that of 2.0 A g(-1). Furthermore, the Si nanosheet electrodes show volume expansion of only 42% after 200 cycles.
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Cites
The Scherrer Formula for X-Ray Particle Size Determination
Patterson, A. L. (1939) · Physical Review · doi:10.1103/physrev.56.978 · Cited by 9,152
Nanostructured materials for advanced energy conversion and storage devices
Aricò, A. S., Bruce, P., Scrosati, B., Tarascon, J.-M., & van Schalkwijk, W. (2005) · Nature Materials · doi:10.1038/nmat1368 · Cited by 8,826
High-performance lithium battery anodes using silicon nanowires
Chan, C. K., Peng, H., Liu, G., McIlwrath, K., Zhang, X. F., Huggins, R. A., & Cui, Y. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2007.411 · Cited by 6,683
Nanomaterials for Rechargeable Lithium Batteries
Bruce, P. G., Scrosati, B., & Tarascon, J. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702505 · Cited by 5,886
Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
Kasavajjula, U., Wang, C., & Appleby, A. J. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.09.084 · Cited by 2,491
Wu, H., Chan, G., Choi, J. W., Ryu, I., Yao, Y., McDowell, M. T., Lee, S. W., Jackson, A., Yang, Y., Hu, L., et al. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.35 · Cited by 2,478
Designing nanostructured Si anodes for high energy lithium ion batteries
Wu, H., & Cui, Y. (2012) · Nano Today · doi:10.1016/j.nantod.2012.08.004 · Cited by 2,350
Li-alloy based anode materials for Li secondary batteries
Park, C.-M., Kim, J.-H., Kim, H., & Sohn, H.-J. (2010) · Chemical Society Reviews · doi:10.1039/b919877f · Cited by 1,703
Silicon Nanotube Battery Anodes
Park, M.-H., Kim, M. G., Joo, J., Kim, K., Kim, J., Ahn, S., Cui, Y., & Cho, J. (2009) · Nano Letters · doi:10.1021/nl902058c · Cited by 1,493
Nanostructured silicon for high capacity lithium battery anodes
Szczech, J. R., & Jin, S. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00281j · Cited by 1,395
Reversible Cycling of Crystalline Silicon Powder
Obrovac, M. N., & Krause, L. J. (2007) · Journal of The Electrochemical Society · doi:10.1149/1.2402112 · Cited by 1,259
Highly Reversible Lithium Storage in Nanostructured Silicon
Graetz, J., Ahn, C. C., Yazami, R., & Fultz, B. (2003) · Electrochemical and Solid-State Letters · doi:10.1149/1.1596917 · Cited by 701
Ryou, M., Kim, J., Lee, I., Kim, S., Jeong, Y. K., Hong, S., Ryu, J. H., Kim, T., Park, J., Lee, H., et al. (2013) · Advanced Materials · doi:10.1002/adma.201203981 · Cited by 622
Self-citationPrelithiated Silicon Nanowires as an Anode for Lithium Ion Batteries
Liu, N., Hu, L., McDowell, M. T., Jackson, A., & Cui, Y. (2011) · ACS Nano · doi:10.1021/nn2017167 · Cited by 578
Nie, M., Abraham, D. P., Chen, Y., Bose, A., & Lucht, B. L. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp404155y · Cited by 578
Guggenheim, S., & Martin, R. T. (1995) · Clays and Clay Minerals · doi:10.1346/ccmn.1995.0430213 · Cited by 398
Silicon nanowires for Li-based battery anodes: a review
Zamfir, M. R., Nguyen, H. T., Moyen, E., Lee, Y. H., & Pribat, D. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta11714f · Cited by 368
Nanostructured electrodes for high-power lithium ion batteries
Mukherjee, R., Krishnan, R., Lu, T.-M., & Koratkar, N. (2012) · Nano Energy · doi:10.1016/j.nanoen.2012.04.001 · Cited by 341
Structural and electrochemical study of the reaction of lithium with silicon nanowires
Chan, C. K., Ruffo, R., Hong, S. S., Huggins, R. A., & Cui, Y. (2009) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.12.047 · Cited by 292
Lin, Y.-M., Klavetter, K. C., Abel, P. R., Davy, N. C., Snider, J. L., Heller, A., & Mullins, C. B. (2012) · Chemical Communications · doi:10.1039/c2cc31712e · Cited by 290
Dai, F., Zai, J., Yi, R., Gordin, M. L., Sohn, H., Chen, S., & Wang, D. (2014) · Nature Communications · doi:10.1038/ncomms4605 · Cited by 262
Synthesis of Ultrathin Silicon Nanosheets by Using Graphene Oxide as Template
Lu, Z., Zhu, J., Sim, D., Zhou, W., Shi, W., Hng, H. H., & Yan, Q. (2011) · Chemistry of Materials · doi:10.1021/cm202891p · Cited by 184
Synthesis of Si Nanosheets by a Chemical Vapor Deposition Process and Their Blue Emissions
Kim, U., Kim, I., Park, Y., et al. (2011) · ACS Nano · doi:10.1021/nn103385p · Cited by 121
Yoo, J., Kim, J., Choi, M., Park, Y., Hong, J., Baek, K. M., Kang, K., & Jung, Y. S. (2014) · Advanced Energy Materials · doi:10.1002/aenm.201400622 · Cited by 103
Cited by
Toward Practical High-Energy and High-Power Lithium Battery Anodes: Present and Future
Wang, C., Yang, C., & Zheng, Z. (2022) · Advanced Science · doi:10.1002/advs.202105213 · Cited by 337
Ionically Conductive Self‐Healing Binder for Low Cost Si Microparticles Anodes in Li‐Ion Batteries
Munaoka, T., Yan, X., Lopez, J., To, J. W. F., Park, J., Tok, J. B. ‐., Cui, Y., & Bao, Z. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703138 · Cited by 322
Constructing Pure Si Anodes for Advanced Lithium Batteries
Je, M., Han, D.-Y., Ryu, J., & Park, S. (2023) · Accounts of Chemical Research · doi:10.1021/acs.accounts.3c00308 · Cited by 175
Self-citation
Metadata
- Authors
- Ryu, J., Hong, D., Choi, S., & Park, S.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-01-26
- Volume
- 10
- Issue
- 2
- Pages
- 2843-2851
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2262646201
- Cited by
- 334
- References
- 24
- FWCI
- 20.43
- Type
- journal article
- Language
- en
- Open access
- closed
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