The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Highly Efficient Light-Emitting Diodes of Colloidal Metal–Halide Perovskite Nanocrystals beyond Quantum Size
Open accessAbstract
Colloidal metal–halide perovskite quantum dots (QDs) with a dimension less than the exciton Bohr diameter D B (quantum size regime) emerged as promising light emitters due to their spectrally narrow light, facile color tuning, and high photoluminescence quantum efficiency (PLQE). However, their size-sensitive emission wavelength and color purity and low electroluminescence efficiency are still challenging aspects. Here, we demonstrate highly efficient light-emitting diodes (LEDs) based on the colloidal perovskite nanocrystals (NCs) in a dimension > D B (regime beyond quantum size) by using a multifunctional buffer hole injection layer (Buf-HIL). The perovskite NCs with a dimension greater than D B show a size-irrespective high color purity and PLQE by managing the recombination of excitons occurring at surface traps and inside the NCs. The Buf-HIL composed of poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS) and perfluorinated ionomer induces uniform perovskite particle films with complete film coverage and prevents exciton quenching at the PEDOT:PSS/perovskite particle film interface. With these strategies, we achieved a very high PLQE (∼60.5%) in compact perovskite particle films without any complex post-treatments and multilayers and a high current efficiency of 15.5 cd/A in the LEDs of colloidal perovskite NCs, even in a simplified structure, which is the highest efficiency to date in green LEDs that use colloidal organic–inorganic metal–halide perovskite nanoparticles including perovskite QDs and NCs. These results can help to guide development of various light-emitting optoelectronic applications based on perovskite NCs.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Bright light-emitting diodes based on organometal halide perovskite
Tan, Z.-K., Moghaddam, R. S., Lai, M. L., Docampo, P., Higler, R., Deschler, F., Price, M., Sadhanala, A., Pazos, L. M., Credgington, D., et al. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.149 · Cited by 4,450
Self-citationElectronic wave functions in semiconductor clusters: experiment and theory
Brus, L. (1986) · The Journal of Physical Chemistry · doi:10.1021/j100403a003 · Cited by 3,276
Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes
Cho, H., Jeong, S.-H., Park, M.-H., Kim, Y.-H., Wolf, C., Lee, C.-L., Heo, J. H., Sadhanala, A., Myoung, N., Yoo, S., et al. (2015) · Science · doi:10.1126/science.aad1818 · Cited by 2,925
Self-citationZhang, F., Zhong, H., Chen, C., Wu, X.-G., Hu, X., Huang, H., Han, J., Zou, B., & Dong, Y. (2015) · ACS Nano · doi:10.1021/acsnano.5b01154 · Cited by 2,431
Impact of microstructure on local carrier lifetime in perovskite solar cells
de Quilettes, D. W., Vorpahl, S. M., Stranks, S. D., Nagaoka, H., Eperon, G. E., Ziffer, M. E., Snaith, H. J., & Ginger, D. S. (2015) · Science · doi:10.1126/science.aaa5333 · Cited by 2,198
Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells
Im, J.-H., Jang, I.-H., Pellet, N., Grätzel, M., & Park, N.-G. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.181 · Cited by 1,759
Efficient perovskite light-emitting diodes featuring nanometre-sized crystallites
Xiao, Z., Kerner, R. A., Zhao, L., Tran, N. L., Lee, K. M., Koh, T.-W., Scholes, G. D., & Rand, B. P. (2017) · Nature Photonics · doi:10.1038/nphoton.2016.269 · Cited by 1,374
Nontemplate Synthesis of CH3NH3PbBr3 Perovskite Nanoparticles
