The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Chromium(III) Terephthalate Metal Organic Framework (MIL-101): HF-Free Synthesis, Structure, Polyoxometalate Composites, and Catalytic Properties
Abstract
Hybrid materials of the metal–organic framework (MOF), chromium(III) terephthalate (MIL-101), and phosphotungstic acid (PTA) were synthesized in aqueous media in the absence of hydrofluoric acid. XRD analysis of the MIL101/PTA composites indicates the presence of ordered PTA assemblies residing in both the large cages and small pores of MIL-101, which suggests the formation of previously undocumented structures. The MIL101/PTA structure enables a PTA payload 1.5–2 times higher than previously achieved. The catalytic performance of the MIL101/PTA composites was assessed in the Baeyer condensation of benzaldehyde and 2-naphthol, in the three-component condensation of benzaldehyde, 2-naphthol, and acetamide, and in the epoxidation of caryophyllene by hydrogen peroxide. The catalytic efficiency was demonstrated by the high (over 80–90%) conversion of the reactants under microwave-assisted heating. In four consecutive reaction cycles, the catalyst recovery was in excess of 75%, whereas the product yields were maintained above 92%. The simplicity of preparation, exceptional stability, and reactivity of the novel composites indicate potential in utilization of these catalytic matrices in a multitude of catalytic reactions and engineering processes.
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Cited by
Heterogeneous Catalysis by Polyoxometalates in Metal–Organic Frameworks
Samaniyan, M., Mirzaei, M., Khajavian, R., Eshtiagh-Hosseini, H., & Streb, C. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b03439 · Cited by 389
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals
Dhakshinamoorthy, A., Opanasenko, M., Čejka, J., & Garcia, H. (2013) · Catalysis Science & Technology · doi:10.1039/c3cy00350g · Cited by 296
Taking organic reactions over metal-organic frameworks as heterogeneous catalysis
Hu, M.-L., Safarifard, V., Doustkhah, E., Rostamnia, S., Morsali, A., Nouruzi, N., Beheshti, S., & Akhbari, K. (2018) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2017.07.057 · Cited by 283
Kaur, H., Devi, N., Siwal, S. S., Alsanie, W. F., Thakur, M. K., & Thakur, V. K. (2023) · ACS Omega · doi:10.1021/acsomega.2c07719 · Cited by 273
Metadata
- Authors
- Bromberg, L., Diao, Y., Wu, H., Speakman, S. A., & Hatton, T. A.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-27
- Volume
- 24
- Issue
- 9
- Pages
- 1664-1675
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1986289620
- Cited by
- 444
- References
- 41
- FWCI
- 14.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bromberg, L., Diao, Y., Wu, H., Speakman, S. A., & Hatton, T. A. (2012). Chromium(III) Terephthalate Metal Organic Framework (MIL-101): HF-Free Synthesis, Structure, Polyoxometalate Composites, and Catalytic Properties. Chemistry of Materials. https://doi.org/10.1021/cm2034382
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