The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
From Metal–Organic Framework to Li2S@C–Co–N Nanoporous Architecture: A High-Capacity Cathode for Lithium–Sulfur Batteries
Abstract
Owing to the high theoretical specific capacity (1166 mAh g –1 ), lithium sulfide (Li 2 S) has been considered as a promising cathode material for Li–S batteries. However, the polysulfide dissolution and low electronic conductivity of Li 2 S limit its further application in next-generation Li–S batteries. In this report, a nanoporous Li 2 S@C–Co–N cathode is synthesized by liquid infiltration–evaporation of ultrafine Li 2 S nanoparticles into graphitic carbon co-doped with cobalt and nitrogen (C–Co–N) derived from metal–organic frameworks. The obtained Li 2 S@C–Co–N architecture remarkably immobilizes Li 2 S within the cathode structure through physical and chemical molecular interactions. Owing to the synergistic interactions between C–Co–N and Li 2 S nanoparticles, the Li 2 S@C–Co–N composite delivers a reversible capacity of 1155.3 (99.1% of theoretical value) at the initial cycle and 929.6 mAh g –1 after 300 cycles, with nearly 100% Coulombic efficiency and a capacity fading of 0.06% per cycle. It exhibits excellent rate capacities of 950.6, 898.8, and 604.1 mAh g –1 at 1C, 2C, and 4C, respectively. Such a cathode structure is promising for practical applications in high-performance Li–S batteries.
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Citations
Cites
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Cited by
He, J., Luo, L., Chen, Y., & Manthiram, A. (2017) · Advanced Materials · doi:10.1002/adma.201702707 · Cited by 521
Self-citationIndra, A., Song, T., & Paik, U. (2018) · Advanced Materials · doi:10.1002/adma.201705146 · Cited by 507
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Sun, W., Cai, C., Tang, X., Lv, L.-P., & Wang, Y. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.06.093 · Cited by 90
Metadata
- Authors
- He, J., Chen, Y., Lv, W., Wen, K., Xu, C., Zhang, W., Li, Y., Qin, W., & He, W.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-08
- Volume
- 10
- Issue
- 12
- Pages
- 10981-10987
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2560814032
- Cited by
- 305
- References
- 43
- FWCI
- 22.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- He, J., Chen, Y., Lv, W., Wen, K., Xu, C., Zhang, W., Li, Y., Qin, W., & He, W. (2016). From Metal–Organic Framework to Li2S@C–Co–N Nanoporous Architecture: A High-Capacity Cathode for Lithium–Sulfur Batteries. ACS Nano. https://doi.org/10.1021/acsnano.6b05696
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