Thermal degradation of segmented polyurethanes

Petrović, Zoran S.; Zavargo, Zoltan; Flyn, Joseph H.; Macknight, William J.

doi:10.1002/app.1994.070510615

Cited by 404Thermal and Kinetic AnalysisPolymer Science and PVCPolymer crystallization and properties

Thermal degradation of segmented polyurethanes

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Petrović, Zoran S., Zavargo, Zoltan, Flyn, Joseph H., Macknight, William J.·1994·Journal of Applied Polymer Science

DOI 10.1002/app.1994.070510615

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Abstract

Abstract Thermal degradation of polyurethane samples was studied by a thermogravimetric method. The effect of soft‐segment length and soft‐segment concentration on activation energy of the degradation process was measured. Three methods of calculation gave activation energies at different stages of the very complex weight loss process. It was shown that at initial stages of the weight loss the process was dominated by hard‐segment degradation. Activation energy of the whole process calculated by the Ozawa–Flynn method did not offer clear insight into the structure–stability relationship of polyurethanes. The second method showed that activation energy of the initial stage of degradation increased with decrease in hard‐segment length. The Flynn method of calculating activation energy produced fairly constant activation energy of the first 40% degradation, at around 150 kJ/mol, for polymers in the C series. Generally, calculation of kinetic parameters of a complex degradation process as in polyurethanes gives results that are not easy to interpret. It has been shown qualitatively that polymers with higher soft‐segment concentration display lower initial weight loss and higher onset temperatures of degradation. © 1994 John Wiley & Sons, Inc.

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Thermoplastic SMPUs undergo thermal degradation first via decomposition of urethane bonds before soft segments start to decompose.
“Thermoplastic SMPUs undergo thermal degradation first via decomposition of urethane bonds before soft segments start to decompose [235,236].”
From Review on the Functional Determinants and Durability of Shape Memory Polymers (2010) · cites this paper as [236]

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Authors: Petrović, Z. S., Zavargo, Z., Flyn, J. H., & Macknight, W. J.
Affiliations: University of Novi Sad (RS)
National Institute of Standards and Technology (US)
University of Massachusetts Amherst (US)
Venue: Journal of Applied Polymer Science
Publisher: Wiley
Published: 1994-02-07
Volume: 51
Issue: 6
Pages: 1087-1095
ISSN: 0021-8995 (ISSN-L)
1097-4628
DOI: 10.1002/app.1994.070510615
OpenAlex: W1973937445
Cited by: 404
References: 18
Citations by year: 2026: 14 · 2025: 14 · 2024: 24 · 2023: 17 · 2022: 19 · 2021: 12 · 2020: 12 · 2019: 22 · 2018: 21 · 2017: 19 · 2016: 25 · 2015: 19 · 2014: 21 · 2013: 17 · 2012: 16
FWCI: 2.35
Type: journal article
Language: en
Open access: green
works.bepress.com
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor, 3318 d)
Locations: Journal of Applied Polymer Science (publishedVersion)
ScholarWorks@UMassAmherst (University of Massachusetts Amherst) (submittedVersion)
Topics: Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
Physical Sciences › Materials Science › Polymers and Plastics › Polymer Science and PVC
Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
Keywords: segmented polyurethanes, thermal degradation, activation energy, soft segment length, degradation kinetics, structure-stability relationship, weight loss

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Thermal degradation of segmented polyurethanes

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