The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Surfactant-Free High Internal Phase Emulsions Stabilized by Cellulose Nanocrystals
Abstract
Cellulose nanocrystals (CNCs) are rod-like colloidal particles that irreversibly adsorb at the oil-water interface to produce ultrastable emulsions. When the internal phase fraction is increased, these CNCs can produce gel-like oil-in-water high internal phase emulsions (HIPEs) in which more than 90% of the hydrophobic phase is stabilized by less than 0.1% wt. of CNCs. However, a one-step preparation of HIPEs is not possible, and incorporation of the high internal phase fraction requires the prior preparation of Pickering emulsions. We propose that this two-step process to create CNC HIPEs relies on a swelling process of the droplets that does not desorb the CNCs from the interface, decreasing the coverage ratio of the droplets and leading to coalescence. As a result, this process leads to a drops deformation and a new interfacial networking organization as revealed by confocal laser scanning microscopy (CLSM) and scanning electron microscopy (SEM) images.
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Cited by
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Pickering stabilization of foams and emulsions with particles of biological origin
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Metadata
- Authors
- Capron, I., & Cathala, B.
- Venue
- Biomacromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-01-08
- Volume
- 14
- Issue
- 2
- Pages
- 291-296
- ISSN
- 1525-7797 (ISSN-L)
- 1526-4602
- OpenAlex
- W2334910708
- Cited by
- 437
- References
- 23
- FWCI
- 10.21
- Type
- journal article
- Language
- en
- Open access
- closed
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