Schmidt, L. C., Pertegás, A., González-Carrero, S., Malinkiewicz, O., Agouram, S., Mínguez Espallargas, G., Bolink, H. J., Galian, R. E., & Pérez-Prieto, J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja4109209 · Cited by 1,327
Multicolored Organic/Inorganic Hybrid Perovskite Light‐Emitting Diodes
Kim, Y., Cho, H., Heo, J. H., Kim, T., Myoung, N., Lee, C., Im, S. H., & Lee, T. (2015) · Advanced Materials · doi:10.1002/adma.201403751 · Cited by 1,273
Self-citationLi, J., Xu, L., Wang, T., Song, J., Chen, J., Xue, J., Dong, Y., Cai, B., Shan, Q., Han, B., et al. (2017) · Advanced Materials · doi:10.1002/adma.201603885 · Cited by 1,176
Kwak, J., Bae, W. K., Lee, D., Park, I., Lim, J., Park, M., Cho, H., Woo, H., Yoon, D. Y., Char, K., et al. (2012) · Nano Letters · doi:10.1021/nl3003254 · Cited by 942
Self-citationLi, G., Rivarola, F. W. R., Davis, N. J. L. K., Bai, S., Jellicoe, T. C., de la Peña, F., Hou, S., Ducati, C., Gao, F., Friend, R. H., et al. (2016) · Advanced Materials · doi:10.1002/adma.201600064 · Cited by 901
Self-citationQuantum Dot Light-Emitting Devices with Electroluminescence Tunable over the Entire Visible Spectrum
Anikeeva, P. O., Halpert, J. E., Bawendi, M. G., & Bulović, V. (2009) · Nano Letters · doi:10.1021/nl9002969 · Cited by 872
Galkowski, K., Mitioglu, A., Miyata, A., Plochocka, P., Portugall, O., Eperon, G. E., Wang, J. T.-W., Stergiopoulos, T., Stranks, S. D., Snaith, H. J., et al. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03435c · Cited by 768
Zhang, X., Lin, H., Huang, H., Reckmeier, C., Zhang, Y., Choy, W. C. H., & Rogach, A. L. (2016) · Nano Letters · doi:10.1021/acs.nanolett.5b04959 · Cited by 731
Huang, H., Susha, A. S., Kershaw, S. V., Hung, T. F., & Rogach, A. L. (2015) · Advanced Science · doi:10.1002/advs.201500194 · Cited by 617
Efficient Luminescence from Perovskite Quantum Dot Solids
Kim, Y., Yassitepe, E., Voznyy, O., Comin, R., Walters, G., Gong, X., Kanjanaboos, P., Nogueira, A. F., & Sargent, E. H. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b09084 · Cited by 555
Self-citationMetal halide perovskite light emitters
Kim, Y.-H., Cho, H., & Lee, T.-W. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1607471113 · Cited by 549
Self-citationBright Light‐Emitting Diodes Based on Organometal Halide Perovskite Nanoplatelets
Ling, Y., Yuan, Z., Tian, Y., Wang, X., Wang, J. C., Xin, Y., Hanson, K., Ma, B., & Gao, H. (2016) · Advanced Materials · doi:10.1002/adma.201503954 · Cited by 513
Jang, D. M., Park, K., Kim, D. H., Park, J., Shojaei, F., Kang, H. S., Ahn, J.-P., Lee, J. W., & Song, J. K. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b01430 · Cited by 504
Heo, J. H., Song, D. H., & Im, S. H. (2014) · Advanced Materials · doi:10.1002/adma.201403140 · Cited by 497
Self-citationColor-Pure Violet-Light-Emitting Diodes Based on Layered Lead Halide Perovskite Nanoplates
Liang, D., Peng, Y., Fu, Y., Shearer, M. J., Zhang, J., Zhai, J., Zhang, Y., Hamers, R. J., Andrew, T. L., & Jin, S. (2016) · ACS Nano · doi:10.1021/acsnano.6b02683 · Cited by 447
High-Efficiency Light-Emitting Diodes of Organometal Halide Perovskite Amorphous Nanoparticles
Xing, J., Yan, F., Zhao, Y., Chen, S., Yu, H., Zhang, Q., Zeng, R., Demir, H. V., Sun, X., Huan, A., et al. (2016) · ACS Nano · doi:10.1021/acsnano.6b01540 · Cited by 401
Colloidal CsPbBr3 Perovskite Nanocrystals: Luminescence beyond Traditional Quantum Dots
Swarnkar, A., Chulliyil, R., Ravi, V. K., Irfanullah, M., Chowdhury, A., & Nag, A. (2015) · Angewandte Chemie · doi:10.1002/ange.201508276 · Cited by 395
