The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Organocatalytic Ring Opening Polymerization of Trimethylene Carbonate
Abstract
A variety of organocatalysts has been surveyed in the ring opening polymerization of trimethylene carbonate. Excellent control was found for several of these catalysts yielding well-defined polycarbonates with molecular weights up to 50,000 g mol(-1), polydispersities below 1.08, and high end-group fidelity. Melt or bulk polymerization was accomplished without loss of control of molecular weight or polydispersity, and random ester-carbonate bulk polymerizations were also demonstrated. Furthermore, by combining disparate polymerization techniques using bifunctional initiators, the mild polymerization conditions allow for the preparation of new block copolymers. Hydrogen-bond activation of monomer and initiator/propagating species is proposed as the underlying mechanism, which can be tuned to mitigate adverse side reactions.
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Citations
Cites
Enzyme catalyzed synthesis of polyesters
Varma, I. K., Albertsson, A.-C., Rajkhowa, R., & Srivastava, R. K. (2005) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2005.06.010 · Cited by 274
Andronova, N., & Albertsson, A.-C. (2006) · Biomacromolecules · doi:10.1021/bm060081c · Cited by 103
Polylactones 12. Cationic polymerization of 2,2‐dimethyltrimethylene carbonate
Kricheldorf, H. R., Dunsing, R., & Albet, A. S. I. (1987) · Die Makromolekulare Chemie · doi:10.1002/macp.1987.021881020 · Cited by 93
Cited by
Organocatalysis by N-Heterocyclic Carbenes
Enders, D., Niemeier, O., & Henseler, A. (2007) · Chemical Reviews · doi:10.1021/cr068372z · Cited by 3,059
Organocatalytic Ring-Opening Polymerization
Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489
Self-citationNitroxide-mediated polymerization
Nicolas, J., Guillaneuf, Y., Lefay, C., Bertin, D., Gigmes, D., & Charleux, B. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.002 · Cited by 1,380
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907
Self-citationBiodegradable nanostructures with selective lysis of microbial membranes
Nederberg, F., Zhang, Y., Tan, J. P. K., Xu, K., Wang, H., Yang, C., Gao, S., Guo, X. D., Fukushima, K., Li, L., et al. (2011) · Nature Chemistry · doi:10.1038/nchem.1012 · Cited by 614
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Metadata
- Authors
- Nederberg, F., Lohmeijer, B. G. G., Leibfarth, F., Pratt, R. C., Choi, J., Dove, A. P., Waymouth, R. M., & Hedrick, J. L.
- Venue
- Biomacromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-12-07
- Volume
- 8
- Issue
- 1
- Pages
- 153-160
- ISSN
- 1525-7797 (ISSN-L)
- 1526-4602
- OpenAlex
- W1986791363
- Cited by
- 346
- References
- 3
- FWCI
- 4.89
- Type
- journal article
- Language
- en
- Open access
- closed
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