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Anatase TiO2 with Dominant High-Energy {001} Facets: Synthesis, Properties, and Applications

Liu, Shengwei, Yu, Jiaguo, Jaroniec, Mietek·2011·Chemistry of Materials

Abstract

Control of the surface structure of inorganic materials, in particular titania (TiO 2 ), by chemical processes under nonequilibrium conditions is of growing interest from scientific and utilitarian viewpoints. Titania is one of the most important materials because of its unique surface, electronic, and photocatalytic properties, which make this material applicable in many areas of science and technology ranging from adsorption, catalysis and photocatalysis to biomedicine, environmental monitoring and cleanup, energy conversion and storage, etc. Here we review the existing strategies for the synthesis of anatase TiO 2 micro- and nanosheets with exposed high-energy {001} facets and for the assembly of these nanosheets into various hierarchical structures. The {001} facets are stabilized by specific capping agents (typically, fluoride), which are used to control the growth of titania crystals. The presence of high-energy facets in titania improves significantly its adsorption, electronic, and photocatalytic properties, making this material attractive for various environmental and energy-related applications.

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Metadata

Authors
Liu, S., Yu, J., & Jaroniec, M.
Venue
Chemistry of Materials
Published
2011-07-27
Volume
23
Issue
18
Pages
4085-4093
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2003353322
Cited by
714
References
2
FWCI
31.00
Type
journal article
Language
en
Open access
closed

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