Polyaniline-Modified Mg/Al Layered Double Hydroxide Composites and Their Application in Efficient Removal of Cr(VI)
Abstract
The organic–inorganic hybrid material of polyaniline/Mg/Al layered double hydroxides (PANI/LDHs) was fabricated through in situ oxidative polymerization. PANI/LDHs were characterized by field emission scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, and thermogravimetric analysis. The results showed that PANI was successfully grown on PANI/LDHs. PANI/LDHs were further applied to remove Cr(VI) from aqueous solution, which exhibited outstanding removal capacity toward Cr(VI) (393.70 mg/g), comparable to Cr(VI) removal on PANI nanotubes (198.67 mg/g) and many other materials. The adsorption kinetics followed the pseudo-second-order model. The adsorption of Cr(VI) on PANI/LDHs was highly pH dependent. The Langmuir model described the adsorption isotherm data better than the Freundlich model. Thermodynamic parameters for the adsorption system were calculated and suggested that the adsorption process was spontaneous and endothermic. As a result, this study indicates that PANI/LDHs may be ideal materials for Cr(VI) wastewater treatment.
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At pH ≤ 1, Cr(VI) exists primarily as chromic acid (H2CrO4).
“At pH ≤ 1, Cr(VI) exists primarily as chromic acid (H2CrO4).”
From Optimized removal of hexavalent chromium from water using spent tea leaves treated with ascorbic acid (2022) · cites this paper as [44]
At pH 1-7, the hydrogen chromate (HCrO4−) ion dominates.
“At pH 1–7, the hydrogen chromate (HCrO4–1) ion dominates, whereas above pH 7 only the chromate ion (CrO4–2) prevails40,43,44.”
From Optimized removal of hexavalent chromium from water using spent tea leaves treated with ascorbic acid (2022) · cites this paper as [44]
Above pH 7, only the chromate ion (CrO4−2) prevails.
“At pH 1–7, the hydrogen chromate (HCrO4–1) ion dominates, whereas above pH 7 only the chromate ion (CrO4–2) prevails40,43,44.”
From Optimized removal of hexavalent chromium from water using spent tea leaves treated with ascorbic acid (2022) · cites this paper as [44]
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- Authors
- Zhu, K., Gao, Y., Tan, X., & Chen, C.
- Affiliations
- University of Science and Technology of China (CN)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Chen, Changlun
- Venue
- ACS Sustainable Chemistry & Engineering
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-06-29
- Volume
- 4
- Issue
- 8
- Pages
- 4361-4369
- ISSN
- 2168-0485 (ISSN-L)
- OpenAlex
- W2440425374
- Cited by
- 228
- References
- 41
- Citations by year
- 2026: 9 · 2025: 10 · 2024: 13 · 2023: 25 · 2022: 34 · 2021: 23 · 2020: 29 · 2019: 28 · 2018: 37 · 2017: 18 · 2016: 2
- FWCI
- 12.61
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Sustainable Chemistry & Engineering (publishedVersion)
- Funders
- National Natural Science Foundation of China (21477133, 41273134)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Layered Double Hydroxides Synthesis and Applications
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Keywords
- polyaniline, Mg-Al layered double hydroxide, organic-inorganic hybrid materials, hexavalent chromium removal, Cr(VI) adsorption, wastewater treatment, in situ oxidative polymerization, adsorption kinetics, adsorption isotherms, adsorption thermodynamics, pH dependence
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