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Topochemical Synthesis of Sodium Metal Phosphate Olivines for Sodium-Ion Batteries
Abstract
New metastable olivine phases of sodium metal phosphates, Na[Mn 1– x M x ]PO 4 (M = Fe, Ca, Mg), nanorods are synthesized by a simple solid-state reaction at low temperature (≤100 °C) by means of a topotactic molten salt reaction that converts NH 4 [Mn 1– x M x ]PO 4 •H 2 O (M = Fe, Ca, Mg) to Na[Mn 1– x M x ]PO 4 . Their crystal structures are characterized via XRD Rietveld refinement and electron diffraction. A full range of solid solution behavior was observed for olivine Na 1– x Mn 0.5 Fe 0.5 PO 4, in contrast to that of LiMPO 4 (M = Fe, Mn) olivine materials, and is ascribed to ion size effects. The solid solution behavior of NaMn 0.5 Fe 0.5 PO 4 was confirmed by electrochemical characterization.
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Citations
Cited by
Kim, S., Seo, D., Ma, X., Ceder, G., & Kang, K. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200026 · Cited by 3,370
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
Pan, H., Hu, Y.-S., & Chen, L. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40847g · Cited by 3,319
Prussian blue: a new framework of electrode materials for sodium batteries
Lu, Y., Wang, L., Cheng, J., & Goodenough, J. B. (2012) · Chemical Communications · doi:10.1039/c2cc31777j · Cited by 1,162
An Amorphous Red Phosphorus/Carbon Composite as a Promising Anode Material for Sodium Ion Batteries
Kim, Y., Park, Y., Choi, A., Choi, N., Kim, J., Lee, J., Ryu, J. H., Oh, S. M., & Lee, K. T. (2013) · Advanced Materials · doi:10.1002/adma.201204877 · Cited by 854
Self-citationExtraction of lithium with functionalized lithium ion-sieves
Xu, X., Chen, Y., Wan, P., Gasem, K., Wang, K., He, T., Adidharma, H., & Fan, M. (2016) · Progress in Materials Science · doi:10.1016/j.pmatsci.2016.09.004 · Cited by 536
Metadata
- Authors
- Lee, K. T., Ramesh, T. N., Nan, F., Botton, G., & Nazar, L. F.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-07-20
- Volume
- 23
- Issue
- 16
- Pages
- 3593-3600
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2332110027
- Cited by
- 309
- References
- 0
- FWCI
- 16.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lee, K. T., Ramesh, T. N., Nan, F., Botton, G., & Nazar, L. F. (2011). Topochemical Synthesis of Sodium Metal Phosphate Olivines for Sodium-Ion Batteries. Chemistry of Materials. https://doi.org/10.1021/cm200450y
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