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From Metal–Organic Framework to Li2S@C–Co–N Nanoporous Architecture: A High-Capacity Cathode for Lithium–Sulfur Batteries

He, Jiarui, Chen, Yuanfu, Lv, Weiqiang, Wen, Kechun, Xu, Chen, Zhang, Wanli, Li, Yanrong, Qin, Wu, He, Weidong·2016·ACS Nano

DOI 10.1021/acsnano.6b05696

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Abstract

Owing to the high theoretical specific capacity (1166 mAh g –1 ), lithium sulfide (Li 2 S) has been considered as a promising cathode material for Li–S batteries. However, the polysulfide dissolution and low electronic conductivity of Li 2 S limit its further application in next-generation Li–S batteries. In this report, a nanoporous Li 2 S@C–Co–N cathode is synthesized by liquid infiltration–evaporation of ultrafine Li 2 S nanoparticles into graphitic carbon co-doped with cobalt and nitrogen (C–Co–N) derived from metal–organic frameworks. The obtained Li 2 S@C–Co–N architecture remarkably immobilizes Li 2 S within the cathode structure through physical and chemical molecular interactions. Owing to the synergistic interactions between C–Co–N and Li 2 S nanoparticles, the Li 2 S@C–Co–N composite delivers a reversible capacity of 1155.3 (99.1% of theoretical value) at the initial cycle and 929.6 mAh g –1 after 300 cycles, with nearly 100% Coulombic efficiency and a capacity fading of 0.06% per cycle. It exhibits excellent rate capacities of 950.6, 898.8, and 604.1 mAh g –1 at 1C, 2C, and 4C, respectively. Such a cathode structure is promising for practical applications in high-performance Li–S batteries.

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Authors: He, J., Chen, Y., Lv, W., Wen, K., Xu, C., Zhang, W., Li, Y., Qin, W., & He, W.
Venue: ACS Nano
Publisher: American Chemical Society (ACS)
Published: 2016-12-08
Volume: 10
Issue: 12
Pages: 10981-10987
ISSN: 1936-0851 (ISSN-L)
1936-086X
DOI: 10.1021/acsnano.6b05696
OpenAlex: W2560814032
Cited by: 305
References: 43
FWCI: 22.87
Type: journal article
Language: en
Open access: closed

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From Metal–Organic Framework to Li2S@C–Co–N Nanoporous Architecture: A High-Capacity Cathode for Lithium–Sulfur Batteries

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