The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
High Quantum Yield Blue Emission from Lead-Free Inorganic Antimony Halide Perovskite Colloidal Quantum Dots
Abstract
Colloidal quantum dots (QDs) of lead halide perovskite have recently received great attention owing to their remarkable performances in optoelectronic applications. However, their wide applications are hindered from toxic lead element, which is not environment- and consumer-friendly. Herein, we utilized heterovalent substitution of divalent lead (Pb 2+ ) with trivalent antimony (Sb 3+ ) to synthesize stable and brightly luminescent Cs 3 Sb 2 Br 9 QDs. The lead-free, full-inorganic QDs were fabricated by a modified ligand-assisted reprecipitation strategy. A photoluminescence quantum yield (PLQY) was determined to be 46% at 410 nm, which was superior to that of other reported halide perovskite QDs. The PL enhancement mechanism was unraveled by surface composition derived quantum-well band structure and their large exciton binding energy. The Br-rich surface and the observed 530 meV exciton binding energy were proposed to guarantee the efficient radiative recombination. In addition, we can also tune the inorganic perovskite QD (Cs 3 Sb 2 X 9 ) emission wavelength from 370 to 560 nm via anion exchange reactions. The developed full-inorganic lead-free Sb-perovskite QDs with high PLQY and stable emission promise great potential for efficient emission candidates.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Dabbousi, B. O., Rodriguez-Viejo, J., Mikulec, F. V., Heine, J. R., Mattoussi, H., Ober, R., Jensen, K. F., & Bawendi, M. G. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp971091y · Cited by 4,229
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors
Zhu, H., Fu, Y., Meng, F., Wu, X., Gong, Z., Ding, Q., Gustafsson, M. V., Trinh, M. T., Jin, S., & Zhu, X.-Y. (2015) · Nature Materials · doi:10.1038/nmat4271 · Cited by 2,836
Akkerman, Q. A., D’Innocenzo, V., Accornero, S., Scarpellini, A., Petrozza, A., Prato, M., & Manna, L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b05602 · Cited by 2,197
Cited by
Wei, Y., Cheng, Z., & Lin, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00740c · Cited by 1,206
Leng, M., Yang, Y., Zeng, K., Chen, Z., Tan, Z., Li, S., Li, J., Xu, B., Li, D., Hautzinger, M. P., et al. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201704446 · Cited by 533
Self-citationAchieving Near-Unity Photoluminescence Efficiency for Blue-Violet-Emitting Perovskite Nanocrystals
Mondal, N., De, A., & Samanta, A. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01909 · Cited by 435
Bi, C., Wang, S., Li, Q., Kershaw, S. V., Tian, J., & Rogach, A. L. (2019) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.9b00290 · Cited by 367
Ghosh, A., Paul, S., Das, M., Sarkar, P. K., Bhardwaj, P., Sheet, G., Das, S., Kalimuddin, S., Datta, A., & Acharya, S. (2024) · ACS Nano · doi:10.1021/acsnano.4c06297 · Cited by 15
Metadata
- Authors
- Zhang, J., Yang, Y., Deng, H., Farooq, U., Yang, X., Khan, J., Tang, J., & Song, H.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-09-11
- Volume
- 11
- Issue
- 9
- Pages
- 9294-9302
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2752483144
- Cited by
- 581
- References
- 3
- FWCI
- 23.61
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
