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Metal Hexacyanoferrates: Electrosynthesis, in Situ Characterization, and Applications
Abstract
This review focuses on the electrosynthesis, in situ characterization, and technological applications of Prussian blue analogues with the generic formula A h M k [Fe(CN) 6 ] l · m H 2 O, where h, k, l, and m are stoichiometric numbers, A = alkali metal cation, and M is a transition metal. Six such metal hexacyanoferrate (MHCF) compounds derived from Cu, Pd, In, V, Co, and Ni are featured in this article against the backdrop of the Prussian blue parent compound itself and other related compounds. The use of cyclic voltammetry and complementary techniques including scanning probe microscopies, quartz crystal microgravimetry, and ac impedance spectroscopy, for studying the growth of MHCF films on targeted substrates, is discussed. Spectroelectrochemical in situ characterization of these films in the UV−visible and IR regions is then reviewed. Finally, the use of Prussian blue and its analogues in devices for displays and “smart” windows, photoimaging, environmental remediation, chemical/biological sensing, energy conversion, and magneto-optic/opto-magnetic switching is described. Electrocatalysis of targeted reactions and structural changes upon ion uptake by the MHCF compounds constitute the other topics in this review.
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Citations
Cited by
Electrochromics for smart windows: Oxide-based thin films and devices
Granqvist, C. G. (2014) · Thin Solid Films · doi:10.1016/j.tsf.2014.02.002 · Cited by 1,080
Sensor and biosensor preparation, optimisation and applications of Prussian Blue modified electrodes
Ricci, F., & Palleschi, G. (2005) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2004.12.001 · Cited by 781
Synthesis of Prussian Blue Nanoparticles with a Hollow Interior by Controlled Chemical Etching
Hu, M., Furukawa, S., Ohtani, R., Sukegawa, H., Nemoto, Y., Reboul, J., Kitagawa, S., & Yamauchi, Y. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201105190 · Cited by 532
Oxide electrochromics: An introduction to devices and materials
Granqvist, C. G. (2012) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2011.08.021 · Cited by 440
Prussian blue and its derivatives as electrode materials for electrochemical energy storage
Xu, Y., Zheng, S., Tang, H., Guo, X., Xue, H., & Pang, H. (2017) · Energy Storage Materials · doi:10.1016/j.ensm.2017.06.002 · Cited by 322
Prussian blue analogues and their derived nanomaterials for electrocatalytic water splitting
Cao, L.-M., Lu, D., Zhong, D.-C., & Lu, T.-B. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213156 · Cited by 267
Metadata
- Authors
- de Tacconi, N. R., Rajeshwar, K., & Lezna, R. O.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-07-08
- Volume
- 15
- Issue
- 16
- Pages
- 3046-3062
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2067715706
- Cited by
- 460
- References
- 0
- FWCI
- 18.92
- Type
- journal article
- Language
- en
- Open access
- closed
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