The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Fatty Acid-Derived Diisocyanate and Biobased Polyurethane Produced from Vegetable Oil: Synthesis, Polymerization, and Characterization
Abstract
A new linear saturated terminal diisocyanate was synthesized from oleic acid via Curtius rearrangement, and its chemical structure was identified by FTIR, (1)H and (13)C NMR, and MS. The feasibility of utilizing this new diisocyanate for the production of polyurethanes (PUs) was demonstrated by reacting it with commercial petroleum-derived polyols and canola oil-derived polyols, respectively. The physical properties of the PUs prepared from fatty acid-derived diisocyanate were compared to those prepared from the same polyols with a similar but petroleum-derived commercially available diisocyanate: 1,6-hexamethylene diisocyanate. It was found that the fatty acid-derived diisocyanate was capable of producing PUs with comparable properties within acceptable tolerances. This work is the first that establishes the production of linear saturated terminal diisocyanate derived from fatty acids and corresponding PUs mostly from lipid feedstock.
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Vegetable oil-based polymeric materials: synthesis, properties, and applications
Xia, Y., & Larock, R. C. (2010) · Green Chemistry · doi:10.1039/c0gc00264j · Cited by 864
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Miao, S., Wang, P., Su, Z., & Zhang, S. (2014) · Acta Biomaterialia · doi:10.1016/j.actbio.2013.08.040 · Cited by 573
Vegetable oil based eco-friendly coating materials: A review article
Alam, M., Akram, D., Sharmin, E., Zafar, F., & Ahmad, S. (2014) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2013.12.023 · Cited by 458
Sustainable polymers from biomass: Bridging chemistry with materials and processing
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Metadata
- Authors
- Hojabri, L., Kong, X., & Narine, S. S.
- Venue
- Biomacromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-12
- Volume
- 10
- Issue
- 4
- Pages
- 884-891
- ISSN
- 1525-7797 (ISSN-L)
- 1526-4602
- OpenAlex
- W1989634615
- Cited by
- 269
- References
- 29
- FWCI
- 9.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hojabri, L., Kong, X., & Narine, S. S. (2009). Fatty Acid-Derived Diisocyanate and Biobased Polyurethane Produced from Vegetable Oil: Synthesis, Polymerization, and Characterization. Biomacromolecules. https://doi.org/10.1021/bm801411w
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
