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The Preparation of Carbon-Supported Magnesium Nanoparticles using Melt Infiltration
Open accessAbstract
Magnesium dihydride contains 7.7 wt % hydrogen. However, its application for hydrogen storage is impeded by its high stability and slow kinetics. Bringing the size of Mg(H 2 ) into the nanometer range will not only enhance the reaction rates but has also been theoretically predicted to change the thermodynamic stability and destabilize the MgH 2 with respect to Mg. However, the preparation of such small particles is a major challenge. We identified a method to prepare large amounts of nanometer-sized nonoxidized magnesium crystallites. The method is based on infiltration of nanoporous carbon with molten magnesium. The size of the Mg crystallites is directly influenced by the pore size of the carbon and can be varied from 2–5 to less than 2 nm. The majority of the nanocrystallites is not oxidized after preparation. No bulk magnesium was detected in the samples with nanoparticle loadings up to 15 wt % on carbon. These 3D supported nanomaterials present interesting systems to study how nanosizing and support interaction can steer the hydrogen sorption properties of metal hydrides.
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Cited by
Jeon, K.-J., Moon, H. R., Ruminski, A. M., Jiang, B., Kisielowski, C., Bardhan, R., & Urban, J. J. (2011) · Nature Materials · doi:10.1038/nmat2978 · Cited by 731
Yu, X., Tang, Z., Sun, D., Ouyang, L., & Zhu, M. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.03.001 · Cited by 716
Advanced carbon aerogels for energy applications
Biener, J., Stadermann, M., Suss, M., Worsley, M. A., Biener, M. M., Rose, K. A., & Baumann, T. F. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00627k · Cited by 651
Hydrogen in magnesium: new perspectives toward functional stores
Aguey-Zinsou, K.-F., & Ares-Fernández, J.-R. (2010) · Energy & Environmental Science · doi:10.1039/b921645f · Cited by 447
Review of magnesium hydride-based materials: development and optimisation
Crivello, J.-C., Dam, B., Denys, R. V., Dornheim, M., Grant, D. M., Huot, J., Jensen, T. R., de Jongh, P., Latroche, M., Milanese, C., et al. (2016) · Applied Physics A · doi:10.1007/s00339-016-9602-0 · Cited by 409
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Metadata
- Authors
- de Jongh, P. E., Wagemans, R. W. P., Eggenhuisen, T. M., Dauvillier, B. S., Radstake, P. B., Meeldijk, J. D., Geus, J. W., & de Jong, K. P.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-10-26
- Volume
- 19
- Issue
- 24
- Pages
- 6052-6057
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1975151846
- Cited by
- 216
- References
- 0
- FWCI
- 6.03
- Type
- journal article
- Language
- en
- Open access
- green
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- de Jongh, P. E., Wagemans, R. W. P., Eggenhuisen, T. M., Dauvillier, B. S., Radstake, P. B., Meeldijk, J. D., Geus, J. W., & de Jong, K. P. (2007). The Preparation of Carbon-Supported Magnesium Nanoparticles using Melt Infiltration. Chemistry of Materials. https://doi.org/10.1021/cm702205v
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