The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
Open accessAbstract
This account explores the catalytic reduction of dinitrogen by molybdenum complexes that contain the [HIPTN(3)N](3-) ligand ([HIPTN(3)N](3-)) = [(HIPTNCH(2)CH(2))(3)N](3-), where HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H3) at room temperature and pressure with protons and electrons. A total of 7-8 equiv of ammonia is formed out of approximately 12 possible (depending upon the Mo derivative employed). No hydrazine is formed. Numerous X-ray studies of proposed intermediates in the catalytic cycle suggest that N(2) is being reduced at a sterically protected, single Mo center operating in oxidation states between Mo(III) and Mo(VI). Subtle variations of the [HIPTN(3)N](3-) ligand are not as successful as a consequence of an unknown shunt in the catalytic cycle that consumes reduction equivalents to yield (it is proposed) dihydrogen [corrected]
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Cites
Structure–function relationships of alternative nitrogenases
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Doray, B., Ghosh, P., Griffith, J., Geuze, H. J., & Kornfeld, S. (2002) · Science · doi:10.1126/science.1075327 · Cited by 312
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Wang, M., Khan, M. A., Mohsin, I., Wicks, J., Ip, A. H., Sumon, K. Z., Dinh, C.-T., Sargent, E. H., Gates, I. D., & Kibria, M. G. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03808c · Cited by 518
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Eizawa, A., Arashiba, K., Tanaka, H., Kuriyama, S., Matsuo, Y., Nakajima, K., Yoshizawa, K., & Nishibayashi, Y. (2017) · Nature Communications · doi:10.1038/ncomms14874 · Cited by 257
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Metadata
- Authors
- Schrock, R. R.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-11-10
- Volume
- 38
- Issue
- 12
- Pages
- 955-962
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W3020848186
- Cited by
- 496
- References
- 2
- FWCI
- 11.77
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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