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π-Organogels of Self-Assembled p-Phenylenevinylenes: Soft Materials with Distinct Size, Shape, and Functions
Abstract
This Account is focused on the self-assembly of p-phenylenevinylenes, a linear pi-system, which has been extensively studied over the years due to both fundamental and technological importance. A serendipitous observation of the gelation of an oligo( p-phenylenevinylene) (OPV) derivative in nonpolar hydrocarbon solvents that led to a new class of functional materials, namely, pi-organogels, is described. Strategies to control the size, shape, and functions of the supramolecular architectures of OPV self-assemblies are highlighted. Formation of nano- to microsized helical architectures, control on chromophore packing, self-assembly induced modulation of optical properties, and application as light-harvesting assemblies are the important features of this novel class of photonically and electronically active soft materials.
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Metadata
- Authors
- Ajayaghosh, A., & Praveen, V. K.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-05-10
- Volume
- 40
- Issue
- 8
- Pages
- 644-656
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2143613206
- Cited by
- 855
- References
- 35
- FWCI
- 39.52
- Type
- journal article
- Language
- en
- Open access
- closed
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