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Coordination-Driven Multistep Assembly of Metal–Polyphenol Films and Capsules
Open accessAbstract
Abstract We report the assembly of metal-polyphenol complex (MPC) films and capsules through the sequential deposition of iron(III) ions (Fe(III)) and a natural polyphenol, tannic acid (TA), driven by metal–ligand coordination. Stable Fe(III)/TA films and capsules were formed, indicating lateral and longitudinal cross-linking of TA by Fe(III) in the film structure. Quartz crystal microbalance, ultraviolet–visible (UV-vis) spectrophotometry, and X-ray photoelectron spectroscopy were carried out to quantitatively analyze the film growth. A comparison of the MPC capsules prepared through multistep assembly with those obtained through one-step deposition, as reported previously [Ejima et al., Science 2013, 341, 154–156], reveals substantial differences in the nature of complexation and in their physicochemical properties, including permeability, stiffness, and degradability. This study highlights the importance of engineering MPC films with different properties through implementing different assembly methods.
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Cites
Tannins and Human Health: A Review
Chung, K.-T., Wong, T. Y., Wei, C.-I., Huang, Y.-W., & Lin, Y. (1998) · Critical Reviews in Food Science and Nutrition · doi:10.1080/10408699891274273 · Cited by 1,996
A Review of the Antioxidant Mechanisms of Polyphenol Compounds Related to Iron Binding
Perron, N. R., & Brumaghim, J. L. (2009) · Cell Biochemistry and Biophysics · doi:10.1007/s12013-009-9043-x · Cited by 1,370
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Metal Ion-Directed Functional Metal–Phenolic Materials
Geng, H., Zhong, Q.-Z., Li, J., Lin, Z., Cui, J., Caruso, F., & Hao, J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c01042 · Cited by 531
Self-citationApplications of tannic acid in membrane technologies: A review
Yan, W., Shi, M., Dong, C., Liu, L., & Gao, C. (2020) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2020.102267 · Cited by 473
Yu, Y., Li, P., Zhu, C., Ning, N., Zhang, S., & Vancso, G. J. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201904402 · Cited by 363
Natural polyphenols as versatile platforms for material engineering and surface functionalization
Xu, L. Q., Neoh, K.-G., & Kang, E.-T. (2018) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.08.005 · Cited by 353
Metadata
- Authors
- Rahim, M. A., Ejima, H., Cho, K. L., Kempe, K., Müllner, M., Best, J. P., & Caruso, F.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-02-10
- Volume
- 26
- Issue
- 4
- Pages
- 1645-1653
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2323224573
- Cited by
- 399
- References
- 2
- FWCI
- 9.07
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Rahim, M. A., Ejima, H., Cho, K. L., Kempe, K., Müllner, M., Best, J. P., & Caruso, F. (2014). Coordination-Driven Multistep Assembly of Metal–Polyphenol Films and Capsules. Chemistry of Materials. https://doi.org/10.1021/cm403903m
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