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A Novel Wet Chemistry Approach for the Synthesis of Hybrid 2D Free-Floating Single or Multilayer Nanosheets of MS2@oleylamine (M═Mo, W)

Altavilla, Claudia, Sarno, Maria, Ciambelli, Paolo·2011·Chemistry of Materials

Abstract

A new wet chemistry approach, based on low-temperature (360 °C) decomposition in oleylamine of single-source precursors containing both metal and sulfur, is proposed for the production of stable free-standing nanosheets of MoS 2 and WS 2 . The one-pot synthesis permits high-quality 2D nanosheet crystals of MoS 2 and WS 2 to be obtained with a modular number of nanolayers for units. The layered materials obtained are covered by a dynamic protective coating of oleylamine that stabilizes the suspension, avoids aggregation and oxidation phenomena, and could be easily functionalized with other molecules or nanosystems to introduce new properties to the hybrid organic–inorganic nanocomposite. The reaction products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), attenuated total reflectance Fourier transform infrared spectroscopy (ART-FTIR), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis coupled with mass spectrometry (TG-MS), and dynamic light scattering (DLS) for particle size distribution (PSD).

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Metadata

Authors
Altavilla, C., Sarno, M., & Ciambelli, P.
Venue
Chemistry of Materials
Published
2011-08-11
Volume
23
Issue
17
Pages
3879-3885
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2314915452
Cited by
317
References
1
FWCI
7.59
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Novel Wet Chemistry Approach for the Synthesis of Hybrid 2D Free-Floating Single or Multilayer Nanosheets of MS2@oleylamine (M═Mo, W). https://app.cochat.ai/papers/10.1021/cm200837g
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Altavilla, C., Sarno, M., & Ciambelli, P. (2011). A Novel Wet Chemistry Approach for the Synthesis of Hybrid 2D Free-Floating Single or Multilayer Nanosheets of MS2@oleylamine (M═Mo, W). Chemistry of Materials. https://doi.org/10.1021/cm200837g

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