The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Hierarchically Structured Manganese Oxide-Coated Magnetic Nanocomposites for the Efficient Removal of Heavy Metal Ions from Aqueous Systems
Abstract
In this study, hierarchical MnO2-coated magnetic nanocomposite (Fe3O4/MnO2) was synthesized by a mild hydrothermal process, and its application for removing heavy metal ions from contaminated water systems was examined. Structural characterization showed that the Fe3O4 nanoparticle core was coated with amorphous MnO2 shell with flowerlike morphology. The as-prepared nanocomposite had a large surface area and high magnetic saturation value, which ensured its good sorption ability and convenience of separation. Fe3O4/MnO2 exhibited a greatly improved removal capacity toward four different heavy metals (Cd(II), Cu(II), Pb(II), and Zn(II)) compared to unmodified Fe3O4 nanoparticles. The adsorption property of Fe3O4/MnO2 was studied with Cd(II) in more detail. The sorption equilibrium data were well fitted to the Langmuir model, and the maximum adsorption capacity toward Cd(II) was 53.2 mg g(-1). Fe3O4/MnO2 retained over 80% of its adsorption capacity under various solution conditions that are typically encountered in natural waters. This nanocomposite was easily recovered and reused through consecutive adsorption-desorption experiments with the assistance of an external magnetic field. Overall, the findings propose that Fe3O4/MnO2 could be used as an effective recyclable adsorbent for heavy metal ions.
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Cites
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Manganese oxide minerals: Crystal structures and economic and environmental significance
Post, J. E. (1999) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.96.7.3447 · Cited by 1,854
Effect of phosphate complexation on Cd2+ sorption by manganese dioxide (β-MnO2)
Zaman, M. I., Mustafa, S., Khan, S., & Xing, B. (2009) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2008.10.053 · Cited by 89
Cited by
Ihsanullah, Abbas, A., Al-Amer, A. M., Laoui, T., Al-Marri, M. J., Nasser, M. S., Khraisheh, M., & Atieh, M. A. (2016) · Separation and Purification Technology · doi:10.1016/j.seppur.2015.11.039 · Cited by 1,259
Role of nanomaterials as adsorbents in heavy metal ion removal from waste water: A review
Wadhawan, S., Jain, A., Nayyar, J., & Mehta, S. K. (2020) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2019.101038 · Cited by 530
Gómez-Pastora, J., Bringas, E., & Ortiz, I. (2014) · Chemical Engineering Journal · doi:10.1016/j.cej.2014.06.119 · Cited by 396
Liu, Q., Zhong, L.-B., Zhao, Q.-B., Frear, C., & Zheng, Y.-M. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b04598 · Cited by 316
Mechanism and kinetics of adsorption and removal of heavy metals from wastewater using nanomaterials
Singh, S., Kapoor, D., Khasnabis, S., Singh, J., & Ramamurthy, P. C. (2021) · Environmental Chemistry Letters · doi:10.1007/s10311-021-01196-w · Cited by 220
Metadata
- Authors
- Kim, E.-J., Lee, C.-S., Chang, Y.-Y., & Chang, Y.-S.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-25
- Volume
- 5
- Issue
- 19
- Pages
- 9628-9634
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2080308487
- Cited by
- 359
- References
- 3
- FWCI
- 17.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kim, E.-J., Lee, C.-S., Chang, Y.-Y., & Chang, Y.-S. (2013). Hierarchically Structured Manganese Oxide-Coated Magnetic Nanocomposites for the Efficient Removal of Heavy Metal Ions from Aqueous Systems. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am402615m
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