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Structural and Morphological Control of Cationic Surfactant-Templated Mesoporous Silica
Abstract
Micelle-templated mesoporous silica materials are rapidly becoming important in many fields of chemistry for hosting reactants or catalysts in confined space. Fine control of the pore size, wall structure, surface functionalization, defects, and morphology is needed for fine-tuning the pores as nanoreactors. We review the physical chemistry of solution silicate species and surfactants in the synthesis of mesoporous silicas. Controls in surfactant packing and liquid crystalline phase transformation can lead to various tailored synthesis strategies. Postsynthesis treatments further make more stable mesoporous materials.
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Citations
Cited by
On the controllable soft-templating approach to mesoporous silicates
Wan, Y., & Zhao (2007) · Chemical Reviews · doi:10.1021/cr068020s · Cited by 2,371
Hollow‐Structured Mesoporous Materials: Chemical Synthesis, Functionalization and Applications
Li, Y., & Shi, J. (2014) · Advanced Materials · doi:10.1002/adma.201305319 · Cited by 759
Zhu, C., Du, D., Eychmüller, A., & Lin, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00255 · Cited by 672
Template-Directed Materials for Rechargeable Lithium-Ion Batteries
Cheng, F., Tao, Z., Liang, J., & Chen, J. (2008) · Chemistry of Materials · doi:10.1021/cm702091q · Cited by 537
Self-assembly: from crystals to cells
Grzybowski, B. A., Wilmer, C. E., Kim, J., Browne, K. P., & Bishop, K. J. M. (2009) · Soft Matter · doi:10.1039/b819321p · Cited by 447
Metadata
- Authors
- Lin, H.-P., & Mou, C.-Y.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-08-16
- Volume
- 35
- Issue
- 11
- Pages
- 927-935
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2150416472
- Cited by
- 431
- References
- 0
- FWCI
- 11.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lin, H.-P., & Mou, C.-Y. (2002). Structural and Morphological Control of Cationic Surfactant-Templated Mesoporous Silica. Accounts of Chemical Research. https://doi.org/10.1021/ar000074f
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