Efficient Blue Electroluminescence Using Quantum-Confined Two-Dimensional Perovskites
Kumar, S., Jagielski, J., Yakunin, S., Rice, P., Chiu, Y.-C., Wang, M., Nedelcu, G., Kim, Y., Lin, S., Santos, E. J. G., et al. (2016) · ACS Nano · doi:10.1021/acsnano.6b05775 · Cited by 354
Self-citationMaximizing the emissive properties of CH3NH3PbBr3 perovskite nanoparticles
Gonzalez-Carrero, S., Galian, R. E., & Pérez-Prieto, J. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta05878j · Cited by 340
Size‐Controlled Soft‐Template Synthesis of Carbon Nanodots toward Versatile Photoactive Materials
Kwon, W., Lee, G., Do, S., Joo, T., & Rhee, S. (2014) · Small · doi:10.1002/smll.201301770 · Cited by 285
Self-citationOrganometal Halide Perovskite Quantum Dot Light‐Emitting Diodes
Deng, W., Xu, X., Zhang, X., Zhang, Y., Jin, X., Wang, L., Lee, S., & Jie, J. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201601054 · Cited by 270
Exciton Binding Energy and the Nature of Emissive States in Organometal Halide Perovskites
Zheng, K., Zhu, Q., Abdellah, M., Messing, M. E., Zhang, W., Generalov, A., Niu, Y., Ribaud, L., Canton, S. E., & Pullerits, T. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01252 · Cited by 268
Kim, Y.-H., Lee, G.-H., Kim, Y.-T., Wolf, C., Yun, H. J., Kwon, W., Park, C. G., & Lee, T.-W. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.05.002 · Cited by 227
Self-citationDi, D., Musselman, K. P., Li, G., Sadhanala, A., Ievskaya, Y., Song, Q., Tan, Z.-K., Lai, M. L., MacManus-Driscoll, J. L., Greenham, N. C., et al. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/jz502615e · Cited by 180
Self-citationLaser Crystallization of Organic–Inorganic Hybrid Perovskite Solar Cells
Jeon, T., Jin, H. M., Lee, S. H., Lee, J. M., Park, H. I., Kim, M. K., Lee, K. J., Shin, B., & Kim, S. O. (2016) · ACS Nano · doi:10.1021/acsnano.6b03815 · Cited by 160
Tachikawa, T., Karimata, I., & Kobori, Y. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01566 · Cited by 124
Cited by
Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent
Lin, K., Xing, J., Quan, L. N., de Arquer, F. P. G., Gong, X., Lu, J., Xie, L., Zhao, W., Zhang, D., Yan, C., et al. (2018) · Nature · doi:10.1038/s41586-018-0575-3 · Cited by 3,355
Perovskites for Next-Generation Optical Sources
Quan, L. N., Rand, B. P., Friend, R. H., Mhaisalkar, S. G., Lee, T.-W., & Sargent, E. H. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00107 · Cited by 983
Self-citationYao, J.-S., Ge, J., Han, B.-N., Wang, K.-H., Yao, H.-B., Yu, H.-L., Li, J.-H., Zhu, B.-S., Song, J.-Z., Chen, C., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b11955 · Cited by 549
Zn-Alloyed CsPbI3 Nanocrystals for Highly Efficient Perovskite Light-Emitting Devices
Shen, X., Zhang, Y., Kershaw, S. V., Li, T., Wang, C., Zhang, X., Wang, W., Li, D., Wang, Y., Lu, M., et al. (2019) · Nano Letters · doi:10.1021/acs.nanolett.8b04339 · Cited by 532
Improving the Stability of Metal Halide Perovskite Materials and Light‐Emitting Diodes
Cho, H., Kim, Y., Wolf, C., Lee, H., & Lee, T. (2018) · Advanced Materials · doi:10.1002/adma.201704587 · Cited by 470
Self-citation
Metadata
- Authors
- Kim, Y.-H., Wolf, C., Kim, Y.-T., Cho, H., Kwon, W., Do, S., Sadhanala, A., Park, C. G., Rhee, S.-W., Im, S. H., Friend, R. H., & Lee, T.-W.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-22
- Volume
- 11
- Issue
- 7
- Pages
- 6586-6593
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2622010062
- Cited by
- 375
- References
- 33
- FWCI
- 20.47
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
